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US4842987A Expired / Lapsed US ⏱️ 0.0 years remaining

Photosensitive element for producing printing plates or resist images

Assignee: BASF SE
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Filing: 1987-06-15
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Granted: 1989-06-27
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Expires: 2007-06-15
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Abstract

Abstract A photosensitive recording element which is suitable for the production of printing plates or resist images possesses a photopolymerizable recording layer which is applied to a dimensionally stable base, can be developed in an aqueous alkaline medium and contains, as a polymeric binder, one or more film-forming copolymers which are insoluble in water but soluble or dispersible in aqueous alkaline solutions and consist of from 10 to 50% by weight of one or more N-vinylamides, preferably N-vinylcaprolactam and/or N-vinylpyrrolidone, from 5 to 30% by weight of acrylic acid and/or methacrylic acid, from 30 to 80% by weight of one or more comonomers from the group consisting of the vinyl aromatics and (meth)acrylates of monoalkanols and from 0.2 to 5% by weight of an olefinically unsaturated compound which contains basic nitrogen atoms and has a pK a >4.

Inventors

  • 👤 Albert Elzer
  • 👤 Axel Sanner
  • 👤 Hans Schupp
  • 👤 Erich Beck

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-09 03:12
CPC Classifications
G; G03; G03F; G03F7/00; G03F7/004; G03F7/027; G03F7/032; G03F7/033; Y; Y10; Y10S; Y10S430/00; Y10S430/1053; Y10S430/1055; Y10S430/114; Y10S430/117

