Process for producing propylene oligomers

Claim 2

A process for producing propylene oligomers using a catalyst comprising a transition metal compound and an organometallic compound which comprises oligomerizing propylene in the presence of a catalyst comprising a cyclopentadienyl compound represented by the formula (1): (R.sub.5 C.sub.5).sub.m.M.X.sub.4-m ( 1) wherein R represents an alkyl group of 1-20 carbon atoms, R 5 C 5 represents an alkyl substituted cyclopentadienyl group, M represents a zirconium atom or a hafnium atom, X represents a hydrogen atom, an alkyl group of 1-20 carbon atoms or a halogen atom and m represents a real number of 2-4; and a condensation product of an organoaluminum compound and water as an organometallic compound.

Claim 3

A process for producing propylene oligomers using a catalyst comprising a transition metal compound and an organometallic compound which comprises oligomerizing propylene in the presence of a catalyst comprising a coordination compound obtained by reacting a cyclopentadienyl compound represented by the formula (1): (R.sub.5 C.sub.5).sub.m.M.X.sub.4-m ( 1) wherein R represents an alkyl group of 1-20 carbon atoms, R 5 C 5 represents an alkyl substituted cyclopentadienyl group, M represents a zirconium atom or a hafnium atom, X represents a hydrogen atom, an alkyl group of 1-20 carbon atoms or a halogen atom and m represents a real number of 2-4, with an electron donating compound having at least one atom selected from the group consisting of oxygen and nitrogen; and a condensation product of an organoaluminum compound and water as an organometallic compound.

Claim 4

A process for producing propylene oligomers using a catalyst comprising a transition metal compound and an organometallic compound which comprises oligomerizing propylene in the presence of a catalyst comprising a coordination compound obtained by reacting a cyclopentadienyl compound represented by the formula (1): (R.sub.5 C.sub.5).sub.m.M.X.sub.4-m ( 1) wherein R represents an alkyl group of 1-20 carbon atoms, R 5 C 5 represents an alkyl substituted cyclopentadienyl group, M represents a zirconium atom or a hafnium atom, X represents a hydrogen atom, an alkyl group of 1-20 carbon atoms or a halogen atom and m represents a real number of 2-4, with an electron donating compound having at least one atom selected from the group consisting of oxygen and nitrogen; and a condensation product of an organoaluminum compound and water as an organometallic compound.

Claim 5

A process according to claim 1 wherein the organoaluminum compound is a trialkylaluminum of 1-5 carbon atoms.

Claim 6

A process according to claim 1 wherein the organoaluminum compound is at least one compound selected from the group consisting of methylaluminum and triethylaluminum.

Claim 7

A process according to claim 2 wherein the electron donating compound is an ester or an organic compound containing nitrogen.

Claim 8

A process according to claim 2 wherein the electron donating compound is at least one compound selected from the group consisting of aromatic esters, aromatic amines and heterocyclic amines.

Claim 9

A process according to claim 2 wherein the electron donating compound is at least one compound selected from the group consisting of lower alkyl esters of benzoic acid, lower alkyl esters of lower alkoxybenzoic acids, anilines which may have lower alkyl group on benzene ring as a substituent and piperidine.

Claim 10

A process according to claim 2 wherein the electron donating compound is a compound selected from the group consisting of ethyl benzoate, ethyl methoxybenzoate, toluidine and piperidine.

Claim 11

A process according to claim 1 wherein the blending ratio of the alkyl substituted cyclopentadienyl compound and the condensation product of the organoaluminum compound and water when they are reacted is 10-5,000 in terms of atomic ratio aluminum atom/zirconium atom or hafnium atom.

Claim 12

A process according to claim 2 wherein ratio (b)/(a) of the alkyl substituted cyclopentadienyl compound (a) and the electron donating compound (b) is 0.1-10 in molar ratio.

Claim 13

A process according to claim 2 wherein the blending ratio of the coordination compound obtained by reaction of the alkyl substituted cyclopentadienyl compound and the electron donating compound and the condensation product of the organoaluminum compound and water is 10-5,000 in terms of atomic ratio of aluminum atom and zirconium or hafnium atom (Al/Zr or Hf).

Claim 14

A process according to claim 1 wherein the oligomerization reaction of propylene is carried out at a reaction temperature of 0°-100° C. and a reaction pressure of 10 kg/cm 2 G or less.

Claim 15

A process according to claim 1 wherein the oligomerization reaction of propylene is carried out in a solvent.

Claim 16

A process according to claim 1 wherein the propylene oligomer is a mixture of propylene oligomers having vinyl group at molecular terminal which are represented by the formula: ##STR2## wherein q represents a real number of 1-9.

Claim 17

A process for producing propylene oligomers according to claim 1 wherein the propylene is oligomerized reaction proceeds in the presence of hydrogen.

Claim 18

A process for producing propylene oligomers according to claim 2 wherein the propylene is oligomerized in the presence of hydrogen.