US4842924A
Expired / Lapsed
US
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Novel compositions based on reinforcement with microfibrillar networks of rigid-rod polymers
Assignee: Individual
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Filing: 1986-08-25
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Granted: 1989-06-27
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Expires: 2006-08-25
Abstract
Abstract A process for fabricating a composite in the form of a network of microfibrils which includes interpenetrating the microfibrils with a matrix material to form a composite which includes two continuous interpenetrating phases, a matrix-material phase and a microfibrillar-reinforcing-network phase. There is disclosed composites in the form of a fiber and in the form of a film.
Inventors
- 👤 Richard J. Farris
- 👤 Yachin Cohen
- 👤 Steven J. DeTeresa
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-01 08:00
CPC Classifications
B; B29; B29C; B29C70/00; B29C70/04; B29C70/06; B29C70/10; B29B; B29B15/00; B29B15/08; B29B15/10; B29B15/12; B29B15/122; C; C03; C03C; C03C14/00; C03C14/002; C04; C04B; C04B28/00; C04B28/24; C04B28/26; C08; C08J; C08J5/00; C08J5/04; C03C2214/00; C03C2214/02; Y; Y10; Y10S; Y10S428/00; Y10S428/903; Y10S428/91; Y10T; Y10T428/00; Y10T428/249921; Y10T428/249924; Y10T428/249928; Y10T428/24994; Y10T428/29; Y10T428/2913
Claims Analysis
Total Claims: 24
Claim 1
Independent Claim
82 words
A composite that comprises a network of interconnected microfibrils of rigid polymer chains that are oriented along the long axis of the microfibrils and constitute one continuous microfibrillar-network-reinforcing phase of the composite, and a solid-matrix material interpenetrated within the three dimensional network and adhered to the microfibrils of the three dimensional microfibrillar chains to constitute a second continuous phase, in which the matrix phase serves to transmit at least one of enhanced shear forces, compression forces and tension forces between the microfibrils.
Claim 2
Dependent Claim
82 words
A composite that comprises a network of interconnected microfibrils of rigid polymer chains that are oriented along the long axis of the microfibrils and constitute one continuous microfibrillar-network-reinforcing phase of the composite, and a solid-matrix material interpenetrated within the three dimensional network and adhered to the microfibrils of the three dimensional microfibrillar chains to constitute a second continuous phase, in which the matrix phase serves to transmit at least one of enhanced shear forces, compression forces and tension forces between the microfibrils.
Claim 3
Dependent Claim
21 words
A composite according to claim 1 in which the matrix material is taken from the group consisting of cross-linkable organic materials.
Claim 4
Dependent Claim
14 words
A composite according to claim 1 in which the matrix material is an inorganic.
Claim 5
Dependent Claim
14 words
A composite according to claim 1 in which the matrix material is a glass.
Claim 6
Dependent Claim
14 words
A composite according to claim 1 in which the matrix material is sodium silicate.
Claim 7
Dependent Claim
36 words
A composite according to claim 1 in which the composite is a fiber and in which the microfibrils are oriented along the long axis of the fiber and constitute one continuous microfibrillar-reinforcing phase of the fiber.
Claim 8
Dependent Claim
18 words
A composite according to claim 1 in which the composite is formed in the form of a mat.
Claim 9
Dependent Claim
34 words
A multilayered composite that comprises a plurality of layer of the mat in claim 7 formed one upon the other and cured, whereby the solid-matrix material serves, upon curing, as a binder between layers.
Claim 10
Dependent Claim
57 words
A composite according to claim 8 in which individual microfibrils have cross-dimensions between about 50 Å and 100 Å, in which adhesion between the microfibrils is about as strong as cohesion within the microfibrils and in which the microfibrils are oriented along the long axis of the composite and constitute one continuous microfibrillar-network-reinforcing phase of the composite.
Claim 11
Dependent Claim
39 words
A composite according to claim 1 in which the polymers that form the microfibrils are taken from the groups consisting of aromatic polyamides; polyhydrazides and polyamide-hydrazides; aromatic-heterocyclic polymers; poly isocyanates; cellulose and its derivatives; polyamino acids and copolymers thereof.
