US4558117A
Expired / Lapsed
US
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Organic solvent-soluble photosensitive polyimide resin
Assignee: Ube Corp
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Filing: 1984-05-30
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Granted: 1985-12-10
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Expires: 2004-05-30
Abstract
Abstract An organic solvent-soluble photosensitive polyimide resin having excellent heat resistance and electrical and mechanical properties, comprising a copolycondensation product of a biphenyltetracarboxylic acid component with an aromatic diamine component consisting of 40 to 90 molar % of a diamine compound of the formula (I) and 10 to 60 molar % of a diaminodiphenylether compound of the formula (II), <IMAGE> (I) <IMAGE> (II) wherein X=-CO-O- or -CH2-O-, R1 and R2=an organic residue having an ethylenically unsaturated radical, and R3=H or -NHCOR2.
Inventors
- 👤 Tsunetomo Nakano
- 👤 Hiroshi Yasuno
- 👤 Kazuaki Nishio
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-01 16:34
CPC Classifications
C; C08; C08G; C08G73/00; C08G73/06; C08G73/10; C08G73/1042; C08G73/1003; C08G73/1007; C08G73/1025; C08G73/1067; C08G73/1071; G; G03; G03F; G03F7/00; G03F7/004; G03F7/038; G03F7/0387
Claims Analysis
Total Claims: 8
Claim 1
Independent Claim
151 words
An organic solvent-soluble photosensitive polyimide resin comprising a copolycondensation product of an aromatic tetracarboxylic acid component consisting of at least one member selected from the group consisting of biphenyltetracarboxylic acids and dianhydrides, esters and salts thereof with an aromatic diamine component consisting of 40 to 90 molar % of at least one aromatic diamine compound of the formula (I): ##STR7## and 10 to 60 molar % of at least one aromatic diamine compound of the formula (II): ##STR8## in which formulae (I) and (II) X represents a divalent radical selected from the group consisting of --CO--O-- and --CH 2 --O--, R 1 and R 2 respectively represent, independently from each other, an organic residue having an ethylenically unsaturated radical, and R 3 represents a member selected from the group consisting of a hydrogen atom and radicals of the formula --NHCOR 2 , wherein R 2 is the same as defined above.
Claim 2
Dependent Claim
151 words
An organic solvent-soluble photosensitive polyimide resin comprising a copolycondensation product of an aromatic tetracarboxylic acid component consisting of at least one member selected from the group consisting of biphenyltetracarboxylic acids and dianhydrides, esters and salts thereof with an aromatic diamine component consisting of 40 to 90 molar % of at least one aromatic diamine compound of the formula (I): ##STR7## and 10 to 60 molar % of at least one aromatic diamine compound of the formula (II): ##STR8## in which formulae (I) and (II) X represents a divalent radical selected from the group consisting of --CO--O-- and --CH 2 --O--, R 1 and R 2 respectively represent, independently from each other, an organic residue having an ethylenically unsaturated radical, and R 3 represents a member selected from the group consisting of a hydrogen atom and radicals of the formula --NHCOR 2 , wherein R 2 is the same as defined above.
Claim 3
Dependent Claim
27 words
The photosensitive polyimide resin as claimed in claim 1, wherein said biphenyltetracarboxylic acid is selected from the group consisting of 3,3'4,4'-biphenyltetracarboxylic acid, 2,2',3,3'-biphenyltetracarboxylic acid, and 2,3,3',4'-biphenyltetracarboxylic acid.
Claim 4
Dependent Claim
33 words
The photosensitive polyimide resin as claimed in claim 1, wherein the organic residue represented by R 1 in the formula (I) is selected from the group consisting of those of the formulae: ##STR9##
Claim 5
Dependent Claim
36 words
The photosensitive polyimide resin as claimed in claim 1, wherein the organic residue represented by R 2 in the formula (II) is selected from the group consisting of those of the formulae --CH═CH 2 and ##STR10##
Claim 6
Dependent Claim
80 words
The photosensitive polyimide resin as claimed in claim 1, wherein said aromatic diamine compound of the formula (I) is selected from the group consisting of 3,5-diaminobenzoic acid ethyleneglycol monoacrylate ester, 3,5-diaminobenzoic acid ethyleneglycol monomethacrylate ester, 3,5-diaminobenzoic acid glycidyl acrylate ester, 3,5-diaminobenzoic acid glycidyl methacrylate ester, 3,5-diaminobenzoic acid cinnamic acid ester, 2,4-diaminobenzoic acid ethyleneglycol monoacrylate ester, 2,4-diaminobenzoic acid ethyleneglycol monomethacrylate ester, 2,4-diaminobenzoic acid glycidyl acrylate ester, 2,4-diaminobenzoic acid glycidyl methacrylate ester, 2,4-diaminobenzoic acid cinnamic acid ester, 3,5-diaminobenzyl acrylate, and 3,5-diaminobenzyl methacrylate.
Claim 7
Dependent Claim
30 words
The photosensitive polyimide resin as claimed in claim 1, wherein said aromatic diamine compound of the formula (II) is selected from the group consisting of 4-acrylamido-3,4'-diaminodiphenylether, 4-cinnamamido-3,4'-diaminodiphenylether, 3,4'-diacrylamido-3'4-diaminodiphenylether, and 3,4'-dicinnamamido-3',4-diaminodiphenylether.
Claim 8
Dependent Claim
71 words
The photosensitive polyamide resin as claimed in claim 1, wherein said aromatic tetracarboxylic acid component consists of 25 to 75 molar parts of at least one member selected from the group consisting of 3,3',4,4'-biphenyltetracarboxylic acid, 2,2',3,3'-biphenyltetracarboxylic acid and dianhydrides, esters, and salts of the above-mentioned acids and 25 to 75 molar parts of at least one member selected from the group consisting of 2,3,3',4'-biphenyltetracarboxylic acid and dianhydride, esters, and salts thereof.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1988-12-09 | 1989-06-10 | 1989-12-10 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1992-12-09 | 1993-06-10 | 1993-12-10 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1996-12-09 | 1997-06-10 | 1997-12-10 | $7700.00 | Window Closed / Lapsed |