Claims Analysis
Total Claims: 25
Claim 1
Independent Claim
419 words
A process for forming electroless copper plating patterns comprising: (a) laminating a substrate with a photocurable laminate, (b) exposing said photocurable laminate to a high energy ray, (c) removing unexposed parts of the laminate, and (d) electrolessly plating a desired part of the laminate with copper; wherein said photocurable laminate comprises a photocurable layer and a film-shaped substrate capable of substantially transmitting high-energy rays, said photocurable layer comprises (a) 100 parts by weight of a compound having recurring units represented by the following formulae [A] and [B] ##STR45## wherein R 0 is a vinyl group, an epoxy group or an episulfide group; R 1 is a hydrogen atom, an alkyl group of 1 to 6 carbon atoms or a halogen atom; and R 1 and R 0 are attached to the position ortho, meta or para to the carbon atom of the main chain; and wherein W, X, Y and Z are each a hydrogen atom, a halogen atom, a cyano group, an alkyl group of 1 to 6 carbon atoms, a halogenated alkyl group of 1 to 6 carbon atoms, an aryl group of 6 to 30 carbon atoms substituted with alkyl or halogenated alkyl groups of 1 to 6 carbon atoms, an aryl group of 6 to 30 carbon atoms substituted with silicon-containing groups, an aryl group of 6 to 30 carbon atoms, --COOR 2 , --COR 2 , --O--COR 2 (R 2 is an alkyl or halogenated alkyl group of 1 to 12 carbon atoms, an aryl group of 6 to 30 carbon atoms substituted with alkyl or halogenated alkyl groups of 1 to 6 carbon atoms, an aryl group of 6 to 30 carbon atoms substituted with silicon-containing groups, or an aryl group of 6 to 30 carbon atoms), a nitro group, a silicon-containing group, or a substituent having heterocyclic rings substituted with at least one R 3 (R 3 is a hydrogen atom, a hydroxyl group, a carboxyl group, a halogen atom, a nitro group, an amino group, a cyano group, an alkyl or halogenated alkyl group of 1 to 6 carbon atoms, an aryl group of 6 to 30 carbon atoms or a silicon-containing group) and (b) 5 to 1,000 parts by weight of a compound, which is compatible with compound (a), having a group represented by the formula --(R.sub.4).sub.n wherein R 4 is a group having a double bond and n is an integer of 1 to 50 and characterized by a viscosity at 20° C. of from 0.001 to 500 poises.
Claim 2
Dependent Claim
419 words
A process for forming electroless copper plating patterns comprising: (a) laminating a substrate with a photocurable laminate, (b) exposing said photocurable laminate to a high energy ray, (c) removing unexposed parts of the laminate, and (d) electrolessly plating a desired part of the laminate with copper; wherein said photocurable laminate comprises a photocurable layer and a film-shaped substrate capable of substantially transmitting high-energy rays, said photocurable layer comprises (a) 100 parts by weight of a compound having recurring units represented by the following formulae [A] and [B] ##STR45## wherein R 0 is a vinyl group, an epoxy group or an episulfide group; R 1 is a hydrogen atom, an alkyl group of 1 to 6 carbon atoms or a halogen atom; and R 1 and R 0 are attached to the position ortho, meta or para to the carbon atom of the main chain; and wherein W, X, Y and Z are each a hydrogen atom, a halogen atom, a cyano group, an alkyl group of 1 to 6 carbon atoms, a halogenated alkyl group of 1 to 6 carbon atoms, an aryl group of 6 to 30 carbon atoms substituted with alkyl or halogenated alkyl groups of 1 to 6 carbon atoms, an aryl group of 6 to 30 carbon atoms substituted with silicon-containing groups, an aryl group of 6 to 30 carbon atoms, --COOR 2 , --COR 2 , --O--COR 2 (R 2 is an alkyl or halogenated alkyl group of 1 to 12 carbon atoms, an aryl group of 6 to 30 carbon atoms substituted with alkyl or halogenated alkyl groups of 1 to 6 carbon atoms, an aryl group of 6 to 30 carbon atoms substituted with silicon-containing groups, or an aryl group of 6 to 30 carbon atoms), a nitro group, a silicon-containing group, or a substituent having heterocyclic rings substituted with at least one R 3 (R 3 is a hydrogen atom, a hydroxyl group, a carboxyl group, a halogen atom, a nitro group, an amino group, a cyano group, an alkyl or halogenated alkyl group of 1 to 6 carbon atoms, an aryl group of 6 to 30 carbon atoms or a silicon-containing group) and (b) 5 to 1,000 parts by weight of a compound, which is compatible with compound (a), having a group represented by the formula --(R.sub.4).sub.n wherein R 4 is a group having a double bond and n is an integer of 1 to 50 and characterized by a viscosity at 20° C. of from 0.001 to 500 poises.
