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US4839261A Expired / Lapsed US ⏱️ 0.0 years remaining

Photocurable laminate

Assignee: Asahi Kasei Corp
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Filing: 1987-09-15
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Granted: 1989-06-13
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Expires: 2007-09-15
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Abstract

Abstract A process for forming electroless copper plating patterns comprising: (a) laminating a substrate with a photocurable laminate, (b) exposing said photocurable laminate to a high energy ray, (c) removing unexposed parts of the laminate, and (d) electrolessly plating a desired pat of the laminate with copper; wherein said photocurable layer comprises (a) 100 parts by weight of a compound having recurring units represented by the following formulae [A] and [B] ##STR1## and (b) 5 to 1,000 parts by weight of a compound, which is compatible with compound (a), having a group represented by the formula --(R.sub.4).sub.n wherein R 4 is a group having a double bond and n is an integer of 1 to 50 and characterized by a viscosity at 20° C. of from 0.001 to 500 poises.

Inventors

  • 👤 Nobuo Nakazaki
  • 👤 Hideo Ai
  • 👤 Manabu Miyao

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-01 17:17
CPC Classifications
H; H05; H05K; H05K3/00; G; G03; G03F; G03F7/00; G03F7/004; G03F7/027; G03F7/032; G03F7/033; G03F7/26; G03F7/38

