Patent US4830940A successfully refreshed from Google Patents.
US4830940A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Non-agueous lithium battery
Assignee: Greatbatch Ltd
•
Filing: 1986-01-14
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Granted: 1989-05-16
•
Expires: 2006-01-14
Abstract
Abstract A solid cathode liquid organic electrolyte lithium cell for delivering high current pulses comprising a casing, a cathode structure inthe casing comprising a plurality of plates in spaced apart relation, a lithium anond comprising a plurality of anode sections interposed between the cathode plates, a non-aqueous liquid organic electrolyte comprising the combination of a lithum dalt and an organic solvent in the casing operatively contacting the anode and the cathode an electrical connection provided to the anode and an electrical connection provided to the cathode. In accordance with one aspect of the invention the cathode includes as active material Ag x V 2 O y where x is in the range from about 0.5 to about 2.0 and y is in the range from about 4.5 to about 6.0 which advantageously has high volumetric capacity and high rate capability with the result that the cell of the present invention delivers high capacity, shows good current pulsing behavior at various levels of discharge, and has a sloping discharge cause enabling end of life to be predicted. In accordance with another aspect of the present invention, the anode comprises a continuous elongated lithium element enclosed within a separator and folded into a plurality of sections interposed between the cathode plates, each of which individually is enclosed within separator material thereby enhancing the reliability of the cell. The cell of the present invention finds advantageous use as a power source for an implantable cardiac defibrillator.
Inventors
- 👤 Pamela P. Keister
- 👤 Ralph T. Mead
- 👤 Barry C. Muffoletto
- 👤 Ester S. Takeuchi
- 👤 Steven J. Ebel
- 👤 Michael A. Zelinsky
- 👤 John M. Greenwood
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-29 13:31
CPC Classifications
H; H01; H01M; H01M4/00; H01M4/02; H01M4/36; H01M4/48; H01M4/54; A; A61; A61N; A61N1/00; A61N1/18; A61N1/32; A61N1/36; A61N1/372; A61N1/378; H01M10/00; H01M10/04; H01M10/0413; H01M10/045; H01M10/0454; H01M4/06; H01M4/08; H01M4/12; H01M4/483; H01M50/00; H01M50/10; H01M50/172; H01M50/174; H01M50/176; H01M50/50; H01M50/531; H01M50/538; H01M50/54; H01M6/00; H01M6/04; H01M6/06; H01M6/10; H01M6/103; H01M6/14; H01M6/16; A61N1/375; A61N1/3758; H01M50/102; H01M50/103; H01M50/30
Claims Analysis
Total Claims: 59
Claim 1
Independent Claim
174 words
A solid cathode liquid organic electrolyte alkali metal primary cell for delivering high current pulses comprising: (a) a casing: (b) cathode means in said casing comprising a plurality of plates in spaced apart relation, said cathode means including as active material Ag x V 2 O y where x is in the range from about 0.5 to about 2.0 and y is in the range from about 4.5 to about 6.0 so as to have high volumetric capacity and high rate capability; (c) alkali metal anode means comprising a plurality of anode sections interposed between said cathode plates; (d) a non-aqueous electrolyte in said casing operatively contacting said anode means and said cathode means; (e) means for providing electrical connection to said anode means; and (f) means for providing electrical connection to said cathode means; (g) said cathode means, anode means and electrolyte co-operating to enable said cell to deliver high current pulses and rapidly recover the cell open circuit voltage and to enable said cell to have high capacity and low self discharge.
Claim 2
Dependent Claim
174 words
A solid cathode liquid organic electrolyte alkali metal primary cell for delivering high current pulses comprising: (a) a casing: (b) cathode means in said casing comprising a plurality of plates in spaced apart relation, said cathode means including as active material Ag x V 2 O y where x is in the range from about 0.5 to about 2.0 and y is in the range from about 4.5 to about 6.0 so as to have high volumetric capacity and high rate capability; (c) alkali metal anode means comprising a plurality of anode sections interposed between said cathode plates; (d) a non-aqueous electrolyte in said casing operatively contacting said anode means and said cathode means; (e) means for providing electrical connection to said anode means; and (f) means for providing electrical connection to said cathode means; (g) said cathode means, anode means and electrolyte co-operating to enable said cell to deliver high current pulses and rapidly recover the cell open circuit voltage and to enable said cell to have high capacity and low self discharge.
