US4863787A
Expired / Lapsed
US
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Damage tolerant composites containing infusible particles
Assignee: Hexcel Corp
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Filing: 1986-07-09
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Granted: 1989-09-05
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Expires: 2006-07-09
Abstract
Abstract Damage tolerant composites comprising high strength filaments in the form of bundles or tows of continuous fiber and a tough phase separated, crosslinked epoxy resin matrix are disclosed. The crosslinked epoxy resin matrix comprises infusible particles made from a rubber polymer that reside primarily between plies of the composite and critically have a median particle size between 10-75 microns. Prepregs for making the damage tolerant composites and methods of making such prepregs and the epoxy resin compositions thereof are also disclosed. The epoxy resin compositions comprise the infusible particles which become segregated as to size on a surface layer of the prepreg during the process of combining the high strength filaments of the prepreg and the resin containing the epoxy resin composition.
Inventors
- 👤 Irena Gawin
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-29 18:46
CPC Classifications
C; C08; C08G; C08G59/00; C08G59/18; C08G59/20; C08G59/22; C08G59/226; C08G59/32; C08G59/38; C08G59/40; C08G59/50; C08G65/00; C08G65/34; C08G65/48; C08J; C08J5/00; C08J5/24; C08J5/241; C08J5/243; C08J5/249; C08L; C08L63/00; C08L65/00; C08L71/00; C08L81/00; C08L81/06; C08J2363/00; Y; Y10; Y10T; Y10T428/00; Y10T428/29; Y10T428/31504; Y10T428/31511; Y10T442/00; Y10T442/20; Y10T442/2926; Y10T442/2984
Claims Analysis
Total Claims: 20
Claim 1
Independent Claim
137 words
A method of making a prepreg suitable for making damage tolerant composites, said method comprising: forming a thermosettable epoxy resin composition comprising infusible particles (a) respectively comprising an amount of a rubber polymer and (b) having a median size between about 10 and 75 microns, said epoxy resin composition being capable of curing into a crosslinked epoxy thermoset that is phase separated and has a K 10 above about 1 MPa√m; combining together said epoxy resin composition and high strength filaments in the form of one or more filament bundles or tows such that at least 50% of said particles having a dimension greater than 10 microns are dispersed in that part of said prepreg which is closer to a resin surface thereof that is on said bundles or tows than contained within said bundles or tows.
Claim 2
Independent Claim
137 words
A method of making a prepreg suitable for making damage tolerant composites, said method comprising: forming a thermosettable epoxy resin composition comprising infusible particles (a) respectively comprising an amount of a rubber polymer and (b) having a median size between about 10 and 75 microns, said epoxy resin composition being capable of curing into a crosslinked epoxy thermoset that is phase separated and has a K 10 above about 1 MPa√m; combining together said epoxy resin composition and high strength filaments in the form of one or more filament bundles or tows such that at least 50% of said particles having a dimension greater than 10 microns are dispersed in that part of said prepreg which is closer to a resin surface thereof that is on said bundles or tows than contained within said bundles or tows.
Claim 3
Dependent Claim
61 words
A method in accordance with claim 1, wherein said epoxy resin composition is made by a process comprising combining ingredients comprising (a) a polyepoxide component comprising a polyepoxide compound having a glass transition below 50° C., (b) a reactive polyarylene polyether sulfone having a molecular weight between 2,000 and 10,000 (number average); (c) an amine hardener; and (d) a rubber polymer.
Claim 4
Dependent Claim
17 words
A method in accordance with claim 1, wherein said particles are made a carboxy butadiene arylonitrile polymer.
Claim 5
Dependent Claim
159 words
A prepreg containing a reactive aromatic oligomer and useful in making damage tolerant structural composites, said prepreg comprising one or more high strength filament tows or bundles and a thermosettable epoxy resin composition, said thermosettable epoxy resin composition comprising said oligomer and impregnating said tows or bundles to provide a portion of said thermosettable epoxy resin composition contained within said tows or bundles and a portion of said thermosettable epoxy resin composition atop a surface of said tows or bundles as a resin surface of said prepreg, said thermosettable epoxy resin composition comprising infusible particles which contain a rubber polymer and have a median size between about 10 microns and 75 microns, said infusible particles distributed in said thermosettable epoxy resin composition such that the number of said particles having a dimension greater than 10 microns is greater in that part of said thermosettable epoxy resin composition closer to said resin surface than contained within said tows or bundles.
