Patent US1724894A successfully refreshed from Google Patents.
US4861677A
Expired / Lapsed
US
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Coextrudable adhesive for polystyrene, and products therefrom
Assignee: EIDP Inc
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Filing: 1988-06-03
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Granted: 1989-08-29
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Expires: 2008-06-03
Abstract
Abstract A blend of ethylene vinyl acetate copolymer, ethylene vinyl acetate copolymer modified by grafting with a comonomer containing pendant acid or acid derivative functionality, and impact-modified polystyrene provides a useful adhesive, particularly for bonding polystyrene to gas barrier polymers.
Inventors
- 👤 I-Hwa Lee
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-29 08:09
CPC Classifications
B; B32; B32B; B32B27/00; B32B27/06; B32B27/08; C; C08; C08L; C08L23/00; C08L23/02; C08L23/04; C08L23/08; B32B27/30; B32B27/302; B32B27/306; B32B7/00; B32B7/04; B32B7/12; C09; C09J; C09J123/00; C09J123/02; C09J123/04; C09J123/08; C09J151/00; C09J151/06; B32B2307/00; B32B2307/50; B32B2307/558; B32B2325/00; B32B2331/00; B32B2331/04; B32B2439/00; C08L2666/00; C08L2666/02; C08L2666/04; C08L2666/24; Y; Y10; Y10T; Y10T428/00; Y10T428/31504; Y10T428/31855; Y10T428/31909; Y10T428/31913
Claims Analysis
Total Claims: 13
Claim 1
Independent Claim
190 words
An extrudable bonding resin composition consisting essentially of: (a) about 55 to about 80 percent by weight of an ethylene vinyl acetate copolymer portion consisting essentially of (i) 0 to about 99 percent by weight of a copolymer of about 60 to about 87 weight percent ethylene and about 13 to about 40 weight percent vinyl acetate comonomer, and (ii) about 1 to 100 percent by weight of a copolymer of at least about 50 weight percent ethylene; about 3 to about 50 weight percent vinyl acetate comonomer, the amount of said vinyl acetate comonomer being within about 10 percent of the amount of vinyl acetate comonomer in copolymer (i), if present; and a grafted comonomer containing pendant carboxylic acid or carboxylic acid derivative functionality, wherein the amount of said grafted comonomer comprises about 0.03 to about 0.5 percent by weight of the total composition and the total amount of copolymerized vinyl acetate of (i) and (ii) exceeds about 13.5 percent by weight of the total composition; and (b) about 20 to about 45 percent by weight of an impact modified polystyrene having a molecular weight of greater than 50,000.
Claim 2
Dependent Claim
190 words
An extrudable bonding resin composition consisting essentially of: (a) about 55 to about 80 percent by weight of an ethylene vinyl acetate copolymer portion consisting essentially of (i) 0 to about 99 percent by weight of a copolymer of about 60 to about 87 weight percent ethylene and about 13 to about 40 weight percent vinyl acetate comonomer, and (ii) about 1 to 100 percent by weight of a copolymer of at least about 50 weight percent ethylene; about 3 to about 50 weight percent vinyl acetate comonomer, the amount of said vinyl acetate comonomer being within about 10 percent of the amount of vinyl acetate comonomer in copolymer (i), if present; and a grafted comonomer containing pendant carboxylic acid or carboxylic acid derivative functionality, wherein the amount of said grafted comonomer comprises about 0.03 to about 0.5 percent by weight of the total composition and the total amount of copolymerized vinyl acetate of (i) and (ii) exceeds about 13.5 percent by weight of the total composition; and (b) about 20 to about 45 percent by weight of an impact modified polystyrene having a molecular weight of greater than 50,000.
Claim 3
Dependent Claim
38 words
The composition of claim 1 wherein the amount of ethylene vinyl acetate portion is about 55 to about 70 weight percent and the impact modified polystyrene is about 30 to about 45 percent by weight of the composition.
Claim 4
Dependent Claim
24 words
The composition of claim 1 wherein the amount of vinyl acetate comonomer in copolymer (i) is about 25 to about 35 percent by weight.
Claim 5
Dependent Claim
24 words
The composition of claim 1 wherein the amount of vinyl acetate comonomer in copolymer (ii) is about 15 to about 35 percent by weight.
Claim 6
Dependent Claim
29 words
The composition of claim 4 wherein the carboxylic acid or carboxylic acid derivative is grafted onto polymer (ii) in an amount of about 0.05 to about 5 weight percent.
Claim 7
Dependent Claim
28 words
The composition of claim 5 wherein the carboxylic acid or carboxylic acid derivative is an ethylenically unsaturated mono, di, or polycarboxylic acid, anhydride, salt, amide, imide, or ester.
Claim 8
Dependent Claim
44 words
The composition of claim 6 wherein the carboxylic acid or carboxylic acid derivative is acrylic acid, methacrylic acid, maleic acid, fumaric acid, itaconic acid, crotonic acid, itaconic anhydride, maleic anhydride, dimethyl maleic anhydride monosodium maleate, disodium maleate, diethyl fumarate, maleic anhydride and maleic acid.
Claim 9
Dependent Claim
16 words
The composition of claim 6 wherein the carboxylic acid or carboxylic acid derivative is an anhydride.
Claim 10
Dependent Claim
11 words
The composition of claim 8 wherein the anhydride is maleic anhydride.
Claim 11
Dependent Claim
20 words
The composition of claim 1 wherein the impact modified polystyrene has an impact strength of at least about 92 J/m.
Claim 12
Dependent Claim
29 words
A laminated structure comprising at least one structural layer, at least one barrier layer, and at least one bonding layer of the extrudable bonding resin composition of claim 1.
Claim 13
Dependent Claim
23 words
The laminated structure of claim 11 wherein the structural layer is high impact polystyrene and the barrier layer is ethylene vinyl alcohol copolymer.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1992-08-28 | 1993-02-27 | 1993-08-29 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1996-08-28 | 1997-02-27 | 1997-08-29 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2000-08-28 | 2001-02-27 | 2001-08-29 | $7700.00 | Window Closed / Lapsed |