Claim 3
Dependent Claim
44 words
A cell according to claim 1, wherein said cathode means includes as active material Ag x V 2 O y where x is in the range from about 0.95 to about 1.1 and y is in the range from about 5.0 to about 6.0.
Claim 4
Dependent Claim
13 words
A cell according to claim 1, wherein said anode means is of lithium.
Claim 5
Dependent Claim
47 words
A cell according to claim 1, wherein each of said cathode plates comprises a cathode conductor including a body portion and a lead portion extending therefrom, a cathode mixture pressed onto said conductor body portion in the form of a pellet and including said cathode active material.
Claim 6
Dependent Claim
23 words
A cell according to claim 4, where said cathode pellet further comprises a binder and conductors including graphite powder and acetylene black power.
Claim 7
Dependent Claim
28 words
A cell according to claim 4, wherein said cathode mixture includes an additive selected from the group consisting of lithium salts, lithium ion conducting electrolyte and solid surfactant.
Claim 8
Dependent Claim
17 words
A cell according to claim 4, wherein said pellet is enclosed in an envelope of separator material.
Claim 9
Dependent Claim
27 words
A cell according to claim 1, wherein said anode means comprises a continuous elongated lithium element enclosed within separator material and folded into said plurality of sections.
Claim 10
Dependent Claim
77 words
A cell according to claim 1, wherein said anode means comprises: (a) an enlongated ribbon-like anode conductor element. (b) a pair of elongated ribbon-like lithium elements pressed together against opposite sides of said conductor element to form an anode structure; (c) separator material encapsulating said anode structure; and (d) said anode structure being folded at spaced intervals along the length thereof to form a sepentine-like structure to receive between the folds thereof said plurality of cathode plates.
Claim 11
Dependent Claim
19 words
A cell according to claim 9, wherein said anode conductor element includes at least one terminal tab extending therefrom.
Claim 12
Dependent Claim
25 words
A cell according to claim 10, wherein said casing is of electrically conductive material and wherein said terminal tab is electrically connected to said casing.
Claim 13
Dependent Claim
13 words
A cell according to claim 1, wherein said electrolyte is an organic liquid.
Claim 14
Dependent Claim
20 words
A cell according to claim 1, wherein said electroyte is a combination of a lithium salt and an organic solvent.
Claim 15
Dependent Claim
25 words
A cell according to claim 1, wherein said casing means is of electrically conductive material and said anode means is electrically connected to said casing.
Claim 16
Dependent Claim
34 words
A cell according to claim 14, wherein said means for providing electrical connection to said cathode means comprises conductor means electrically connnected to said cathode means extending through said casing and electrically insulated therefrom.
Claim 17
Dependent Claim
24 words
A cell according to claim 1, wherein said casing is of electrically conductive material and said cathode means is electrically connected to said casing.
Claim 18
Dependent Claim
34 words
A cell according to claim 15 wherein said means for providing electrical connection to said anode means comprises conductor means electrically connected to said anode means extending through said casing and electrically insulated therefrom.
Claim 19
Dependent Claim
13 words
A cell according to claim 1, in combination with an implantable cardiac defibrillator.
Claim 20
Dependent Claim
24 words
A cell according to claim 1, wherein said anode means comprises a plurality of plates defining said anode sections interposed between said cathode plates.
Claim 21
Dependent Claim
137 words
A solid cathode liquid electrolyte alkali metal primary cell for delivering high current pulses comprising: (a) a casing of electrically conductive material; (b) cathode means in said casing comprising a plurality of plates of cathode active material in spaced apart relation, each of said plates including conductor means extending therefrom; (c) anode means comprising a continuous elongated alkali metal element enclosed within a separator and folded into a plurality of sections interposed between said cathode plates, said anode means comprising anode conductor means extending therefrom; (d) a non-aqueous electrolyte in said casing operatively contacting said anode means and said cathode means; (e) means for connecting said anode conductor means to said casing; (f) conductor means electrically connected to said cathode means extending through said casing; and (g) means for electrically insulating said conductor means from said casing.