Claim 3
Dependent Claim
40 words
The process for forming electroless copper plating patterns according to claim 1, wherein the film-shaped substrate is polyethylene terephthalate, polyvinyl alcohol, polyvinyl chloride, vinyl chloride copolymer, polymethyl methacrylate, methyl methacrylate copolymer, polystyrene, polyacrylonitrile, styrene copolymer, polyamide or a cellulose derivative.
Claim 4
Dependent Claim
28 words
The process for forming electroless copper plating patterns according to claim 1, wherein the high-energy rays are ultraviolet rays, far-ultraviolet rays, laser beams, soft X-rays or electron beams.
Claim 5
Dependent Claim
24 words
The process for forming electroless copper plating patterns according to claim 3, wherein the high-energy rays are ultraviolet rays, far-ultraviolet rays, or laser beams.
Claim 6
Dependent Claim
24 words
The process for forming electroless copper plating patterns according to claim 1, wherein compound (a) has a number-average molecular weight of 3,000 to 1,000,000.
Claim 7
Dependent Claim
24 words
The process for forming electroless copper plating patterns according to claim 5, wherein compound (a) has a number-average molecular weight of 5,000 to 500,000.
Claim 8
Dependent Claim
19 words
The process for forming electroless copper plating patterns according to claim 1, wherein R 1 is a hydrogen atom.
Claim 9
Dependent Claim
38 words
The process for forming electroless copper plating patterns according to claim 1, wherein R 0 and R 1 of formula [A] are each at a position of meta or para to the carbon atom of the main chain.
Claim 10
Dependent Claim
22 words
The process for forming electroless copper plating patterns according to claim 8, wherein R 0 of formula [A] is a vinyl group.
Claim 11
Dependent Claim
22 words
The process for forming electroless copper plating patterns according to claim 1, wherein the W of formula [B] is a hydrogen atom.
Claim 12
Dependent Claim
228 words
The process for forming electroless copper plating patterns according to claim 10, wherein the X, Y and Z of formula [B] are each a hydrogen atom, a cyano group, an alkyl group of 1 to 6 carbon atoms, a halogenated alkyl group of 1 to 6 carbon atoms, an aryl group of 6 to 30 carbon atoms substituted with alkyl or halogenated alkyl groups of 1 to 6 carbon atoms, an aryl group of 6 to 30 carbon atoms substituted with silicon-containing groups, an aryl group of 6 to 30 carbon atoms, --COOR 2 , --COR 2 , --O--COR 2 (R 2 is an alkyl or halogenated alkyl group of 1 to 12 carbon atoms, an aryl group of 6 to 30 carbon atoms substituted with alkyl or halogenated alkyl groups of 1 to 6 carbon atoms, an aryl group of 6 to 30 carbon atoms substituted with silicon-containing groups or an aryl group of 6 to 30 carbon atoms), a nitro group, a silicon-containing group or a substituent having heterocyclic rings substituted with at least one R 3 (R 3 is a hydrogen atom, a hydroxyl group, a carboxyl group, a halogen atom, a nitro group, an amino group, a cyano group, an alkyl or halogenated alkyl group of 1 to 6 carbon atoms, an aryl group of 6 to 30 carbon atoms or a silicon-containing group).