Claims Analysis

Total Claims: 12
Claim 1
Independent Claim 284 words
In a photosensitive recording element which is suitable for the production of negative-working printing plates or resist images and possesses a photopolymerizable recording layer which is applied to a dimensionally stable base, which layer can be developed in an aqueous alkaline medium and which layer contains a polymeric binder, the improvement which comprises: using as the polymeric binder, one or more film-forming copolymers which are insoluble in water but soluble or dispersible in aqueous alkaline solutions and consists essentially of from 10 to 50% by weight of one or more N-vinylamides, from 5 to 30% by weight of acrylic acid, methacrylic acid or a mixture of acrylic acid and methacrylic acid and from 30 to 80% by weight of one or more comonomers from the group consisting of the vinylaromatics and esters of acrylic acid or methacrylic acid with monoalkanols of 1 to 8 carbon atoms and from 0.2 to 5% by weight of at least one copolymerizable, olefinically unsaturated organic compound which contains basic nitrogen atoms and has a pK a >4, selected from the group consisting of compounds of the formulae ##STR3## where n is from 2 to 6, R is hydrogen or methyl and R 1 and R 2 are identical or different and are each hydrogen, a straight-chain or branched alkyl or hydroxyalkyl radical of 1 to 6 carbon atoms, a straight-chain or branched hydroxyalkyl radical of 1 l to 6 carbon atoms whose hydroxyl groups are etherified with alkanols of 1 to 4 carbon atoms, or cycloakyl of 5 or 6 carbon atoms, or R 1 and R 2 together form a five-membered or six-membered ring which may contain a further hetero atom, N-vinylimidazole and 2-methyl-1-vinylimidazole as copolymerized units.
Claim 2
Dependent Claim 284 words
In a photosensitive recording element which is suitable for the production of negative-working printing plates or resist images and possesses a photopolymerizable recording layer which is applied to a dimensionally stable base, which layer can be developed in an aqueous alkaline medium and which layer contains a polymeric binder, the improvement which comprises: using as the polymeric binder, one or more film-forming copolymers which are insoluble in water but soluble or dispersible in aqueous alkaline solutions and consists essentially of from 10 to 50% by weight of one or more N-vinylamides, from 5 to 30% by weight of acrylic acid, methacrylic acid or a mixture of acrylic acid and methacrylic acid and from 30 to 80% by weight of one or more comonomers from the group consisting of the vinylaromatics and esters of acrylic acid or methacrylic acid with monoalkanols of 1 to 8 carbon atoms and from 0.2 to 5% by weight of at least one copolymerizable, olefinically unsaturated organic compound which contains basic nitrogen atoms and has a pK a >4, selected from the group consisting of compounds of the formulae ##STR3## where n is from 2 to 6, R is hydrogen or methyl and R 1 and R 2 are identical or different and are each hydrogen, a straight-chain or branched alkyl or hydroxyalkyl radical of 1 to 6 carbon atoms, a straight-chain or branched hydroxyalkyl radical of 1 l to 6 carbon atoms whose hydroxyl groups are etherified with alkanols of 1 to 4 carbon atoms, or cycloakyl of 5 or 6 carbon atoms, or R 1 and R 2 together form a five-membered or six-membered ring which may contain a further hetero atom, N-vinylimidazole and 2-methyl-1-vinylimidazole as copolymerized units.
Claim 3
Dependent Claim 57 words
A recording element as defined in claim 1, wherein the copolymers present as polymeric binders in the photo-polymerizable recording layer contain, as copolymerized compounds of the formulae (I) and/or (II), dialkylaminoalkyl methacrylates or dialkylaminoalkyl methacrylamides, where n is from 2 to 6 and R 1 and R 2 are straight-chain alkyl of 1 to 4 carbon atoms.
Claim 4
Dependent Claim 56 words
A recording element as defined in claim 1, wherein the copolymers present as polymeric binders in the photo-polymerizable recording layer contain, as copolymerized compounds of the formulae (I) and/or (II), one or more compounds from the group consisting of dimethylaminoethyl acrylate, dimethylaminoethyl methacrylate, diethylaminoethyl acrylate, diethylaminoethyl methacrylate, dimethylaminoethyl acrylamide, dimethylaminoethyl methacrylamide, diethylaminoethyl acrylamide and diethylaminoethyl methacrylamide.
Claim 5
Dependent Claim 56 words
A recording element as defined in claim 2, wherein the copolymers present as a polymeric binder in the photo-polymerizable recording layer contain, as copolymerized compounds of the formulae (I) and/or (II), one or more compounds from the group consisting of dimethylaminoethyl acrylate, dimethylaminoethyl methacrylate, diethylaminoethyl acrylate, diethylaminoethyl methacrylate, dimethylaminoethyl acrylamide, dimethylaminoethyl methacrylamide, diethylaminoethylacrylamide and diethylaminoethyl methacrylamide.
Claim 6
Dependent Claim 38 words
A photosensitive recording element as defined in claim 1, wherein the copolymers present as polymeric binders in the photopolymerizable recording layer contain, as polymerized N-vinylamide comonomers, one or more N-vinyllactams from the group consisting of N-vinylpyrrolidone and, N-vinylcaprolactam.
Claim 7
Dependent Claim 27 words
A photosensitive recording element as defined in claim 1, wherein an N-vinyllactam/(meth)acrylic acid/methyl methacrylate/dimethylaminoethyl (meth)acrylate copolymer is present as a polymeric binder in the photopolymerizable recording layer.
Claim 8
Dependent Claim 26 words
A photosensitive recording element as defined in claim 1, wherein an N-vinyllactam/(meth)acrylic acid/styrene/dimethylaminoethyl (meth)acrylate copolymer is present as a polymeric binder in the photopolymerizable recording layer.
Claim 9
Dependent Claim 40 words
A photosensitive recording element as defined in claim 1, wherein the photopolymerizable recording layer contains, in addition to the polymeric binder, one or more ethylenically unsaturated, photopolymerizable compounds and one or more photoinitiators, with or without further additives or assistants.
Claim 10
Dependent Claim 38 words
A photosensitive recording element as defined in claim 8, wherein the photopolymerizable recording layer contains, as ethylenically unsaturated, photopolymerizable compounds, monomers or oligomers possessing two or more acryloyl or methacryloyl groups or a mixture of such monomers,and oligomers.
Claim 11
Dependent Claim 33 words
A photosensitive recording element as defined in claim 8, wherein the photopolymerizable recording layer contains the polymeric binders and the ethylenically unsaturated photopolymerizable compound.s in a weight ratio of from 1:99 to 90:10.
Claim 12
Dependent Claim 33 words
A photosensitive recording element as defined in claim 9 wherein the photopolymerizable recording layer contains the polymeric binders and the ethylenically unsaturated, photopolymerizable compounds in a weight ratio of from 1:99 to 90:10.

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1992-06-26 1992-12-26 1993-06-27 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1996-06-26 1996-12-26 1997-06-27 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2000-06-26 2000-12-26 2001-06-27 $7700.00 Window Closed / Lapsed

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