Claim 22
Dependent Claim
137 words
A solid cathode liquid electrolyte alkali metal primary cell for delivering high current pulses comprising: (a) a casing of electrically conductive material; (b) cathode means in said casing comprising a plurality of plates of cathode active material in spaced apart relation, each of said plates including conductor means extending therefrom; (c) anode means comprising a continuous elongated alkali metal element enclosed within a separator and folded into a plurality of sections interposed between said cathode plates, said anode means comprising anode conductor means extending therefrom; (d) a non-aqueous electrolyte in said casing operatively contacting said anode means and said cathode means; (e) means for connecting said anode conductor means to said casing; (f) conductor means electrically connected to said cathode means extending through said casing; and (g) means for electrically insulating said conductor means from said casing.
Claim 23
Dependent Claim
20 words
A cell according to claim 20, wherein each of said cathode plates is enclosed in an envelope of separator material.
Claim 24
Dependent Claim
44 words
A cell according to claim 20, wherein said cathode means includes as active material Ag x V 2 O y where x is in the range from about 0.5 to about 2.0 and y is in the range from about 4.5 to about 6.0.
Claim 25
Dependent Claim
50 words
A cell according to claim 22, wherein each of said cathode conductor means comprises a body portion and a lead portion and wherein each of said cathode plates comprises a cathode mixture pressed onto said conductor body portion in the form of a pellet and including said cathode active material.
Claim 26
Dependent Claim
23 words
A cell according to claim 23, wherein said cathode pellet further comprises a binder and conductors including graphite powder and acetylene black powder.
Claim 27
Dependent Claim
17 words
A cell according to claim 23, wherein said pellet is enclosed in an envelope of separator material.
Claim 28
Dependent Claim
78 words
A cell according to claim 20, wherein said lithium anode means comprises: (a) an elongated ribbon-like anode conductor element; (b) a pair of elongated ribbon-like lithium elements pressed together against opposite sides of said conductor element to form an anode structure; (c) separator material encapsulating said anode structure; and (d) said anode structure being folded at spaced intervals along the length thereof to form a serpentine-like structure to receive between the folds thereof said plurality of cathode plates.
Claim 29
Dependent Claim
24 words
A cell according to claim 26, wherein anode conductor means includes at least one terminal tab extending therefrom and electrically connected to said casing.
Claim 30
Dependent Claim
13 words
A cell according to claim 20, wherein said electrolyte is an organic liquid.
Claim 31
Dependent Claim
19 words
A cell according to claim 28, wherein said electrolyte is a combination of lithuim salt and an organic solvent.
Claim 32
Dependent Claim
131 words
A cathode for an alkali metal non-aqueous silver vanadium oxide primary cell for delivering successive high current pulses and rapidly recovering the cell open circuit voltage and including a plurality of cathode components in spaced relation and adapted to be interposed between a plurality of anode sections, each of said cathode components comprising a cathode conductor including a body portion and a lead portion extending therefrom, a cathode mixture pressed onto said conductor body portion in the form of a pellet and including cathode active material, said cathode active material comprising Ag x V 2 O y where x is in the range from about 0.5 to about 2.0 and y is in the range from about 4.5 to about 6.0, said material having high volumetric capacity and high rate capability.
Claim 33
Dependent Claim
131 words
A cathode for an alkali metal non-aqueous silver vanadium oxide primary cell for delivering successive high current pulses and rapidly recovering the cell open circuit voltage and including a plurality of cathode components in spaced relation and adapted to be interposed between a plurality of anode sections, each of said cathode components comprising a cathode conductor including a body portion and a lead portion extending therefrom, a cathode mixture pressed onto said conductor body portion in the form of a pellet and including cathode active material, said cathode active material comprising Ag x V 2 O y where x is in the range from about 0.5 to about 2.0 and y is in the range from about 4.5 to about 6.0, said material having high volumetric capacity and high rate capability.
Claim 34
Dependent Claim
30 words
A cathode according to claim 30, wherein x is in the range from about 0.95 to about 1.1 and y is in the range from about 5.0 to about 6.0.
Claim 35
Dependent Claim
22 words
A cathode according to claim 30, wherein said cathode mixture further includes binder and conductors including graphite powder and acetylene black powder.
Claim 36
Dependent Claim
28 words
A cathode according to claim 30, wherein said cathode mixture contains an additive selected from the group consisting of lithium salts, solid lithium ion conducting electrolyte and surfactant.
