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US4391729A Expired / Lapsed US ⏱️ 0.0 years remaining

Metal oxide composite cathode material for high energy density batteries

Assignee: Greatbatch Ltd
•
Filing: 1980-06-30
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Granted: 1983-07-05
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Expires: 2000-06-30
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Abstract

Abstract An electrochemical cell incorporating cathode materials comprising at least one metal oxide, at least one metal, or mixture of metals or metal oxides incorporated in the matrix of a host metal oxide. The cathode materials of this invention are constructed by the chemical addition, reaction, or otherwise intimate contact of various metal oxides and/or metal elements during thermal treatment in mixed states. The materials thereby produced contain metals and oxides of the groups IB, IIB, IIIB, IVB, VB, VIB, VIIB, and VIII, which includes the noble metals and/or their oxide compounds. The incorporation of the metal oxides, metals or mixtures thereof substantially increases the discharge capacity and the overall performance of the cathode materials.

Inventors

  • 👤 Charles C. Liang
  • 👤 M. Elizabeth Bolster
  • 👤 Robert M. Murphy

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-28 16:17
CPC Classifications
H; H01; H01M; H01M4/00; H01M4/02; H01M4/36; H01M4/48; H01M4/485; H01M4/54; Y; Y02; Y02E; Y02E60/00; Y02E60/10

Claims Analysis

Total Claims: 15
Claim 1
Independent Claim 78 words
A method of making a composite cathode comprising at least one metal oxide, metal or mixtures of metals and metal oxides in the matrix of a host metal oxide which comprises: thermally treating by heating above decomposition temperature a mixture of a host metal oxide and a thermally decomposable metal compound of a metal selected from the group consisting of Groups IB, IIB, IIIB, IVB, VB, VIB, VIIB and VIII, and forming the resultant mass into said cathode.
Claim 2
Independent Claim 78 words
A method of making a composite cathode comprising at least one metal oxide, metal or mixtures of metals and metal oxides in the matrix of a host metal oxide which comprises: thermally treating by heating above decomposition temperature a mixture of a host metal oxide and a thermally decomposable metal compound of a metal selected from the group consisting of Groups IB, IIB, IIIB, IVB, VB, VIB, VIIB and VIII, and forming the resultant mass into said cathode.
Claim 3
Dependent Claim 17 words
A method of claim 1, wherein thermal treatment is for a period of at least 24 hours.
Claim 4
Dependent Claim 14 words
A method of claim 1, wherein the decomposable metal compound is a metal oxide.
Claim 5
Dependent Claim 14 words
A method of claim 3, wherein the decomposable metal compound is a metal salt.
Claim 6
Dependent Claim 29 words
A method of claim 4, wherein the decomposable compound is selected from the group consisting of metal nitrate, metal nitrite, metal carbonate and ammonium salts of transition metal oxyanions.
Claim 7
Dependent Claim 13 words
A method of claim 4, wherein the decomposable metal compound is ammonium vanadate.
Claim 8
Dependent Claim 13 words
A method of claim 1, wherein the decomposable metal compound is silver nitrate.
Claim 9
Dependent Claim 23 words
A method of claim 1, wherein a first decomposable metal compound is mixed with a second decomposable metal compound prior to thermal treatment.
Claim 10
Dependent Claim 16 words
A method of claim 8, wherein the decomposable metal salts are ammonium vanadate and silver nitrate.
Claim 11
Dependent Claim 23 words
A method of claim 1, wherein the thermally treated decomposable metal compound is combined with a metal oxide prior to forming the cathode.
Claim 12
Dependent Claim 20 words
A method of claim 1, further comprising the step of admixing a suitable binder material prior to forming the cathode.
Claim 13
Dependent Claim 11 words
A method of claim 11, wherein the binder material is carbon.
Claim 14
Dependent Claim 13 words
A method of claim 12, wherein the binder material is carbon and Teflon.
Claim 15
Dependent Claim 34 words
A method of claim 1, further comprising the step of admixing a metal selected from the group consisting of groups IB, IIB, IIIB, IVB, VB, VIB, VIIB, and VIII prior to forming the cathode.

References Cited (Backward Citations)

US3423242A Cited
US3945848A Cited
US3998658A Cited
US4125689A Cited
US4158722A Cited
US4142996A Cited
US4146685A Cited
US4277360A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1986-07-04 1987-01-03 1987-07-05 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1990-07-04 1991-01-03 1991-07-05 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1994-07-04 1995-01-03 1995-07-05 $7700.00 Window Closed / Lapsed

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