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US3945848A Expired / Lapsed US ⏱️ 0.0 years remaining

Lithium-metal oxide organic electrolyte systems

Assignee: Duracell Inc USA
•
Filing: 1974-06-24
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Granted: 1976-03-23
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Expires: 1994-06-24
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Abstract

Abstract This invention relates to a novel primary battery comprising at least one positive plate composed of cobalt, oxides and their mixtures, and at least one negative plate having a metal selected from the group of light metals, said plates being disposed in an electrolyte comprising an organic solvent selected from the group consisting of tetrahydrofuran, N-nitrosodimethylamine, dimethyl sulfite, propylene carbonate, gamma-butyrolactone, dimethyl carbonate, dimethoxy ethane, aceto-nitrile and the mixtures thereof, and having dissolved therein soluble salts of the light metals, for example, the perchlorates, hexafluorophosphates, tetrafluoroborates, tetrachloroaluminates, and hexafluoro arsenates of lithium.

Inventors

  • 👤 Arabinda N. Dey
  • 👤 Robert W. Holmes

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-28 21:24
CPC Classifications
H; H01; H01M; H01M6/00; H01M6/14; H01M6/16; H01M4/00; H01M4/02; H01M4/06; H01M4/08; H01M4/36; H01M4/48; H01M4/52; H01M4/523

Claims Analysis

Total Claims: 6
Claim 1
Independent Claim 108 words
A high energy density cell comprising a positive electrode composed of a cobalt oxide positive electrode material selected from the group consisting of Co 2 O 3 and Co 3 O 4 and mixtures thereof; a negative electrode consisting of a metal selected from the group of light metals; said electrodes being disposed in an electrolyte comprising an organic solvent selected from the group consisting of tetrahydrofuran, N-nitrosodimethylamine, dimethyl sulfite, propylene carbonate, gamma-butyrolactone, dimethyl carbonate, dimethoxyethane, acetonitrile, and the mixtures thereof, and having dissolved therein soluble salts of the light metals, wherein said soluble salts are selected from the group consisting of perchlorates, hexafluorophosphates, tetrafluoroborates, tetrachloroaluminates, and hexafluoroarsenates.
Claim 2
Dependent Claim 108 words
A high energy density cell comprising a positive electrode composed of a cobalt oxide positive electrode material selected from the group consisting of Co 2 O 3 and Co 3 O 4 and mixtures thereof; a negative electrode consisting of a metal selected from the group of light metals; said electrodes being disposed in an electrolyte comprising an organic solvent selected from the group consisting of tetrahydrofuran, N-nitrosodimethylamine, dimethyl sulfite, propylene carbonate, gamma-butyrolactone, dimethyl carbonate, dimethoxyethane, acetonitrile, and the mixtures thereof, and having dissolved therein soluble salts of the light metals, wherein said soluble salts are selected from the group consisting of perchlorates, hexafluorophosphates, tetrafluoroborates, tetrachloroaluminates, and hexafluoroarsenates.
Claim 3
Dependent Claim 28 words
The battery according to claim 1 in which the negative electrode is composed of lithium, and the electrolyte is composed of a solution of lithium perchlorate in tetrahydrofuran.
Claim 4
Dependent Claim 24 words
The cell according to claim 2 in which the positive electrode comprises a mixture of said positive electrode material with an electronically conductive diluent.
Claim 5
Dependent Claim 13 words
The cell according to claim 3 wherein said electronically conductive diluent is graphite.
Claim 6
Dependent Claim 19 words
In the cell according to claim 2 wherein said positive electrode mixture includes a binder of a polyfluorinated hydrocarbon.

References Cited (Backward Citations)

US3248265A Cited
US3117032A Cited
US3279952A Cited
US3423242A Cited
US3468716A Cited
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US3484296A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1979-03-23 1979-09-22 1980-03-23 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1983-03-23 1983-09-22 1984-03-23 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1987-03-23 1987-09-22 1988-03-23 $7700.00 Window Closed / Lapsed

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