Claim 37
Dependent Claim
17 words
A cathode according to claim 30, wherein said pellet is enclosed in an envelope of separator material.
Claim 38
Dependent Claim
122 words
An anode for a solid cathode non-aqueous liquid electrolyte alkali metal primary cell for delivering successive high current pulses and rapidly recovering the cell open circuit voltage, said anode comprising: (a) an alongated ribbon-like anode conductor element; (b) a pair of elongated ribbon-like alkali metal elements pressed together against opposite sides of said conductor element to form an anode structure; (c) separator material encapsulating said anode structure, said separator material being in the form of a sheet pressed on said anode structure and heat sealed around the edges thereof; and (d) said anode structure being folded at spaced intervals along the length thereof to form a serpentine-like structure to receive between the folds thereof a plurality of cathode elements of the cell.
Claim 39
Dependent Claim
122 words
An anode for a solid cathode non-aqueous liquid electrolyte alkali metal primary cell for delivering successive high current pulses and rapidly recovering the cell open circuit voltage, said anode comprising: (a) an alongated ribbon-like anode conductor element; (b) a pair of elongated ribbon-like alkali metal elements pressed together against opposite sides of said conductor element to form an anode structure; (c) separator material encapsulating said anode structure, said separator material being in the form of a sheet pressed on said anode structure and heat sealed around the edges thereof; and (d) said anode structure being folded at spaced intervals along the length thereof to form a serpentine-like structure to receive between the folds thereof a plurality of cathode elements of the cell.
Claim 40
Dependent Claim
14 words
An anode according to claim 35, wherein said alkali metal elements are of lithium.
Claim 41
Dependent Claim
15 words
An anode according to claim 35, further including at least on terminal tab extending therefrom.
Claim 42
Dependent Claim
173 words
A solid cathode liquid electrolyte alkali metal primary cell for delivering high current pulses comprising: (a) a casing; (b) cathode means in said casing comprising a plurality of plates in spaced apart relation, each of said plates comprising cathode active material enclosed within separator material and each of said plates including conductor means extending therefrom, said separator material being in the form of a sheet pressed on said plate and heat sealed around the edges thereof; (c) anode means comprising a continuous elongated alkali metal element enclosed with separator material and folded into a plurality of sections interposed between said cathode plates, said separator material being in the form of a sheet pressed on said element and heat sealed around the edges thereof, said anode means comprising anode conductor means extending therefrom; (d) a non-aqueous electrolyte in said casing operatively contacting said anode means and said cathode means; (e) means for providing electrical connection to each of said cathode conductor means; and (f) means for providing electrical connection to said anode conductor means.
Claim 43
Dependent Claim
173 words
A solid cathode liquid electrolyte alkali metal primary cell for delivering high current pulses comprising: (a) a casing; (b) cathode means in said casing comprising a plurality of plates in spaced apart relation, each of said plates comprising cathode active material enclosed within separator material and each of said plates including conductor means extending therefrom, said separator material being in the form of a sheet pressed on said plate and heat sealed around the edges thereof; (c) anode means comprising a continuous elongated alkali metal element enclosed with separator material and folded into a plurality of sections interposed between said cathode plates, said separator material being in the form of a sheet pressed on said element and heat sealed around the edges thereof, said anode means comprising anode conductor means extending therefrom; (d) a non-aqueous electrolyte in said casing operatively contacting said anode means and said cathode means; (e) means for providing electrical connection to each of said cathode conductor means; and (f) means for providing electrical connection to said anode conductor means.
Claim 44
Dependent Claim
12 words
A cell according to claim 38, wherein anode means is of lithium.
Claim 45
Dependent Claim
24 words
A cell according to claim 38, wherein said casing is of electrically conductive material and said anode means is electrically connected to said casing.
Claim 46
Dependent Claim
36 words
A cell according to claim 40, wherein said means for providing electrical connection to said cathode conductor means comprises conductor means electrically connected to said cathode conductor means extending through said casing and electrically insulated therefrom.
Claim 47
Dependent Claim
25 words
A cell according to claim 38, wherein said casing is of electrically conductive material and said cathode conductor means is electrically connected to said casing.
