Photoconductive composition

Claim 2

A photoconductive composition comprising an inorganic photoconductive material, a resin binder, and a sensitizing amount of a sensitizing dye containing at least one sulfo group represented by formula (I): ##STR7## wherein: Q 1 is a substituted or unsubstituted atomic group necessary for forming a 5-membered or 6-membered heterocyclic ring or a condensed ring containing a 5-membered or 6-membered heterocyclic ring; R 0 is an alkyl group, a hydroxyalkyl group, an alkoxyalkyl group, an aralkyl group, a carboxyalkyl group, or a sulfoalkyl group; Z is an oxygen atom, a sulfur atom, a selenium atom or a tellurium atom; Q 2 is a substituted or unsubstituted atomic group necessary for forming pyrylium, benzopyrylium, naphthopyrylium, thiopyrylium, benzothiopyrylium, naphthothiopyrylium, selenapyrylium, benzoselenapyrylium, naphthoselenapyrylium, ternapyrylium, benzoternapyrylium, or naphtoterhnapyrylium, which may be substituted; Y 1 and Y 2 , which may be the same or different, each is a hydrogen atom, an aliphatic group or an aromatic group; each L is a methine group or a substituted methine group; p and q each is 0 or 1; r is 2 or 3; and the compound of formula (I) forms an inner salt.

Claim 3

The photoconductive composition as claimed in claim 1, wherein Q 1 represents an atomic group necessary for forming a thiazole ring, a benzothiazole ring, a naphthothiazole ring, a thionaphthene[7,6-d] ring, an oxazole ring, a benzoxazole ring, a naphthoxazole ring, a selenazole ring, a benzoselenazole ring, a naphthoselenazole ring, an oxazolone ring, a selenazoline ring, a thiazoline ring, a pyridine ring, a quinoline ring, an isoquinoline ring, an acridine ring, a 3,3-di-alkylindolenine ring, or a benzoimidazole ring, and the substituent for said substituted group is selected from the group consisting of a halogen atom, a substituted or unsubstituted alkyl group having 1 to 22 carbon atoms, a substituted or unsubstituted aralkyl group having 7 to 22 carbon atoms, a substituted or unsubstituted aryl group having 6 to 22 carbon atoms, a substituted or unsubstituted heterocyclic group containing at least 4 carbon atoms, a hydroxyl group, a cyano group, a nitro group, a carboxyl group, a sulfo group, an alkoxy group containing 1 to 22 carbon atoms, an aryloxy group containing 6 to 22 carbon atoms, a carboxylic acid ester group, an amino group, a monosubstituted amino group, a disubstituted amino group, a substituted or unsubstituted alkylsulfonyl group containing 1 to 22 carbon atoms, a substituted or unsubstituted arylsulfonyl group containing 6 to 22 carbon atoms, a substituted or unsubstituted acyl group containing 2 to 22 carbon atoms, a substituted or unsubstituted carbonamido group containing 1 to 22 carbon atoms and a substituted or unsubstituted sulfonamido group containing 1 to 22 carbon atoms.

Claim 4

The photoconductive composition as claimed in claim 1, wherein each said alkyl moiety contained in R 0 contains from 1 to 18 carbon atoms.

Claim 5

The photoconductive composition as claimed in claim 1, wherein said substituted atomic group represented by Q 2 is substituted with a substituent selected from the group consisting of a halogen atom, a substituted or unsubstituted alkyl group containing 1 to 22 carbon atoms, an alkoxy group containing 1 to 20 carbon atoms, a substituted or unsubstituted aralkyl group containing 7 to 22 carbon atoms, a substituted or unsubstituted aryl group containing 6 to 22 carbon atoms, a hydroxyl group, a cyano group, an alkyloxycarbonyl group containing 1 to 22 carbon atoms, an aryloxycarbonyl group containing 6 to 22 carbon atoms, an alkanesulfonyl group containing 1 to 22 carbon atoms, an arylsulfonyl group containing 6 to 22 carbon atoms, and a substituted or unsubstituted amino group containing 1 to 28 carbon atoms.

Claim 6

The photoconductive composition as claimed in claim 1, wherein Y 1 and Y 2 each is a hydrogen atom, a substituted or unsubstituted alkyl group containing 1 to 22 carbon atoms, a substituted or unsubstituted cycloalkyl group containing 5 to 22 carbon atoms, a substituted or unsubstituted aralkyl group containing 7 to 22 carbon atoms, or a substituted or unsubstituted aryl group containing 6 to 22 carbon atoms.