Claim 13
Dependent Claim
150 words
The process for forming electroless copper plating patterns according to claim 10, wherein the X, Y and Z of formula [B] are each a hydrogen atom, a halogen atom, a cyano group, an alkyl group of 1 to 6 carbon atoms, a halogenated alkyl group of 1 to 6 carbon atoms, an aryl group of 6 to 30 carbon atoms substituted with alkyl or halogenated alkyl groups of 1 to 6 carbon atoms, an aryl group of 6 to 30 carbon atoms substituted with silicon-containing groups, an aryl group of 6 to 30 carbon atoms, a nitro group, silicon-containing group, or a substituent having heterocyclic rings substituted with at least one R 3 (R 3 is a hydrogen atom, a halogen atom, a cyano group, an alkyl or halogenated alkyl group of 1 to 6 carbon atoms, an aryl group of 6 to 30 carbon atoms, or a silicon-containing group).
Claim 14
Dependent Claim
31 words
The process for forming electroless copper plating patterns according to claim 1, wherein the mol fraction of the recurring unit represented by formula [A], of compound (a) is 1 to 99%.
Claim 15
Dependent Claim
31 words
The process for forming electroless copper plating patterns according to claim 13, wherein the mol fraction of the recurring unit represented by formula [A], of compound (a) is 5 to 95%.
Claim 16
Dependent Claim
28 words
The process for forming electroless copper plating patterns according to claim 1, wherein R 4 of compound (b) is one of the groups represented by the formulae ##STR46##
Claim 17
Dependent Claim
34 words
The process for forming electroless copper plating patterns according to claim 1, wherein the amount of compound (b) is 10 to 800 parts by weight based on 100 parts by weight of compound (a).
Claim 18
Dependent Claim
38 words
The process for forming electroless copper plating patterns according to claim 1, wherein said photocurable laminate contains up to 50 parts by weight based on 100 parts by weight of compound (a) of a photopolymerization initiator or photosensitizer.
Claim 19
Dependent Claim
38 words
The process for forming electroless copper plating patterns according to claim 1, wherein said photocurable laminate contains 0.01 to 30 parts by weight based on 100 parts by weight of compound (a) of a photopolymerization initiator or photosensitizer.
Claim 20
Dependent Claim
51 words
The process for forming electroless copper plating patterns according to claim 1, wherein said photocurable layer contains up to 1,000 parts by weight based on 100 parts by weight of compound (a) of compound (c), in which compound (c) is a thermoplastic resin which is compatible with compounds (a) and (b).
Claim 21
Dependent Claim
38 words
The process for forming electroless copper plating patterns according to claim 19, wherein said thermoplastic resin is polymethyl methacrylate, methyl methacrylate copolymer, polystyrene, styrene copolymer, polyvinyl chloride, vinyl chloride copolymer, polyvinyl acetate, vinyl acetate copolymer or polyvinyl alcohol.
Claim 22
Dependent Claim
32 words
The process for forming electroless copper plating patterns according to claim 1, wherein said photocurable laminate further contains an additive, said additive comprising a dye, a stabilizer, a plasticizer or mixtures thereof.
Claim 23
Dependent Claim
26 words
The process for forming electroless copper plating patterns according to claim 1, wherein a plastic protective film is disposed on the surface of the photocurable layer.
Claim 24
Dependent Claim
29 words
The process for forming electroless copper plating patterns according to claim 22, wherein the plastic protective film is a polyethylene terephthalate film, a polypropylene film or a polyethylene film.
Claim 25
Dependent Claim
21 words
The process for forming electroless copper plating patterns according to claim 1, wherein the substrate is a copper-clad, glass-epoxy laminated sheet.