Claim 12
Dependent Claim
80 words
A composite according to claim 10 in which the aromatic polamides are taken from the groups consisting of poly(p-benzamide) (PBA) and poly(p-phenyleneterephthalamide) (PPTA); the aromatic-heterocyclic polymers are taken from the groups consisting of poly(p-phenylene benzobisthiazole) (PBT), poly(p-phenylene benzobisoxazole) (PBO), poly(p-phenylene benzobisimidazole) (PDIAB), poly(2,5(6)benzothiazole) (AB-PBT), and poly(2,5(6)benzimidazole) (AB-PBI); the cellulose and its derivatives is taken from the group consisting of cellulose, cellulose acetate, and hydroxypropyl cellulose; and the polyamino acids are taken from the group consisting of poly(γ-benzyl-L-glutamate), poly(ε-carbobenzoxy-L-Lysine), and poly(L-alanine).
Claim 13
Dependent Claim
52 words
A composite according to claim 1 is which the matrix materials are taken from the group consisting of: organic materials; monomers which can polymerize to a linear polymer; polymers which can infiltrate after coagulation or can be spun together in solution with rigid-chain polymer in a common solvent; and an inorganic material.
Claim 14
Dependent Claim
29 words
A composite according to claim 1 in which adhesion between fibrils of the microfibrils by virtue of the solid-matrix material is about as strong as cohesion between said microfibrils.
Claim 15
Dependent Claim
32 words
A composite according to claim 1 in which the composite is one that effectively utilizes the strength and stiffness characteristics of the microfibrils and in which the solid-matrix material enhances those characteristics.
Claim 16
Dependent Claim
30 words
A composite according to claim 1 in which the individual microfibrils have cross-dimensions no greater than about 100 Å and the composite is a fiber about ten micrometers in diameter.
Claim 17
Dependent Claim
57 words
A composite according to claim 15 in which the individual microfibrils have cross-dimensions between 50 and 100 Å, in which adhesion between the microfibrils is about as strong as cohesion within the microfibrils and in which the microfibrils are oriented along the long axis of the composite and constitute one continuous three-dimensional microfibrillar-network-reinforcing phase of the composite.
Claim 18
Dependent Claim
56 words
A composite according to claim 1 in which the microfibrils of rigid polymer chains denote a polymer which has the ability to form a liquid crystalline phase, either in solution or melt, the reinforcing phase in the composite material being an interconnected network and having a typical width three orders of magnitude smaller than other composites.
Claim 19
Dependent Claim
100 words
A composite that comprises a three-dimensional network of many interconnected microfibrils, that is, the microfibrils are directly connected to other like microfibrils, of rigid polymer chains that are oriented along the long axis of the microfibrils and of the composite and constitute one continuous three-dimensional microfibrillar-network-reinforcing phase of the composite, and a solid-matrix material interpenetrated within the three-dimensional network and adhered to the microfibrils of the microfibrillar chains to constitute a second continuous phase, in which the matrix phase serves to transmit at least one of enhanced shear forced, compression forces and tension forces between the microfibrils of the composite.
Claim 20
Dependent Claim
100 words
A composite that comprises a three-dimensional network of many interconnected microfibrils, that is, the microfibrils are directly connected to other like microfibrils, of rigid polymer chains that are oriented along the long axis of the microfibrils and of the composite and constitute one continuous three-dimensional microfibrillar-network-reinforcing phase of the composite, and a solid-matrix material interpenetrated within the three-dimensional network and adhered to the microfibrils of the microfibrillar chains to constitute a second continuous phase, in which the matrix phase serves to transmit at least one of enhanced shear forced, compression forces and tension forces between the microfibrils of the composite.
Claim 21
Dependent Claim
14 words
A composite according to claim 18 in which said composite is a composite fiber.
Claim 22
Dependent Claim
19 words
A composite according to claim 19 in which said fiber is of the order of ten micrometers in diameter.
Claim 23
Dependent Claim
14 words
A composite according to claim 18 in which said composite is a composite film.
Claim 24
Dependent Claim
18 words
A composite according to claim 21 in which the composite film is the order of ten micrometers thick.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1992-06-26 | 1992-12-26 | 1993-06-27 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1996-06-26 | 1996-12-26 | 1997-06-27 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2000-06-26 | 2000-12-26 | 2001-06-27 | $7700.00 | Window Closed / Lapsed |