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Photosensitive polyimide polymer compositions

Assignee: EMD Performance Materials Corp
•
Filing: 1987-11-24
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Granted: 1989-02-07
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Expires: 2007-11-24
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Abstract

Abstract A photosensitive polyimide polymer composition comprising a solvent soluble polyimide condensation product of an aromatic dianhydride and an aromatic diamine, a polyfunctional ethylenically unsaturated monomer and a photoinitiator. The solvent soluble polyimides of the composition are prepared from at least one compound selected from 2,2-hexafluoro-bis-(3,4-dicarboxyphenyl)tetracarboxylic dianhydride; 1,1-bis-[4-(1,2-dicarboxyphenyl)]-1-phenyl-2,2,2-trifluoroethane dianhydride; 2,2-hexafluoro-bis(3-aminophenyl)propane; 2,2-hexafluoro-bis(4-aminophenyl)propane; 2,2-hexafluoro-bis-[4-(3-aminophenoxy)phenyl]propane; 2,2-hexafluoro-bis-[4-(4-aminophenoxy)phenyl]propane and 1,1-bis-(4-aminopheny)-1-phenyl-2,2,2-trifluoroethane or mixtures thereof.

Inventors

  • 👤 Werner H. Mueller
  • 👤 Dinesh N. Khanna
  • 👤 Rohitkumar H. Vora

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-02 12:07
CPC Classifications
C; C08; C08G; C08G73/00; C08G73/06; C08G73/10; C08G73/1046; C08G73/105; C08G73/1039; C08G73/12; C08G73/123; C08L; C08L79/00; C08L79/04; C08L79/08; G; G03; G03F; G03F7/00; G03F7/004; G03F7/027; G03F7/032; G03F7/037; Y; Y10; Y10S; Y10S430/00; Y10S430/1053; Y10S430/1055; Y10S430/106; Y10S430/107

