Patent US4822654A successfully refreshed from Google Patents.
← Back to Patent Explorer
US4822654A Expired / Lapsed US ⏱️ 0.0 years remaining

Novel vulcanizable rubber compositions and applications thereof

Assignee: JSR Corp
•
Filing: 1988-03-10
•
Granted: 1989-04-18
•
Expires: 2008-03-10
📄 Original PDF 🌐 Google Patents 🔄 Sync Now

Abstract

Abstract A vulcanizable rubber composition comprising (1) 100 parts by weight of a polymer composition comprising (I) a vinylidene fluoride resin, (II) at least one rubber selected from the group consisting of acrylic rubbers, α,β-unsaturated nitrile-conjugated diene copolymer rubbers and hydrides of α,β-unsaturated nitrile-conjugated diene copolymer rubbers, said acrylic rubber consisting of (A) 30 to 99.9% by weight of an alkyl acrylate and/or an alkoxy-substituted alkyl acrylate, (B) 0.1 to 10% by weight of a crosslinkable monomer and (C) 0 to 70% by weight of another ethylenically unsaturated compound copolymerizable with (A) and (B) (the sum of (A), (B) and (C) is 100% by weight) and said α,β-unsaturated nitrile-conjugated diene copolymer rubber consisting of (D) 10 to 60% by weight of an α,β-unsaturated nitrile, (E) 15 to 90% by weight of a conjugated diene and (F) 0 to 75% by weight of another ethylenically unsaturated compound copolymerizable with (D) and (E) (the sum of (D), (E) and (F) is 100% by weight, and (III) another blendable polymer, wherein the weight ratio of (I)/[(II)+(III)] is 5/95 to 60/40 and the weight ratio of (II)/(III) is 100/0 to 50/50, and (2) 0 to 40 parts by weight of a plasticizer. Said rubber composition excels not only in heat resistance, gasoline resistance and sour gasoline resistance but also in gasohol resistance and sour gasohol resistance and further is good in tensile strength, elongation and balance between gasoline resistance and low-temperature resistance. Therefore, said rubber composition can be used in the fluid-contacting surface of a diaphragm and can be suitably used as an inner tube of a fuel hose.

Inventors

  • 👤 Yasuhiko Takemura
  • 👤 Shinichiro Zen
  • 👤 Yoshiaki Zama
  • 👤 Hiroji Enyo

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-08 13:30
CPC Classifications
B; B32; B32B; B32B25/00; B32B25/14; B32B25/04; B32B25/042; B32B1/00; B32B1/08; C; C08; C08L; C08L15/00; C08L15/005; C08L27/00; C08L27/02; C08L27/12; C08L27/16; C08L33/00; C08L33/04; C08L33/06; C08L9/00; C08L9/02; B32B2305/00; B32B2305/72; C08L33/08; Y; Y10; Y10T; Y10T428/00; Y10T428/13; Y10T428/1352; Y10T428/1386