Claim 7

The photoconductive composition as claimed in claim 1, wherein said methine group represented by L is substituted with a substituent selected from the group consisting of a halogen atom, a carboxyl group, a hydroxyl group, an alkyl group containing 1 to 5 carbon atoms, an alkoxy group containing 1 to 5 carbon atoms, an aralkyl group containing 7 to 12 carbon atoms, a substituted or unsubstituted aryl group, and ##STR8## wherein R 3 represents an alkyl group, an aralkyl group or an aryl group.

Claim 8

The photoconductive composition as claimed in claim 1, wherein at least one of Q 1 , R 0 , and L contains --SO 3 .sup.⊖.

Claim 9

The photoconductive composition as claimed in claim 1, wherein said inorganic photoconductive material is selected from the group consisting of zinc oxide, titanium oxide, zinc sulfide and calcium sulfide.

Claim 10

The photoconductive composition as claimed in claim 1, comprising from about 0.0005 to 2.0 parts by weight of said sensitizing dye per 100 parts by weight of said photoconductive material, and about 10 to 90 parts by weight of said resin per 100 parts of the total weight of said photoconductive material and said resin.

Claim 11

The photoconductive composition as claimed in claim 9, comprising from about 0.001 to 1.0 part by weight of said sensitizing dye per 100 parts by weight of said photoconductive material, and about 15 to 60 parts by weight of said resin per 100 parts of the total weight of said photoconductive material and said resin.

Claim 12

A photoconductive composition comprising a support thereon a photoconductive layer comprising a photoconductive composition comprising an inorganic photoconductive material, a resin binder, and a sensitizing amount of a sensitizing dye containing at least one sulfo group represented by formula (I): ##STR9## wherein: Q 1 is a substituted or unsubstituted atomic group necessary for forming a 5-membered or 6-membered heterocyclic ring or a condensed ring containing a 5-membered or 6-membered heterocyclic ring; R o is an alkyl group, a hydroxyalkyl group, an alkoxyalkyl group, an aralkyl group, a carboxyalkyl group, or a sulfoalkyl group; Z is an oxygen atom, a sulfur atom, a selenium atom or a tellurium atom; Q 2 is a substituted or unsubstituted atomic group necessary for forming pyrylium, benzopyrylium, naphthopyrylium, thiopyrylium, benzothiopyrylium, naphthothiopyrylium, selenapyrylium, benzoselenapyrylium, naphthoselenapyrylium, ternapyrylium, benzoternapyrylium, or naphthoternapyrylium, which may be substituted; Y 1 and Y 2 , which may be the same or different, each is a hydrogen atom, an aliphatic group or an aromatic group; each L is a methine group or a substituted methine group; p and q each is 0 or 1; r is 2 or 3; and the compound of formula (I) forms an inner salt.

Claim 13

A photoconductive composition comprising a support thereon a photoconductive layer comprising a photoconductive composition comprising an inorganic photoconductive material, a resin binder, and a sensitizing amount of a sensitizing dye containing at least one sulfo group represented by formula (I): ##STR9## wherein: Q 1 is a substituted or unsubstituted atomic group necessary for forming a 5-membered or 6-membered heterocyclic ring or a condensed ring containing a 5-membered or 6-membered heterocyclic ring; R o is an alkyl group, a hydroxyalkyl group, an alkoxyalkyl group, an aralkyl group, a carboxyalkyl group, or a sulfoalkyl group; Z is an oxygen atom, a sulfur atom, a selenium atom or a tellurium atom; Q 2 is a substituted or unsubstituted atomic group necessary for forming pyrylium, benzopyrylium, naphthopyrylium, thiopyrylium, benzothiopyrylium, naphthothiopyrylium, selenapyrylium, benzoselenapyrylium, naphthoselenapyrylium, ternapyrylium, benzoternapyrylium, or naphthoternapyrylium, which may be substituted; Y 1 and Y 2 , which may be the same or different, each is a hydrogen atom, an aliphatic group or an aromatic group; each L is a methine group or a substituted methine group; p and q each is 0 or 1; r is 2 or 3; and the compound of formula (I) forms an inner salt.

Claim 14

The photoconductive material as claimed in claim 11, wherein said photoconductive layer is from about 1 to 50 μm thick.

Claim 15

The photographic material as claimed in claim 1, wherein said sensitizing dye is present in an amount of from 0.005 to 2.0 parts by weight per 100 parts by weight of the photoconductive material.

Claim 16

The photographic material as claimed in claim 11, wherein said sensitizing dye is present in an amount of from 0.005 to 2.0 parts by weight per 100 parts by weight of the photoconductive material.