Claims Analysis

Total Claims: 17
Claim 1
Independent Claim 61 words
A photosensitive polyimide composition consisting essentially of solvent soluble polyimide which is the condensation product of an aromatic diamine and an aromatic dianhydride; a photoinitiator; a photopolymerizable compound containing at least two terminal ethylenically unsaturated groups; wherein at least one of said dianhydride or said diamine is selected from 2,2-hexafluoro-bis(3,4-dicarboxyphenyl)propane dianhydride; 2,2-hexafluorobis(3-aminophenyl)propane; 2,2-hexafluoro-bis(4-aminophenyl)propane; 2,2-hexafluoro-bis[4-(3-aminophenoxy)phenyl]propane; 2,2-hexafluoro-bis[4-(4-aminophenoxy)phenyl]propane; 1,1-bis(4-aminophenyl)-1-phenyl-2,2-2-trifluoroethane; 1,1-bis-[4-(1,2-dicarboxyphenyl)]-1-phenyl2,2,2-trifluoroethane dianhydride and mixtures thereof.
Claim 2
Dependent Claim 61 words
A photosensitive polyimide composition consisting essentially of solvent soluble polyimide which is the condensation product of an aromatic diamine and an aromatic dianhydride; a photoinitiator; a photopolymerizable compound containing at least two terminal ethylenically unsaturated groups; wherein at least one of said dianhydride or said diamine is selected from 2,2-hexafluoro-bis(3,4-dicarboxyphenyl)propane dianhydride; 2,2-hexafluorobis(3-aminophenyl)propane; 2,2-hexafluoro-bis(4-aminophenyl)propane; 2,2-hexafluoro-bis[4-(3-aminophenoxy)phenyl]propane; 2,2-hexafluoro-bis[4-(4-aminophenoxy)phenyl]propane; 1,1-bis(4-aminophenyl)-1-phenyl-2,2-2-trifluoroethane; 1,1-bis-[4-(1,2-dicarboxyphenyl)]-1-phenyl2,2,2-trifluoroethane dianhydride and mixtures thereof.
Claim 3
Dependent Claim 24 words
A composition according to claim 1 wherein said dianhydride is 2,2-hexafluoro-bis(3,4-dicarboxyphenyl)propane dianhydride and diamine is selected from 2,2-hexafluorobis(4-aminophenyl)propane; 2,2-hexafluoro-bis(3-aminophenyl)propane; 2,2-hexafluoro-bis[4-(3-aminophenoxy)phenyl]propane; 2,2-hexafluoro-bis[4-(4-aminophenoxy)phenyl]propane and mixtures thereof.
Claim 4
Dependent Claim 29 words
A composition according to claim 1 wherein said diamine is 2,2-hexafluoro-bis(3-aminophenyl)propane and said dianhydride is selected from 3,3',4,4'-benzophenone tetracarboxylic dianhydride; bis(3,4-dicarboxyphenyl)ether tetracarboxylic dianhydride; 3,3',4,4'-diphenyl tetracarboxylic dianhydride and mixtures thereof.
Claim 5
Dependent Claim 29 words
A composition according to claim 1 wherein said diamine is 2,2-hexafluoro-bis(4-aminophenyl)propane and said dianhydride is selected from 3,3',4,4'-benzophenone tetracarboxylic dianhydride; bis(3,4-dicarboxyphenyl)ether tetracarboxylic dianhydride; 3,3',4,4'-diphenyl tetracarboxylic dianhydride and mixtures thereof.
Claim 6
Dependent Claim 28 words
A composition according to claim 1 wherein said diamine is selected from 2,2-hexafluoro-bis[4-(3-aminophenoxy)phenyl]propane and said dianhydride is selected from bis(3,4-dicarboxyphenyl)ether tetracarboxylic dianhydride; 3,3',4,4'-diphenyl tetracarboxylic dianhydride and mixtures thereof.
Claim 7
Dependent Claim 28 words
A composition according to claim 1 wherein said diamine is selected from 2,2-hexafluoro-bis[4-(4-aminophenoxy)phenyl]propane and said dianhydride is selected from bis(3,4-dicarboxyphenyl)ether tetracarboxylic dianhydride; 3,3',4,4'-diphenyl tetracarboxylic dianhydride and mixtures thereof.
Claim 8
Dependent Claim 27 words
A composition according to claim 1 wherein said dianhydride is selected from 1,1-bis[4-(1,2-dicarboxyphenyl)]-1-phenyl-2,2,2-trifluoroethane and said diamine is selected from 2,2-hexafluoro-bis(4-aminophenyl)propane; 2,2-hexafluorobis(3-aminophenyl)propane; 2,2-hexafluoro-bis[4-(3-aminophenoxy)phenyl]propane; 2,2-hexafluoro-bis[4-(4-aminophenoxy)phenyl]propane; 1,1-bis(4-aminophenyl)-1-phenyl-2,2,2-trifluoroethane and mixtures thereof.
Claim 9
Dependent Claim 20 words
A composition according to claim 1 wherein said diamine is 1,1-bis(4-aminophenyl)-1-phenyl-2,2,2-trifluoroethane and said dianhydride is selected from 2,2-hexafluoro-bis-(3,4-dicarboxyphenyl propane dianhydride.
Claim 10
Dependent Claim 13 words
A microelectronic circuit coated with a photosensitive polymide composition according to claim 1.
Claim 11
Dependent Claim 13 words
A microelectronic circuit coated with a photosensitive polyimide composition according to claim 2.
Claim 12
Dependent Claim 13 words
A microelectronic circuit coated with a photosensitive polyimide composition according to claim 3.
Claim 13
Dependent Claim 13 words
A microelectronic circuit coated with a photosensitive polyimide composition according to claim 4.
Claim 14
Dependent Claim 13 words
A microelectronic circuit coated with a photosensitive polyimide composition according to claim 5.
Claim 15
Dependent Claim 13 words
A microelectronic circuit coated with a photosensitive polyimide composition according to claim 6.
Claim 16
Dependent Claim 13 words
A microelectronic circuit coated with a photosensitive polyimide composition according to claim 7.
Claim 17
Dependent Claim 13 words
A microelectronic circuit coated with a photosensitive polyimide composition according to claim 8.

References Cited (Backward Citations)

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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1992-02-07 1992-08-08 1993-02-07 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1996-02-07 1996-08-08 1997-02-07 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2000-02-07 2000-08-08 2001-02-07 $7700.00 Window Closed / Lapsed

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