Claim 6
Dependent Claim
159 words
A prepreg containing a reactive aromatic oligomer and useful in making damage tolerant structural composites, said prepreg comprising one or more high strength filament tows or bundles and a thermosettable epoxy resin composition, said thermosettable epoxy resin composition comprising said oligomer and impregnating said tows or bundles to provide a portion of said thermosettable epoxy resin composition contained within said tows or bundles and a portion of said thermosettable epoxy resin composition atop a surface of said tows or bundles as a resin surface of said prepreg, said thermosettable epoxy resin composition comprising infusible particles which contain a rubber polymer and have a median size between about 10 microns and 75 microns, said infusible particles distributed in said thermosettable epoxy resin composition such that the number of said particles having a dimension greater than 10 microns is greater in that part of said thermosettable epoxy resin composition closer to said resin surface than contained within said tows or bundles.
Claim 7
Dependent Claim
18 words
The prepreg in accordance with claim 4, wherein said high strength fiber tows comprise tows of carbon fiber.
Claim 8
Dependent Claim
62 words
The prepreg in accordance with claim 5, wherein said thermosettable resin composition is made by a process comprising combining ingredients comprising (a) a polyepoxide component comprising a polyepoxide compound having a glass transition below 50° C.; (b) a reactive poyarylene polyether sulfone oligomer having a molecular weight between about 2,000 and 10,000; (c) an amine hardener; and (d) a crosslinkable rubber polymer.
Claim 9
Dependent Claim
32 words
The prepreg in accordance with claim 6, wherein there are particles comprising said rubber polymer having a median size less than about 10 microns that are carried within said tows or bundles.
Claim 10
Dependent Claim
21 words
The prepreg in accordance with claim 7, wherein said tows or bundles extend in two or more directions in said prepreg.
Claim 11
Dependent Claim
21 words
The prepreg in accordance with claim 8, wherein said tows or bundles extend in a single direction and form a sheet.
Claim 12
Dependent Claim
21 words
The prepreg in accordance with claim 9, wherein a single tow or bundle of said high strength filaments form said prepreg.
Claim 13
Dependent Claim
154 words
A prepreg useful in making damage tolerant structural composites, said prepreg comprising one or more high strength filament tows or bundles and a thermosettable epoxy resin composition, said thermosettable epoxy resin composition impregnating said tows or bundles to provide a portion of said epoxy resin composition contained within said tows or bundles and a portion of said epoxy resin composition atop a surface of said tows or bundles as a resin surface of said prepreg, said thermosettable epoxy resin forming a phase separated, crosslinked epoxy matrix upon cure and comprising infusible particles which contain a rubber polymer and have a median size between 10 microns and 75 microns, said infusible particles distributed in said thermosettable epoxy resin such that the number of said particles having a dimension greater than 10 microns is greater in that part of said thermosettable epoxy resin composition closer to said resin surface than contained within said tows or bundles.
Claim 14
Dependent Claim
154 words
A prepreg useful in making damage tolerant structural composites, said prepreg comprising one or more high strength filament tows or bundles and a thermosettable epoxy resin composition, said thermosettable epoxy resin composition impregnating said tows or bundles to provide a portion of said epoxy resin composition contained within said tows or bundles and a portion of said epoxy resin composition atop a surface of said tows or bundles as a resin surface of said prepreg, said thermosettable epoxy resin forming a phase separated, crosslinked epoxy matrix upon cure and comprising infusible particles which contain a rubber polymer and have a median size between 10 microns and 75 microns, said infusible particles distributed in said thermosettable epoxy resin such that the number of said particles having a dimension greater than 10 microns is greater in that part of said thermosettable epoxy resin composition closer to said resin surface than contained within said tows or bundles.
Claim 15
Dependent Claim
18 words
The prepreg in accordance with claim 11, wherein said high strength fiber tows comprise tows of carbon fiber.
Claim 16
Dependent Claim
61 words
The prepreg in accordance with claim 12, wherein said thermosettable resin is made by a process comprising combining ingredients comprising (a) a polyepoxide component comprising a polyepoxide compound having a glass transition below about 50° C.; (b) a reactive polyether sulfone oligomer having a molecular weight between about 2,000 and 10,000; (c) an amine hardner; and (d) a crosslinkable rubber polymer.
Claim 17
Dependent Claim
32 words
The prepreg in accordance with claim 13, wherein there are particles comprising said rubber polymer having a median size less than about 10 microns that are carried within said tows or bundles.
Claim 18
Dependent Claim
21 words
The prepreg in accordance with claim 14, wherein said tows or bundles extend in two or more directions in said prepreg.
Claim 19
Dependent Claim
21 words
The prepreg in accordance with claim 15, wherein said tows or bundles extend in a single direction and form a sheet.
Claim 20
Dependent Claim
21 words
The prepreg in accordance with claim 16, wherein a single tow or bundle of said high strength filaments form said prepreg.
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