Aqueous sulfomethylated melamine gel-forming compositions

Claim 1

An aqueous gel-forming composition, useful in the recovering of hydrcarbons from hydrocarbon-bearing subterranean reservoirs, comprising a 1.0-60.0 weight percent sulfomethylated melamine polymer solution prepared by reacting: (A) 1.0 molar equivalent of a melamine of the formula: ##STR3## wherein R 1 through R 6 are selected from the group consisting of hydrogen; carboxymethyl; hydroxyethyl; 2, 3-dihydroxypropyl and 2,3-epoxypropyl with the proviso that at least 2 of R 1 through R 6 be hydrogen and the remainder of R 1 through R 6 be identical; (B) 3.0-6.7 molar equivalents of formaldehyde or a 2-6 carbon atom containing dialdehyde; (C) 0.25-1.25 molar equivalents of an alkali metal or ammonium salt of sulfurous acid; (D) 0.01-1.5 molar equivalents of a gel-modifying agent, said gel-modifying agent functioning to lower the gel-forming amounts of components (A), (B) and (C) necessary to form a gel-forming composition, said gel-modifying agent selected from the group consisting of (1) a ring-substituted primary aniline or primary naphthylamine where the substituent is electron-withdrawing; (2) poly (vinyl alcohol) of MW range 3,000-78,000; (3) poly (acrylamide) of MW range 10,000-100,000; (4) glycerol; (5) a poly (oxyethylene) or poly (oxypropylene) primary amine or a poly (oxyethylene) or poly (oxypropylene) secondary di- or tri- amine of MW 300-2,000; and (6) formaldoxime; for 1-10 hour at 50°-95° C. in an aqueous medium; followed by; (E) 0-5.0 molar equivalents of a water-soluble, acid-generating, gelation-time-regulating agent, said water-soluble acid-generating, gelation-time-regulating agent selected from the group consisting of alkali metal and ammonium salts of fluoroboric acid and persulfurous acid, formaldehyde, glutaraldehyde, glyoxal, dimethyl maleate, dimethyl itaconate, triethyl citrate, ethyl acetate, sodium hexametaphosphate and sodium mono, di- or tribasic phosphate.