US4767169A
Expired / Lapsed
US
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Thin film waveguide electrooptic modulator
Assignee: Celanese Corp
•
Filing: 1987-02-26
•
Granted: 1988-08-30
•
Expires: 2007-02-26
Abstract
Abstract This invention provides a thin film waveguide electrooptic intensity modulation device. The thin film waveguide is an isotropic organic medium which exhibits nonlinear optical response. The device is adapted to modulate waveguided radiation by refractive index change commensurate with change in an applied electric field.
Inventors
- 👤 Chia-Chi Teng
- 👤 Dagobert E. Stuetz
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-26 17:23
CPC Classifications
G; G02; G02F; G02F1/00; G02F1/35; G02F1/355; G02F1/361; G02F1/3615; G02F1/01; G02F1/061; G02F1/065
Claims Analysis
Total Claims: 43
Claim 1
Independent Claim
146 words
A thin film waveguide electrooptic intensity modulation device comprising (1) a transparent optical waveguiding thin film on a supporting substrate, wherein the thin film comprises an organic medium which exhibits nonlinear optical response; (2) a pair of optical input-output coupling means which are structurally integrated with the waveguiding thin film for coupling linearly polarized coherent electromagnetic radiation to the said thin film, wherein the coupling means are in spaced positions such that an optical phase shift between transverse electric mode and transverse magnetic mode of waveguided electromagnetic radiation is an integral multiple of 2 π and the output radiation is linearly polarized; and (3) a pair of elongated strip electrodes parallel to the waveguiding direction and situated in an intermediate zone between the positioned coupling means, and said electrodes are in a spaced proximity for application of a uniform electric field to the thin film waveguide.
Claim 2
Dependent Claim
146 words
A thin film waveguide electrooptic intensity modulation device comprising (1) a transparent optical waveguiding thin film on a supporting substrate, wherein the thin film comprises an organic medium which exhibits nonlinear optical response; (2) a pair of optical input-output coupling means which are structurally integrated with the waveguiding thin film for coupling linearly polarized coherent electromagnetic radiation to the said thin film, wherein the coupling means are in spaced positions such that an optical phase shift between transverse electric mode and transverse magnetic mode of waveguided electromagnetic radiation is an integral multiple of 2 π and the output radiation is linearly polarized; and (3) a pair of elongated strip electrodes parallel to the waveguiding direction and situated in an intermediate zone between the positioned coupling means, and said electrodes are in a spaced proximity for application of a uniform electric field to the thin film waveguide.
Claim 3
Dependent Claim
250 words
A thin film waveguide electrooptic intensity modulation device comprising (1) a transparent optical waveguiding thin film on a supporting substrate, wherein the thin film comprises an isotropic organic polymer medium which exhibits nonlinear optical response, and the waveguiding thin film is laminated between two cladding layers which have a lower index of refraction than the cladded thin film; (2) a pair of optical input-output coupling means which are structurally integrated with the waveguiding thin film for coupling linearly polarized coherent electromagnetic radiation to the said thin film, wherein the coupling means are in spaced positions such that an optical phase shift between transverse electric mode and transverse magnetic mode of waveguided electromagnetic radiation is an integral multiple of 2 π and the output radiation is linearly polarized; and (3) a pair of elongated strip electrodes parallel to the waveguiding direction and situated in an intermediate zone between the positioned coupling means, and said electrodes are connected to a voltage source and are in a spaced proximity for application of a uniform electric field to the thin film waveguide; and wherein the device is adapted to modulate waveguided radiation by refractive index change in the waveguide medium in accordance with the following equations: ##EQU10## where Γ is the radiation phase retardation; Γ o is the radiation phase retardation by the thin film waveguide medium; δφ is the radiation phase shift caused by the applied voltage; I is the input electromagnetic radiation signal; and I o is the output electromagnetic radiation signal.
Claim 4
Dependent Claim
250 words
A thin film waveguide electrooptic intensity modulation device comprising (1) a transparent optical waveguiding thin film on a supporting substrate, wherein the thin film comprises an isotropic organic polymer medium which exhibits nonlinear optical response, and the waveguiding thin film is laminated between two cladding layers which have a lower index of refraction than the cladded thin film; (2) a pair of optical input-output coupling means which are structurally integrated with the waveguiding thin film for coupling linearly polarized coherent electromagnetic radiation to the said thin film, wherein the coupling means are in spaced positions such that an optical phase shift between transverse electric mode and transverse magnetic mode of waveguided electromagnetic radiation is an integral multiple of 2 π and the output radiation is linearly polarized; and (3) a pair of elongated strip electrodes parallel to the waveguiding direction and situated in an intermediate zone between the positioned coupling means, and said electrodes are connected to a voltage source and are in a spaced proximity for application of a uniform electric field to the thin film waveguide; and wherein the device is adapted to modulate waveguided radiation by refractive index change in the waveguide medium in accordance with the following equations: ##EQU10## where Γ is the radiation phase retardation; Γ o is the radiation phase retardation by the thin film waveguide medium; δφ is the radiation phase shift caused by the applied voltage; I is the input electromagnetic radiation signal; and I o is the output electromagnetic radiation signal.
