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US4861676A Expired / Lapsed US ⏱️ 0.0 years remaining

Improved coextrudable adhesive and products therefrom

Assignee: EIDP Inc
•
Filing: 1988-08-29
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Granted: 1989-08-29
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Expires: 2008-08-29
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Abstract

Abstract A blend of ethylene copolymer, ethylene copolymer modified by grafting with a comonomer containing pendant acid or acid derivative functionality, styrene polymer, and alicyclic resin modifier or stabilized rosin ester provides a useful adhesive, particularly for bonding polystyrene to barrier polymers.

Inventors

  • 👤 I-Hwa Lee

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-28 20:30
CPC Classifications
C; C08; C08L; C08L25/00; C08L25/02; C08L25/04; C08L25/06; C08F; C08F255/00; C08F255/02; C09; C09J; C09J123/00; C09J123/02; C09J123/04; C09J123/08; C09J123/0846; C09J123/0853; C09J151/00; C09J151/06; C08L2205/00; C08L2205/02; C08L2205/03; C08L2205/035; C08L23/00; C08L23/02; C08L23/04; C08L23/08; C08L2666/00; C08L2666/02; C08L2666/04; C08L51/00; C08L51/06; C08L93/00; C08L93/04; Y; Y10; Y10T; Y10T428/00; Y10T428/31504; Y10T428/31855; Y10T428/31909; Y10T428/31913