Claims Analysis

Total Claims: 25
Claim 1
Independent Claim 419 words
A process for forming electroless copper plating patterns comprising: (a) laminating a substrate with a photocurable laminate, (b) exposing said photocurable laminate to a high energy ray, (c) removing unexposed parts of the laminate, and (d) electrolessly plating a desired part of the laminate with copper; wherein said photocurable laminate comprises a photocurable layer and a film-shaped substrate capable of substantially transmitting high-energy rays, said photocurable layer comprises (a) 100 parts by weight of a compound having recurring units represented by the following formulae [A] and [B] ##STR45## wherein R 0 is a vinyl group, an epoxy group or an episulfide group; R 1 is a hydrogen atom, an alkyl group of 1 to 6 carbon atoms or a halogen atom; and R 1 and R 0 are attached to the position ortho, meta or para to the carbon atom of the main chain; and wherein W, X, Y and Z are each a hydrogen atom, a halogen atom, a cyano group, an alkyl group of 1 to 6 carbon atoms, a halogenated alkyl group of 1 to 6 carbon atoms, an aryl group of 6 to 30 carbon atoms substituted with alkyl or halogenated alkyl groups of 1 to 6 carbon atoms, an aryl group of 6 to 30 carbon atoms substituted with silicon-containing groups, an aryl group of 6 to 30 carbon atoms, --COOR 2 , --COR 2 , --O--COR 2 (R 2 is an alkyl or halogenated alkyl group of 1 to 12 carbon atoms, an aryl group of 6 to 30 carbon atoms substituted with alkyl or halogenated alkyl groups of 1 to 6 carbon atoms, an aryl group of 6 to 30 carbon atoms substituted with silicon-containing groups, or an aryl group of 6 to 30 carbon atoms), a nitro group, a silicon-containing group, or a substituent having heterocyclic rings substituted with at least one R 3 (R 3 is a hydrogen atom, a hydroxyl group, a carboxyl group, a halogen atom, a nitro group, an amino group, a cyano group, an alkyl or halogenated alkyl group of 1 to 6 carbon atoms, an aryl group of 6 to 30 carbon atoms or a silicon-containing group) and (b) 5 to 1,000 parts by weight of a compound, which is compatible with compound (a), having a group represented by the formula --(R.sub.4).sub.n wherein R 4 is a group having a double bond and n is an integer of 1 to 50 and characterized by a viscosity at 20° C. of from 0.001 to 500 poises.
Claim 2
Dependent Claim 419 words
A process for forming electroless copper plating patterns comprising: (a) laminating a substrate with a photocurable laminate, (b) exposing said photocurable laminate to a high energy ray, (c) removing unexposed parts of the laminate, and (d) electrolessly plating a desired part of the laminate with copper; wherein said photocurable laminate comprises a photocurable layer and a film-shaped substrate capable of substantially transmitting high-energy rays, said photocurable layer comprises (a) 100 parts by weight of a compound having recurring units represented by the following formulae [A] and [B] ##STR45## wherein R 0 is a vinyl group, an epoxy group or an episulfide group; R 1 is a hydrogen atom, an alkyl group of 1 to 6 carbon atoms or a halogen atom; and R 1 and R 0 are attached to the position ortho, meta or para to the carbon atom of the main chain; and wherein W, X, Y and Z are each a hydrogen atom, a halogen atom, a cyano group, an alkyl group of 1 to 6 carbon atoms, a halogenated alkyl group of 1 to 6 carbon atoms, an aryl group of 6 to 30 carbon atoms substituted with alkyl or halogenated alkyl groups of 1 to 6 carbon atoms, an aryl group of 6 to 30 carbon atoms substituted with silicon-containing groups, an aryl group of 6 to 30 carbon atoms, --COOR 2 , --COR 2 , --O--COR 2 (R 2 is an alkyl or halogenated alkyl group of 1 to 12 carbon atoms, an aryl group of 6 to 30 carbon atoms substituted with alkyl or halogenated alkyl groups of 1 to 6 carbon atoms, an aryl group of 6 to 30 carbon atoms substituted with silicon-containing groups, or an aryl group of 6 to 30 carbon atoms), a nitro group, a silicon-containing group, or a substituent having heterocyclic rings substituted with at least one R 3 (R 3 is a hydrogen atom, a hydroxyl group, a carboxyl group, a halogen atom, a nitro group, an amino group, a cyano group, an alkyl or halogenated alkyl group of 1 to 6 carbon atoms, an aryl group of 6 to 30 carbon atoms or a silicon-containing group) and (b) 5 to 1,000 parts by weight of a compound, which is compatible with compound (a), having a group represented by the formula --(R.sub.4).sub.n wherein R 4 is a group having a double bond and n is an integer of 1 to 50 and characterized by a viscosity at 20° C. of from 0.001 to 500 poises.
Claim 3
Dependent Claim 40 words
The process for forming electroless copper plating patterns according to claim 1, wherein the film-shaped substrate is polyethylene terephthalate, polyvinyl alcohol, polyvinyl chloride, vinyl chloride copolymer, polymethyl methacrylate, methyl methacrylate copolymer, polystyrene, polyacrylonitrile, styrene copolymer, polyamide or a cellulose derivative.
Claim 4
Dependent Claim 28 words
The process for forming electroless copper plating patterns according to claim 1, wherein the high-energy rays are ultraviolet rays, far-ultraviolet rays, laser beams, soft X-rays or electron beams.
Claim 5
Dependent Claim 24 words
The process for forming electroless copper plating patterns according to claim 3, wherein the high-energy rays are ultraviolet rays, far-ultraviolet rays, or laser beams.
Claim 6
Dependent Claim 24 words
The process for forming electroless copper plating patterns according to claim 1, wherein compound (a) has a number-average molecular weight of 3,000 to 1,000,000.
Claim 7
Dependent Claim 24 words
The process for forming electroless copper plating patterns according to claim 5, wherein compound (a) has a number-average molecular weight of 5,000 to 500,000.
Claim 8
Dependent Claim 19 words
The process for forming electroless copper plating patterns according to claim 1, wherein R 1 is a hydrogen atom.
Claim 9
Dependent Claim 38 words