Claim 5
Dependent Claim
270 words
A thin film waveguide electrooptic intensity modulation device comprising (1) a transparent optical waveguiding thin film on a supporting substrate, wherein the thin film comprises an isotropic organic polymer medium which exhibits nonlinear optical response, and the waveguiding thin film is laminated between two cladding layers which have a lower index of refraction than the cladded thin film; (2) a pair of optical input-output coupling means which are structurally integrated with the waveguiding thin film for coupling linearly polarized coherent electromagnetic radiation to the said thin film, wherein the coupling means are in spaced positions such that an optical phase shift between transverse electric mode and transverse magnetic mode of waveguided electromagnetic radiation is an integral multiple of 2 π and the output radiation is linearly polarized; (3) a pair of elongated strip electrodes parallel to the waveguiding direction and situated in an intermediate zone between the positioned coupling means, and said electrodes are connected to a voltage source and are in a spaced proximity for application of a uniform electric field to the thin film waveguide; and wherein the device is adapted to modulate waveguided radiation by refractive index change in the waveguide medium in accordance with the following equations: ##EQU11## where Γ is the radiation phase retardation; Γ o is the radiation phase retardation by the thin film waveguide medium; δφ is the radiation phase shift caused by the applied voltage; I is the input electromagnetic radiation signal; I o is the output electromagnetic radiation signal; and wherein the device is in combination with (4) a linearly polarized coherent electromagnetic radiation generating means; and (5) a polarization-sensitive analyzer.
Claim 6
Dependent Claim
270 words
A thin film waveguide electrooptic intensity modulation device comprising (1) a transparent optical waveguiding thin film on a supporting substrate, wherein the thin film comprises an isotropic organic polymer medium which exhibits nonlinear optical response, and the waveguiding thin film is laminated between two cladding layers which have a lower index of refraction than the cladded thin film; (2) a pair of optical input-output coupling means which are structurally integrated with the waveguiding thin film for coupling linearly polarized coherent electromagnetic radiation to the said thin film, wherein the coupling means are in spaced positions such that an optical phase shift between transverse electric mode and transverse magnetic mode of waveguided electromagnetic radiation is an integral multiple of 2 π and the output radiation is linearly polarized; (3) a pair of elongated strip electrodes parallel to the waveguiding direction and situated in an intermediate zone between the positioned coupling means, and said electrodes are connected to a voltage source and are in a spaced proximity for application of a uniform electric field to the thin film waveguide; and wherein the device is adapted to modulate waveguided radiation by refractive index change in the waveguide medium in accordance with the following equations: ##EQU11## where Γ is the radiation phase retardation; Γ o is the radiation phase retardation by the thin film waveguide medium; δφ is the radiation phase shift caused by the applied voltage; I is the input electromagnetic radiation signal; I o is the output electromagnetic radiation signal; and wherein the device is in combination with (4) a linearly polarized coherent electromagnetic radiation generating means; and (5) a polarization-sensitive analyzer.
Claim 7
Dependent Claim
25 words
A waveguide electrooptic device in accordance with claim 3 wherein the thin film comprises a side chain liquid crystalline polymer which exhibits nonlinear optical response.
Claim 8
Dependent Claim
26 words
A waveguide electrooptic device in accordance with claim 3 wherein the thin film comprises a polymer host and a guest component which exhibits nonlinear optical response.
Claim 9
Dependent Claim
28 words
A waveguide electrooptic device in accordance with claim 3 wherein the thin film comprises a polymer host and a guest component, each of which exhibits nonlinear optical response.
Claim 10
Dependent Claim
20 words
A waveguide electrooptic device in accordance with claim 3 wherein the thin film exhibits second order nonlinear optical susceptibility χ.sup.(2).
Claim 11
Dependent Claim
20 words
A waveguide electrooptic device in accordance with claim 3 wherein the thin film exhibits third order nonlinear optical susceptibility χ.sup.(3).
Claim 12
Dependent Claim
18 words
A waveguide electrooptic device in accordance with claim 3 wherein the coupling means are a pair of prisms.
Claim 13
Dependent Claim
19 words
A waveguide electrooptic device in accordance with claim 3 wherein the coupling means are a pair of diffraction gratings.
Claim 14
Dependent Claim
30 words
A waveguide electrooptic device in accordance with claim 3 wherein the electrodes are situated in a spaced proximity, with one electrode on each opposing side of the thin film waveguide.
