US4797238A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Rapid-sintering of alumina
Assignee: Osram Sylvania Inc
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Filing: 1987-05-12
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Granted: 1989-01-10
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Expires: 2007-05-12
Abstract
Abstract An improved process for producing a translucent polycrystalline alumina body comprising rapid-sintering a prefired compacted green body of alumina of predetermined shape is disclosed. The green body of alumina includes alumina doped with one or more sintering aids. Rapid sintering in accordance with the method of the present invention comprises the steps of raising the temperature of the prefired compacted green body of predetermined shape up to maximum sintering temperature at a heating rate greater than or equal to about 0.1° C./second and less than the rate at which the green body experiences thermal shock; and heating the green body at the maximum sintering temperature for a period of time sufficient to produce a translucent polycrystalline alumina body. The rapid sintering is carried out under a flowing gas mixture of nitrogen and at least about 2.5 volume percent hydrogen.
Inventors
- 👤 William H. Rhodes
- 👤 George C. Wei
- 👤 George A. Fryburg
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-06 15:26
CPC Classifications
C; C04; C04B; C04B35/00; C04B35/622; C04B35/64; C04B35/01; C04B35/10; C04B35/111; C04B35/115; Y; Y10; Y10S; Y10S264/00; Y10S264/91
Claims Analysis
Total Claims: 12
Claim 1
Independent Claim
125 words
A process for producing a translucent polycrystalline alumina body comprising: rapid-sintering a prefired, compacted green body of predetermined shape under a flowing gas mixture of nitrogen and at least about 2.5 volume percent and less than 75 volume percent hydrogen, the green body comprising alumina doped with one or more sintering aids, said rapid-sintering comprising the steps of: raising the temperature of said prefired compacted green body of predetermined shape up to a maximum sintering temperature at a heating rate greater than or equal to about 0.1° C./second and less than the heating rate at which the green body experiences thermal shock; and heating the green body at said maximum sintering temperature for a period of time sufficient to produce a translucent polycrystalline alumina body.
Claim 2
Dependent Claim
125 words
A process for producing a translucent polycrystalline alumina body comprising: rapid-sintering a prefired, compacted green body of predetermined shape under a flowing gas mixture of nitrogen and at least about 2.5 volume percent and less than 75 volume percent hydrogen, the green body comprising alumina doped with one or more sintering aids, said rapid-sintering comprising the steps of: raising the temperature of said prefired compacted green body of predetermined shape up to a maximum sintering temperature at a heating rate greater than or equal to about 0.1° C./second and less than the heating rate at which the green body experiences thermal shock; and heating the green body at said maximum sintering temperature for a period of time sufficient to produce a translucent polycrystalline alumina body.
Claim 3
Dependent Claim
29 words
A process in accordance with claim 1 wherein the mixture of N 2 and H 2 contains a volume percent of H 2 from about 2.5% to about 8%.
Claim 4
Dependent Claim
172 words
A process for producing a translucent polycrystalline alumina body comprising: rapid-sintering a prefired, compacted green body of predetermined shape under a flowing gas mixture of nitrogen and at least about 2.5 volume percent and less than 75 volume percent hydrogen, the green body comprising alumina doped with one or more sintering aids, by feeding said prefired compacted green body of predetermined shape into the hot zone of a furnace at a fast feeding speed to heat the green body to a maximum sintering temperature; said fast feeding speed being selected to effect a heating rate greater than or equal to about 0.1° C/second and less than the heating rate at which the green body experiences thermal shock such that the green body is sintered at said maximum sintering temperature for a period of time sufficient to produce a translucent polycrystalline alumina body; movement of the green body through said furnace during rapid-sintering being continuous and uninterrupted, and the hot zone of said furnace during rapid-sintering being maintained at the maximum sintering temperature.
Claim 5
Dependent Claim
172 words
A process for producing a translucent polycrystalline alumina body comprising: rapid-sintering a prefired, compacted green body of predetermined shape under a flowing gas mixture of nitrogen and at least about 2.5 volume percent and less than 75 volume percent hydrogen, the green body comprising alumina doped with one or more sintering aids, by feeding said prefired compacted green body of predetermined shape into the hot zone of a furnace at a fast feeding speed to heat the green body to a maximum sintering temperature; said fast feeding speed being selected to effect a heating rate greater than or equal to about 0.1° C/second and less than the heating rate at which the green body experiences thermal shock such that the green body is sintered at said maximum sintering temperature for a period of time sufficient to produce a translucent polycrystalline alumina body; movement of the green body through said furnace during rapid-sintering being continuous and uninterrupted, and the hot zone of said furnace during rapid-sintering being maintained at the maximum sintering temperature.
Claim 6
Dependent Claim
15 words
A process in accordance with claim 3 wherein the furnace is a continuous belt furnace.
Claim 7
Dependent Claim
19 words
A process in accordance with claim 3 wherein the volume percent H 2 is about 2.5% to about 8%.
Claim 8
Dependent Claim
29 words
A process in accordance with claim 4 wherein the mixture of N 2 and h 2 contains a volume percent of H 2 of about 2.5% to about 8%.
Claim 9
Dependent Claim
42 words
A process in accordance with claim 6 wherein the sintering aid is selected from the group consisting of MgO, Y 2 O 3 , La 2 O 3 , ZrO 2 , HfO 2 , Yb 2 O 3 and mixtures thereof.
Claim 10
Dependent Claim
15 words
A process in accordance with claim 7 wherein the maximum sintering temperature is 2000° C.
Claim 11
Dependent Claim
37 words
A process according to claim 1 wherein the flowing gas mixture contains nitrogen and an amount of hydrogen greater than or equal to about 2.5 volume percent and less than or equal to about 18 volume percent.
Claim 12
Dependent Claim
37 words
A process according to claim 3 wherein the flowing gas mixture contains nitrogen and an amount of hydrogen greater than or equal to about 2.5 volume percent and less than or equal to about 18 volume percent.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1992-01-10 | 1992-07-11 | 1993-01-10 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1996-01-10 | 1996-07-11 | 1997-01-10 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2000-01-10 | 2000-07-11 | 2001-01-10 | $7700.00 | Window Closed / Lapsed |