Claims Analysis

Total Claims: 19
Claim 1
Independent Claim 347 words
An extrudable bonding resin composition consisting essentially of: (a) about 35 to about 84 percent by weight of an ethylene copolymer portion consisting essentially of (i) about 1 to 100 percent by weight of a copolymer of about 45 to about 95 weight percent ethylene and about 5 to about 55 weight percent of at least one comonomer copolymerized therewith selected from the group consisting of unsaturated mono- or dicarboxylic acids of 2-20 carbon atoms, esters of said unsaturated mono- or dicarboxylic acids, vinyl esters of saturated carboxylic acids where the acid group has 1-18 carbon atoms, acrylonitrile, methacrylonitrile, and carbon monoxide, the carbon monoxide being present in an amount of 0 to about 30 weight percent; and a grafted comonomer containing pendant carboxylic acid or carboxylic acid derivative functionality, wherein the amount of said grafted comonomer comprises about 0.03 to about 0.5 percent by weight of the total bonding resin composition, and (ii) 0 to about 99 percent by weight of a copolymer of about 45 to about 95 weight percent ethylene and about 5 to about 55 weight percent of at least one comonomer copolymerized therewith selected from the group consisting of unsaturated mono- or dicarboxylic acids of 2-20 carbon atoms, esters of said unsaturated mono- or dicarboxylic acids, vinyl esters of saturated carboxylic acids where the acid group has 1-18 carbon atoms, acrylonitrile, methacrylonitrile, and carbon monoxide, the carbon monoxide being present in an amount of 0 to about 30 weight percent, wherein the copolymer of (i) and the copolymer of (ii) contain at least one said copolymerized comonomer in common, the amount of each such common comonomer in the copolymer of (ii) being within about 10% of the amount of the corresponding comonomer in copolymer (i), and the total amount of said copolymerized comonomers other than such common comonomers in either copolymer being less than about 10%; (b) about 15 to about 45 percent by weight polystyrene; and (c) about 1 to about 25 weight percent of a saturated alicyclic hydrocarbon resin modifier having a degree of saturation of at least about 80%.
Claim 2
Dependent Claim 347 words
An extrudable bonding resin composition consisting essentially of: (a) about 35 to about 84 percent by weight of an ethylene copolymer portion consisting essentially of (i) about 1 to 100 percent by weight of a copolymer of about 45 to about 95 weight percent ethylene and about 5 to about 55 weight percent of at least one comonomer copolymerized therewith selected from the group consisting of unsaturated mono- or dicarboxylic acids of 2-20 carbon atoms, esters of said unsaturated mono- or dicarboxylic acids, vinyl esters of saturated carboxylic acids where the acid group has 1-18 carbon atoms, acrylonitrile, methacrylonitrile, and carbon monoxide, the carbon monoxide being present in an amount of 0 to about 30 weight percent; and a grafted comonomer containing pendant carboxylic acid or carboxylic acid derivative functionality, wherein the amount of said grafted comonomer comprises about 0.03 to about 0.5 percent by weight of the total bonding resin composition, and (ii) 0 to about 99 percent by weight of a copolymer of about 45 to about 95 weight percent ethylene and about 5 to about 55 weight percent of at least one comonomer copolymerized therewith selected from the group consisting of unsaturated mono- or dicarboxylic acids of 2-20 carbon atoms, esters of said unsaturated mono- or dicarboxylic acids, vinyl esters of saturated carboxylic acids where the acid group has 1-18 carbon atoms, acrylonitrile, methacrylonitrile, and carbon monoxide, the carbon monoxide being present in an amount of 0 to about 30 weight percent, wherein the copolymer of (i) and the copolymer of (ii) contain at least one said copolymerized comonomer in common, the amount of each such common comonomer in the copolymer of (ii) being within about 10% of the amount of the corresponding comonomer in copolymer (i), and the total amount of said copolymerized comonomers other than such common comonomers in either copolymer being less than about 10%; (b) about 15 to about 45 percent by weight polystyrene; and (c) about 1 to about 25 weight percent of a saturated alicyclic hydrocarbon resin modifier having a degree of saturation of at least about 80%.
Claim 3
Dependent Claim 20 words
The composition of claim 1 wherein the copolymer of (i) and the copolymer of (ii) contain the same copolymerized comonomers.
Claim 4
Dependent Claim 27 words
The composition of claim 2 wherein each comonomer in the copolymer of (ii) is within about 5% of the amount of the corresponding comonomer in copolymer (i).
Claim 5
Dependent Claim 48 words
The composition of claim 1 wherein the amount of ethylene copolymer portion is about 45 to about 65 weight percent, the polystyrene portion is about 30 to about 45 weight percent, and the saturated hydrocarbon resin portion is about 5 to about 25 weight percent of the composition.
Claim 6
Dependent Claim 29 words
The composition of claim 1 wherein the amount of comonomer in the copolymer of (i) and copolymer of (ii) each is about 9 to about 30 percent by weight.
Claim 7
Dependent Claim 41 words
The composition of claim 1 wherein the copolymer of (i) and the copolymer of (ii) are selected from the group consisting of ethylene vinyl acetate copolymer, ethylene methyl acrylate copolymer, ethylene n-butyl acrylate copolymer, and ethylene n-butyl acrylate carbon monoxide copolymer.
Claim 8
Dependent Claim 20 words
The composition of claim 6 wherein the copolymer of (i) and the copolymer of (ii) are ethylene vinyl acetate copolymer.
Claim 9
Dependent Claim 29 words
The composition of claim 1 wherein the carboxylic acid or carboxylic acid derivative is grafted onto polymer (i) in an amount of about 0.05 to about 5 weight percent.
Claim 10
Dependent Claim 28 words
The composition of claim 8 wherein the carboxylic acid or carboxylic acid derivative is an ethylenically unsaturated mono, di, or polycarboxylic acid, anhydride, salt, amide, imide, or ester.
Claim 11
Dependent Claim 44 words
The composition of claim 9 wherein the carboxylic acid or carboxylic acid derivative is acrylic acid, methacrylic acid, maleic acid, fumaric acid, itaconic acid, crotonic acid, itaconic anhydride, maleic anhydride, dimethyl maleic anhydride monosodium maleate, disodium maleate, diethyl fumarate, maleic anhydride and maleic acid.
Claim 12
Dependent Claim 16 words
The composition of claim 9 wherein the carboxylic acid or carboxylic acid derivative is an anhydride.
Claim 13
Dependent Claim 11 words
The composition of claim 11 wherein the anhydride is maleic anhydride.
Claim 14
Dependent Claim 23 words
The composition of claim 1 wherein the styrene polymer is impact modified polystyrene having an impact strength of at least about 92 J/m.
Claim 15
Dependent Claim 22 words
The composition of claim 1 wherein component (c) is a hydrocarbon resin having a molecular weight of about 650 to about 860.
Claim 16
Dependent Claim 20 words
The composition of claim 14 wherein the hydrocarbon resin is a saturated terpolymer of alpha-methyl styrene, methyl styrene, and indene.
Claim 17
Dependent Claim 29 words
A laminated structure comprising at least one structural layer, at least one barrier layer, and at least one bonding layer of the extrudable bonding resin composition of claim 1.
Claim 18
Dependent Claim 23 words
The laminated structure of claim 16 wherein the structural layer is high impact polystyrene and the barrier layer is ethylene vinyl alcohol copolymer.
Claim 19
Dependent Claim 21 words
The laminated structure of claim 16 wherein the structural layer is polyethylene and the barrier layer is ethylene vinyl alcohol copolymer.

References Cited (Backward Citations)

US3932332A Cited
JPS5318653A Cited
JPS53127546A Cited
JPS5457582A Cited
US4358557A Cited
JPS58203043A Cited
JPS5955743A Cited
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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1992-08-28 1993-02-27 1993-08-29 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1996-08-28 1997-02-27 1997-08-29 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2000-08-28 2001-02-27 2001-08-29 $7700.00 Window Closed / Lapsed

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