Claim 15
Dependent Claim
42 words
A waveguide electrooptic device in accordance with claim 3 wherein the electrodes when under an applied voltage develop an electric field in the thin film waveguide which modulates waveguided radiation by change in refractive index commensurate with change in the electric field.
Claim 16
Dependent Claim
17 words
A waveguide electrooptic device in accordance with claim 3 wherein the electromagnetic radiation is a laser beam.
Claim 17
Dependent Claim
35 words
A waveguide electrooptic device in accordance with claim 3 wherein the polarization-sensitive analyzer is a polarizer which is crossed relative to the polarization plane of waveguided radiation in the absence of a moderating electric field.
Claim 18
Dependent Claim
20 words
A waveguide electrooptic device in accordance with claim 3 wherein the device is in further combination with a photodetector means.
Claim 19
Dependent Claim
274 words
A thin film waveguide electrooptic intensity modulation device comprising (1) a transparent optical waveguiding thin film on a supporting substrate, wherein the thin film comprises an isotropic organic polymer medium which exhibits nonlinear optical response, and the waveguiding thin film is laminated between two cladding layers which have a lower index of refraction than the cladded thin film; (2) a pair of optical input-output coupling means which are structurally integrated with the waveguiding thin film for coupling linearly polarized coherent electromagnetic radiation to the said thin film, wherein the coupling means are in spaced positions such that an optical phase shift between transverse electric mode and transverse magnetic mode of waveguided electromagnetic radiation is an integral multiple of 2 π and the output radiation is linearly polarized; (3) a pair of elongated strip electrodes parallel to the waveguiding direction and situated in an intermediate zone between the positioned coupling means, and said electrodes are connected to a voltage source and are in a spaced proximity for application of a uniform electric field to the thin film waveguide: wherein the device is adapted to modulate waveguided radiation by refractive index change in the waveguide medium in accordance with the following equations: ##EQU12## where Γ is the radiation phase retardation; Γ o is the radiation phase retardation by the thin film waveguide medium; δφ is the radiation phase shift caused by the applied voltage; I is the input electromagnetic radiation signal; and I o is the output electromagnetic radiation signal; and wherein the device is in combination with (4) a linearly polarized coherent electromagnetic radiation generating means; (5) a polarization-sensitive analyzer; and (6) a photodetector means.
Claim 20
Dependent Claim
274 words
A thin film waveguide electrooptic intensity modulation device comprising (1) a transparent optical waveguiding thin film on a supporting substrate, wherein the thin film comprises an isotropic organic polymer medium which exhibits nonlinear optical response, and the waveguiding thin film is laminated between two cladding layers which have a lower index of refraction than the cladded thin film; (2) a pair of optical input-output coupling means which are structurally integrated with the waveguiding thin film for coupling linearly polarized coherent electromagnetic radiation to the said thin film, wherein the coupling means are in spaced positions such that an optical phase shift between transverse electric mode and transverse magnetic mode of waveguided electromagnetic radiation is an integral multiple of 2 π and the output radiation is linearly polarized; (3) a pair of elongated strip electrodes parallel to the waveguiding direction and situated in an intermediate zone between the positioned coupling means, and said electrodes are connected to a voltage source and are in a spaced proximity for application of a uniform electric field to the thin film waveguide: wherein the device is adapted to modulate waveguided radiation by refractive index change in the waveguide medium in accordance with the following equations: ##EQU12## where Γ is the radiation phase retardation; Γ o is the radiation phase retardation by the thin film waveguide medium; δφ is the radiation phase shift caused by the applied voltage; I is the input electromagnetic radiation signal; and I o is the output electromagnetic radiation signal; and wherein the device is in combination with (4) a linearly polarized coherent electromagnetic radiation generating means; (5) a polarization-sensitive analyzer; and (6) a photodetector means.
Claim 21
Dependent Claim
35 words
A waveguide electrooptic device in accordance with claim 16 wherein the thin film comprises an isotropic medium of a liquid crystalline polymer having a comb structure of mesogenic side chains which exhihit nonlinear optical response.
Claim 22
Dependent Claim
48 words
A waveguide electrooptic device in accordance with claim 16 wherein the thin film comprises an isotropic medium of a liquid crystalline polymer having a comb structure of mesogenic side chains which exhibit nonlinear optical response, and wherein the mesogenic side chains have a permanent external field-induced molecular alignment.
Claim 23
Dependent Claim
61 words
A waveguide electrooptic device in accordance with claim 16 wherein the thin film is centrosymmetric and exhibits a Kerr effect phase shift in accordance with the equation: ##EQU13## where l is the length of the electrode pair; λ is the optical wavelength; η 2 is the Kerr coefficient; V is the applied voltage; and d is the distance between the electrodes.