The process for forming electroless copper plating patterns according to claim 1, wherein R 0 and R 1 of formula [A] are each at a position of meta or para to the carbon atom of the main chain.
Claim 10
Dependent Claim 22 words
The process for forming electroless copper plating patterns according to claim 8, wherein R 0 of formula [A] is a vinyl group.
Claim 11
Dependent Claim 22 words
The process for forming electroless copper plating patterns according to claim 1, wherein the W of formula [B] is a hydrogen atom.
Claim 12
Dependent Claim 228 words
The process for forming electroless copper plating patterns according to claim 10, wherein the X, Y and Z of formula [B] are each a hydrogen atom, a cyano group, an alkyl group of 1 to 6 carbon atoms, a halogenated alkyl group of 1 to 6 carbon atoms, an aryl group of 6 to 30 carbon atoms substituted with alkyl or halogenated alkyl groups of 1 to 6 carbon atoms, an aryl group of 6 to 30 carbon atoms substituted with silicon-containing groups, an aryl group of 6 to 30 carbon atoms, --COOR 2 , --COR 2 , --O--COR 2 (R 2 is an alkyl or halogenated alkyl group of 1 to 12 carbon atoms, an aryl group of 6 to 30 carbon atoms substituted with alkyl or halogenated alkyl groups of 1 to 6 carbon atoms, an aryl group of 6 to 30 carbon atoms substituted with silicon-containing groups or an aryl group of 6 to 30 carbon atoms), a nitro group, a silicon-containing group or a substituent having heterocyclic rings substituted with at least one R 3 (R 3 is a hydrogen atom, a hydroxyl group, a carboxyl group, a halogen atom, a nitro group, an amino group, a cyano group, an alkyl or halogenated alkyl group of 1 to 6 carbon atoms, an aryl group of 6 to 30 carbon atoms or a silicon-containing group).
Claim 13
Dependent Claim 150 words
The process for forming electroless copper plating patterns according to claim 10, wherein the X, Y and Z of formula [B] are each a hydrogen atom, a halogen atom, a cyano group, an alkyl group of 1 to 6 carbon atoms, a halogenated alkyl group of 1 to 6 carbon atoms, an aryl group of 6 to 30 carbon atoms substituted with alkyl or halogenated alkyl groups of 1 to 6 carbon atoms, an aryl group of 6 to 30 carbon atoms substituted with silicon-containing groups, an aryl group of 6 to 30 carbon atoms, a nitro group, silicon-containing group, or a substituent having heterocyclic rings substituted with at least one R 3 (R 3 is a hydrogen atom, a halogen atom, a cyano group, an alkyl or halogenated alkyl group of 1 to 6 carbon atoms, an aryl group of 6 to 30 carbon atoms, or a silicon-containing group).
Claim 14
Dependent Claim 31 words
The process for forming electroless copper plating patterns according to claim 1, wherein the mol fraction of the recurring unit represented by formula [A], of compound (a) is 1 to 99%.
Claim 15
Dependent Claim 31 words
The process for forming electroless copper plating patterns according to claim 13, wherein the mol fraction of the recurring unit represented by formula [A], of compound (a) is 5 to 95%.
Claim 16
Dependent Claim 28 words
The process for forming electroless copper plating patterns according to claim 1, wherein R 4 of compound (b) is one of the groups represented by the formulae ##STR46##
Claim 17
Dependent Claim 34 words
The process for forming electroless copper plating patterns according to claim 1, wherein the amount of compound (b) is 10 to 800 parts by weight based on 100 parts by weight of compound (a).
Claim 18
Dependent Claim 38 words
The process for forming electroless copper plating patterns according to claim 1, wherein said photocurable laminate contains up to 50 parts by weight based on 100 parts by weight of compound (a) of a photopolymerization initiator or photosensitizer.
Claim 19
Dependent Claim 38 words
The process for forming electroless copper plating patterns according to claim 1, wherein said photocurable laminate contains 0.01 to 30 parts by weight based on 100 parts by weight of compound (a) of a photopolymerization initiator or photosensitizer.
Claim 20
Dependent Claim 51 words
The process for forming electroless copper plating patterns according to claim 1, wherein said photocurable layer contains up to 1,000 parts by weight based on 100 parts by weight of compound (a) of compound (c), in which compound (c) is a thermoplastic resin which is compatible with compounds (a) and (b).
Claim 21
Dependent Claim 38 words
The process for forming electroless copper plating patterns according to claim 19, wherein said thermoplastic resin is polymethyl methacrylate, methyl methacrylate copolymer, polystyrene, styrene copolymer, polyvinyl chloride, vinyl chloride copolymer, polyvinyl acetate, vinyl acetate copolymer or polyvinyl alcohol.
Claim 22
Dependent Claim 32 words
The process for forming electroless copper plating patterns according to claim 1, wherein said photocurable laminate further contains an additive, said additive comprising a dye, a stabilizer, a plasticizer or mixtures thereof.
Claim 23
Dependent Claim 26 words
The process for forming electroless copper plating patterns according to claim 1, wherein a plastic protective film is disposed on the surface of the photocurable layer.
Claim 24
Dependent Claim 29 words
The process for forming electroless copper plating patterns according to claim 22, wherein the plastic protective film is a polyethylene terephthalate film, a polypropylene film or a polyethylene film.
Claim 25
Dependent Claim 21 words
The process for forming electroless copper plating patterns according to claim 1, wherein the substrate is a copper-clad, glass-epoxy laminated sheet.

References Cited (Backward Citations)

JPS5620077A Cited
JPS56165141A Cited
US4378264A Cited
JPS5896525A Cited
US4528332A Cited
JPS60134233A Cited
GB2163435A Cited
JPS6131409A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1992-06-12 1992-12-12 1993-06-13 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1996-06-12 1996-12-12 1997-06-13 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2000-06-12 2000-12-12 2001-06-13 $7700.00 Window Closed / Lapsed

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