Claims Analysis

Total Claims: 12
Claim 1
Independent Claim 205 words
A vulcanizable rubber composition comprising (1) 100 parts by weight of a polymer composition comprising (I) a vinylidene fluoride resin containing at least 90 mole % vinylidene fluoride, (II) at least one rubber selected from the group consisting of acrylic rubbers, α,β-unsaturated nitrile-conjugated diene copolymer rubbers and hydrides of α,β-unsaturated nitrile-conjugated diene copolymer rubbers, said acrylic rubber consisting of (A) 30 to 99.9% by weight of an alkyl acrylate and/or an alkoxy-substituted alkyl acrylate, (B) 0.1 to 10% by weight of a crosslikable monomer and (C) 0 to 70% by weight of another ethylenically unsaturated compound copolymerizable with (A) and (B) (the sum of (A), (B) and (C) is 100% by weight), and said α,β-unsaturated nitrile-conjugated diene copolymer rubber consisting of (D) 10 to 60% by weight of an α,β-unsaturated nitrile, (E) 15 to 90% by weight of a conjugated diene and (F) 0 to 75% by weight of another ethylenically unsaturated compound copolymerizable with (D) and (E) (the sum of (D), (E) and (F) is 100% by weight), and (III) optional blendable polymer, wherein the weight ratio of (I)/[(II)+(III)] is 5/95 to 60/40 and the weight ratio of (II)/(III) is 100/0 to 50/50, and (2) 5 to 40 parts by weight of a plasticizer.
Claim 2
Dependent Claim 205 words
A vulcanizable rubber composition comprising (1) 100 parts by weight of a polymer composition comprising (I) a vinylidene fluoride resin containing at least 90 mole % vinylidene fluoride, (II) at least one rubber selected from the group consisting of acrylic rubbers, α,β-unsaturated nitrile-conjugated diene copolymer rubbers and hydrides of α,β-unsaturated nitrile-conjugated diene copolymer rubbers, said acrylic rubber consisting of (A) 30 to 99.9% by weight of an alkyl acrylate and/or an alkoxy-substituted alkyl acrylate, (B) 0.1 to 10% by weight of a crosslikable monomer and (C) 0 to 70% by weight of another ethylenically unsaturated compound copolymerizable with (A) and (B) (the sum of (A), (B) and (C) is 100% by weight), and said α,β-unsaturated nitrile-conjugated diene copolymer rubber consisting of (D) 10 to 60% by weight of an α,β-unsaturated nitrile, (E) 15 to 90% by weight of a conjugated diene and (F) 0 to 75% by weight of another ethylenically unsaturated compound copolymerizable with (D) and (E) (the sum of (D), (E) and (F) is 100% by weight), and (III) optional blendable polymer, wherein the weight ratio of (I)/[(II)+(III)] is 5/95 to 60/40 and the weight ratio of (II)/(III) is 100/0 to 50/50, and (2) 5 to 40 parts by weight of a plasticizer.
Claim 3
Dependent Claim 36 words
The rubber composition according to claim 1, wherein the plasticizer (2) is at least one member selected from the group consisting of phosphoric acid derivatives, adipic acid derivatives, polyester compounds, polyether compounds and poly(ether ester) compounds.
Claim 4
Dependent Claim 26 words
The rubber composition according to claim 1, wherein the optional blendable polymer (III) is a fluororubber, an epichlorohydrin rubber, a chlorosulfonated polyethylene or a poly(vinyl chloride).
Claim 5
Dependent Claim 56 words
The rubber composition according to claim 1, wherein the rubber (II) is a mixture of 100 to 60% by weight of an acrylic rubber having a Mooney viscosity (ML 1+4 (100° C.)) of 20 to 120 and 0 to 40% by weight of an acrylic rubber having a number average molecular polymer of 500 to 10,000.
Claim 6
Dependent Claim 68 words
The rubber composition according to claim 1, wherein the rubber (II) is a mixture of 100 to 60% by weight of an α,β-unsaturated nitrile-conjugated diene copolymer rubber having a Mooney viscosity (ML 1+4 (100° C.)) of 20 to 150 and/or its hydride and 0 to 40% by weight of an α,β-unsaturated nitrile-conjugated diene copolymer rubber having a number average molecular weight of 500 to 10,000 and/or its hydride.
Claim 7
Dependent Claim 29 words
The rubber composition according to claim 1, wherein the rubber (II) is an α,β-unsaturated nitrile-conjugated diene copolymer rubber in which the diene portions are hydrogenated by 50% or more.
Claim 8
Dependent Claim 45 words
The rubber composition according to claim 1, wherein the rubber (II) is at least one rubber selected from the acrylic rubbers and the hydrides of α,β-unsaturated diene copolymer rubbers, and the weight ratio of the vinylidene fluoride resin (I)/the rubber (II) is 5/95 to 60/40.
Claim 9
Dependent Claim 31 words
The rubber composition according to claim 1, wherein the rubber (II) is the acrylic rubber, and the weight ratio of the vinylidene fluoride resin (I)/the rubber (II) is 5/95 to 60/40.
Claim 10
Dependent Claim 18 words
A diaphragm in which the fluid-contacting surface is made from a vulcanizable rubber composition according to claim 1.
Claim 11
Dependent Claim 13 words
A rubber hose made from a vulcanizable rubber composition according to claim 1.
Claim 12
Dependent Claim 15 words
The rubber composition according to claim 1, wherein the optical blendable polymer (III) is absent.

References Cited (Backward Citations)

BE664901A Cited
GB1113602A Cited
US3524906A Cited
US3853809A Cited
JPS5240558A Cited
FR2330723A1 Cited
US4048261A Cited
JPS5589338A Cited
EP0119725A2 Cited
EP0160399A2 Cited
US4625005A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1992-04-17 1992-10-17 1993-04-18 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1996-04-17 1996-10-17 1997-04-18 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2000-04-17 2000-10-17 2001-04-18 $7700.00 Window Closed / Lapsed

Assigned Categories & Tags

No categories assigned to this patent yet.

Assign Category Tag