Claim 24
Dependent Claim
70 words
A waveguide electrooptic device in accordance with claim 16 wherein the thin film is noncentrosymmetric and exhibits a Pockels effect phase shift in accordance with the equation: ##EQU14## where l is the length of the electrode pair; λ is the optical wavelength: η is the index of refraction of the waveguide film; r is the Pockels coefficient; V is the applied voltage; and d is the distance between the electrodes.
Claim 25
Dependent Claim
26 words
A waveguide electrooptic device in accordance with claim 16 wherein the thin film comprises a polymer host, and a guest component which exhibits nonlinear optical response.
Claim 26
Dependent Claim
35 words
A waveguide electrooptic device in accordance with claim 16 wherein the thin film comprises a polymer host, and a guest component which exhibits nonlinear optical response and which has a permanent external field-induced molecular alignment.
Claim 27
Dependent Claim
23 words
A waveguide electrooptic device in accordance with claim 16 wherein the thin film comprises a polymer host and 2-methyl-4-nitroaniline as a guest component.
Claim 28
Dependent Claim
23 words
A waveguide electrooptic device in accordance with claim 16 wherein the thin film comprises a polymer host and 4-N,N-dimethylamino-4'-nitrostilbene as a guest component.
Claim 29
Dependent Claim
86 words
A waveguide electrooptic device in accordance with claim 16 wherein the thin film comprises a polymer host and a quinodimethane guest component corresponding to one of the formulae: ##STR3## where n is an integer with a value between about 0-3; R and R 1 are substituents selected from hydrogen and aliphatic, alicyclic and aromatic groups containing between about 1-20 carbon atoms, and at least one of the R substituents is an electron-donating group, and at least one of the R 1 substituents is an electron-withdrawing group.
Claim 30
Dependent Claim
23 words
A waveguide electrooptic device in accordance with claim 16 wherein the thin film comprises a polymer host and 7,7-di(n-hexyldecylamino)-8,8-dicyanoquinodimethane as a guest component.
Claim 31
Dependent Claim
23 words
A waveguide electrooptic device in accordance with claim 16 wherein the thin film comprises a polymer host and 13,13-di(n-hexadecylamino)-14,14-dicyano-4,5,9,10-tetrahydropyrenequinodimethane as a guest component.
Claim 32
Dependent Claim
19 words
A waveguide electrooptic device in accordance with claim 16 wherein the thin film comprises a polymer host and 11,11-di(n-hexadecylamino)-12,12-dicyano-2,6-naphthoquinodimethane.
Claim 33
Dependent Claim
19 words
A waveguide electrooptic device in accordance with claim 16 wherein at least one of the cladding layers is glass.
Claim 34
Dependent Claim
21 words
A waveguide electrooptic device in accordance with claim 16 wherein at least one of the cladding layers is an organic polymer.
Claim 35
Dependent Claim
18 words
A waveguide electrooptic device in accordance with claim 16 wherein the coupling means are a pair of prisms.
Claim 36
Dependent Claim
19 words
A waveguide electrooptic device in accordance with claim 16 wherein the coupling means are a pair of diffraction gratings.
Claim 37
Dependent Claim
30 words
A waveguide electrooptic device in accordance with claim 16 wherein the electrodes are situated in a spaced proximity with one electrode on each opposing side of the thin film waveguide.
Claim 38
Dependent Claim
19 words
A waveguide electrooptic device in accordance with claim 16 wherein the electrodes are connected to a DC voltage source.
Claim 39
Dependent Claim
19 words
A waveguide electrooptic device in accordance with claim 16 wherein the electrodes are connected to an AC voltage source.
Claim 40
Dependent Claim
17 words
A waveguide electrooptic device in accordance with claim 16 wherein the electromagnetic radiation is a laser beam.
Claim 41
Dependent Claim
35 words
A waveguide electrooptic device in accordance with claim 16 wherein the polarization-sensitive analyzer is a polarizer which is crossed relative to the polarization plane of waveguided radiation in the absence of a moderating electric field.
Claim 42
Dependent Claim
16 words
A waveguide electrooptic device in accordance with claim 16 wherein the photodetector means is a photodiode.
Claim 43
Dependent Claim
18 words
A waveguide electrooptic device in accordance with claim 16 wherein the photodetector means is an optical power meter.
References Cited (Backward Citations)
US3586872A
Cited
US3868589A
Cited
US3810688A
Cited
US3923374A
Cited
US3951513A
Cited
US4515429A
Cited
US4624872A
Cited
US4607095A
Cited
US4655554A
Cited
US4605869A
Cited
US4707303A
Cited
US4694066A
Cited
US4694048A
Cited
US4711532A
Cited
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