Claim 48
Dependent Claim
36 words
A cell according to claim 42, wherein said means for providing electrical connection to said anode conductor means comprises conductor means electrically connected to said anode conductor means extending through said casing and electrically insulated therefrom.
Claim 49
Dependent Claim
121 words
A solide state cathode liquid electrolyte alkali metal primary cell for delivering high current pulses comprising: (a) a casing (b) cathode means in said casing comprising a plurality of interconnected cathode sections in a chain-like arrangement; (c) alkali metal anode means comprising a continuous elongated structure foldable into a plurality of sections; (d) said cathode means and anode means being folded together in a manner providing an arrangement whereby said anode means is folded into a plurality of sections interposed between said cathode sections; (e) a non-aqueous electrolyte in said casing operatively contacting said anode means and said cathode means; (f) means for providing electrical connection to said anode means; and (g) means for providing electrical connection to said cathode means.
Claim 50
Dependent Claim
121 words
A solide state cathode liquid electrolyte alkali metal primary cell for delivering high current pulses comprising: (a) a casing (b) cathode means in said casing comprising a plurality of interconnected cathode sections in a chain-like arrangement; (c) alkali metal anode means comprising a continuous elongated structure foldable into a plurality of sections; (d) said cathode means and anode means being folded together in a manner providing an arrangement whereby said anode means is folded into a plurality of sections interposed between said cathode sections; (e) a non-aqueous electrolyte in said casing operatively contacting said anode means and said cathode means; (f) means for providing electrical connection to said anode means; and (g) means for providing electrical connection to said cathode means.
Claim 51
Dependent Claim
44 words
A cathode for a solid cathode non-aqueous liquid electrolyte alkali metal primary cell comprising: (a) a conductor comprising a plurality of individual sections joined to end-to-end relation; and (b) a corresponding plurality of individual pellets of cathode active material pressed onto said conductor sections.
Claim 52
Dependent Claim
44 words
A cathode for a solid cathode non-aqueous liquid electrolyte alkali metal primary cell comprising: (a) a conductor comprising a plurality of individual sections joined to end-to-end relation; and (b) a corresponding plurality of individual pellets of cathode active material pressed onto said conductor sections.
Claim 53
Dependent Claim
13 words
A cathode according to claim 45, further including separator material encapsulating said pellets.
Claim 54
Dependent Claim
99 words
A solid cathode non-aqueous liquid electrolyte alkali metal primary cell for delivering high current pulses comprising: (a) a casing (b) cathode means in said casing comprising a continuous elongated body comprising cathode active material and a conductor therein, said body folded into a plurality of sections; (c) alkali metal anode means comprising a plurality of anode sections interposed between said cathode sections; (d) a non-queous electrolyte in said casing operatively contacting said anode means and said cathode means; (e) means for providing electrical connection to said anode means; and (f) means for providing electrical connection to said cathode means.
Claim 55
Dependent Claim
99 words
A solid cathode non-aqueous liquid electrolyte alkali metal primary cell for delivering high current pulses comprising: (a) a casing (b) cathode means in said casing comprising a continuous elongated body comprising cathode active material and a conductor therein, said body folded into a plurality of sections; (c) alkali metal anode means comprising a plurality of anode sections interposed between said cathode sections; (d) a non-queous electrolyte in said casing operatively contacting said anode means and said cathode means; (e) means for providing electrical connection to said anode means; and (f) means for providing electrical connection to said cathode means.
Claim 56
Dependent Claim
13 words
A cell according to claim 47, wherein said anode means is of lithium.
Claim 57
Dependent Claim
24 words
A cell according to claim 47, wherein said anode means comprises a plurality of plates defining said anode sections interposed between said cathode sections.
Claim 58
Dependent Claim
26 words
A cell according to claim 47, wherein said anode means comprises a continuous elongated body folded into a plurality of sections interposed between said cathode sections.
Claim 59
Dependent Claim
21 words
A cell according to claim 47, wherein each of said anode means and cathode means is individually enclosed in separator material.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1992-05-15 | 1992-11-14 | 1993-05-16 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1996-05-15 | 1996-11-14 | 1997-05-16 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2000-05-15 | 2000-11-14 | 2001-05-16 | $7700.00 | Window Closed / Lapsed |