Patent US4865946A successfully refreshed from Google Patents.
US4865946A
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Temporary barrier layer for photographic element
Assignee: Eastman Kodak Co
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Filing: 1988-07-05
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Granted: 1989-09-12
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Expires: 2008-07-05
Abstract
Abstract A polymer composition of the formula: ##STR1## wherein R 1 , R 2 , R 3 , G, J, L, x, y, and z are as defined herein is useful as a temporary barrier between reactants in photographic materials. The barrier is particularly useful as a process timing layer in color image transfer film units.
Inventors
- 👤 Wayne A. Bowman
- 👤 Ronald L. Verhow
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-09 18:07
CPC Classifications
G; G03; G03C; G03C8/00; G03C8/42; G03C8/52; G03C8/54
Claims Analysis
Total Claims: 8
Claim 1
Independent Claim
139 words
A photographic element comprising a support having thereon at least one silver halide emulsion layer, a neutralizing layer, and a temporary barrier layer separating the silver halide emulsion layer from the neutralizing layer, said barrier layer including a polymer comprising randomly repeating units of the formula: ##STR4## wherein R 1 and R 2 each independently represents hydrogen or methyl, R 3 represents alkyl of from 1 to 4 carbon atoms, L represents a divalent alkyl linking group of from 2 to 8 carbon atoms, J represents the residue of an organic cross-linking compound having at least one other copolymerizable carbon-carbon double bond, G represents recurring units derived from one or more other polymerized ethylenically unsaturated comonomers, x represents 50 to 80 weight percent, y represents 1 to 40 weight percent, and z represents from 10 to 25 weight percent.
Claim 2
Dependent Claim
139 words
A photographic element comprising a support having thereon at least one silver halide emulsion layer, a neutralizing layer, and a temporary barrier layer separating the silver halide emulsion layer from the neutralizing layer, said barrier layer including a polymer comprising randomly repeating units of the formula: ##STR4## wherein R 1 and R 2 each independently represents hydrogen or methyl, R 3 represents alkyl of from 1 to 4 carbon atoms, L represents a divalent alkyl linking group of from 2 to 8 carbon atoms, J represents the residue of an organic cross-linking compound having at least one other copolymerizable carbon-carbon double bond, G represents recurring units derived from one or more other polymerized ethylenically unsaturated comonomers, x represents 50 to 80 weight percent, y represents 1 to 40 weight percent, and z represents from 10 to 25 weight percent.
Claim 3
Dependent Claim
83 words
A photographic element according to claim 1 wherein the polymer comprises randomly recurring units of the formula: ##STR5## wherein Z is a linking group, R 4 , R 5 , and R 6 are individually hydrogen or methyl, R 7 represents recurring units in the polymer of one or more other polymerized addition polymerizable comonomers, n is 1 or 2, x represents 50 to 89 weight percent, y represents 1 to 40 weight percent, and z represents from 10 to 25 weight percent.
Claim 4
Dependent Claim
20 words
A photographic element according to claim 1 wherein J is selected from the group consisting of ethylenebis(iminocarbonyl), ethylenebis(oxycarbonyl), and phenylene.
Claim 5
Dependent Claim
167 words
In a photographic element comprising at least open silver halide emulsion layer, a dye image-providing layer, a dye image-receiving layer, and a neutralizing layer, said element containing a temporary barrier layer located between the neutralizing layer and the silver halide emulsion layer, said neutralizing layer providing a pH of 11 or less to the silver halide emulsion layer, the improvement wherein the barrier layer includes a polymer comprising randomly repeating units of the formula: ##STR6## wherein R 1 and R 2 each independently represents hydrogen or methyl, R 3 represents alkyl of from 1 to 4 carbon atoms, L represents an divalent alkyl linking group of from 2 to 8 carbon atoms, J represents the residue of an organic cross-linking compound having at least one other copolymerizable carbon-carbon double bond, G represents recurring units derived from one or more other polymerized ethylenically unsaturated comonomers, x represents 50 to 8 weight percent, y represents 1 to 40 weight percent, and z represents from 10 to 25 weight percent.
Claim 6
Dependent Claim
167 words
In a photographic element comprising at least open silver halide emulsion layer, a dye image-providing layer, a dye image-receiving layer, and a neutralizing layer, said element containing a temporary barrier layer located between the neutralizing layer and the silver halide emulsion layer, said neutralizing layer providing a pH of 11 or less to the silver halide emulsion layer, the improvement wherein the barrier layer includes a polymer comprising randomly repeating units of the formula: ##STR6## wherein R 1 and R 2 each independently represents hydrogen or methyl, R 3 represents alkyl of from 1 to 4 carbon atoms, L represents an divalent alkyl linking group of from 2 to 8 carbon atoms, J represents the residue of an organic cross-linking compound having at least one other copolymerizable carbon-carbon double bond, G represents recurring units derived from one or more other polymerized ethylenically unsaturated comonomers, x represents 50 to 8 weight percent, y represents 1 to 40 weight percent, and z represents from 10 to 25 weight percent.
Claim 7
Dependent Claim
83 words
A photographic element according to claim 4 wherein the polymer comprises randomly recurring units of the formula: ##STR7## wherein Z is a linking group, R 4 , R 5 , and R 6 are individually hydrogen or methyl, R 7 represents recurring units in the polymer of one or more other polymerized addition polymerizable comonomers, n is 1 or 2, x represents 50 to 89 weight percent, y represents 1 to 40 weight percent, and z represents from 10 to 25 weight percent.
Claim 8
Dependent Claim
20 words
A photographic element according to claim 4 wherein J is selected from the group consisting of ethylenebis(iminocarbonyl), ethylenebis(oxycarbonyl), and phenylene.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1992-09-11 | 1993-03-13 | 1993-09-12 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1996-09-11 | 1997-03-13 | 1997-09-12 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2000-09-11 | 2001-03-13 | 2001-09-12 | $7700.00 | Window Closed / Lapsed |