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US4707303A Expired / Lapsed US ⏱️ 0.0 years remaining

High performance nonlinear optical substrates

Assignee: CNA Holdings LLC
•
Filing: 1985-06-25
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Granted: 1987-11-17
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Expires: 2005-06-25
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Abstract

Abstract In one embodiment this invention provides a high performance nonlinear optical substrate which comprises a transparent organic polymer film containing an array of charge asymmetric molecules such as 13,13-diamino-14,14-dicyanodiphenoquinodimethane: ##STR1##

Inventors

  • 👤 Alan Buckley
  • 👤 Eui W. Choe
  • 👤 Dagobert E. Stuetz
  • 👤 Anthony F. Garito

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-27 06:41
CPC Classifications
C; C07; C07D; C07D498/00; C07D498/02; C07D498/04; C07C; C07C255/00; G; G02; G02F; G02F1/00; G02F1/35; G02F1/355; G02F1/361; G02F1/3611; C07C2603/00; C07C2603/02; C07C2603/40; C07C2603/42; C07C2603/50

Claims Analysis

Total Claims: 21
Claim 1
Independent Claim 49 words
A nonlinear optical organic substrate exhibiting a χ.sup.(2) susceptibility of at least about 3×10 -6 esu, an absence of interfering fluorescence in the wavelength range between about 0.3-3 μm, an optical loss less than about 0.1 decibel per kilometer, and a response time less than about 10 -13 second.
Claim 2
Dependent Claim 49 words
A nonlinear optical organic substrate exhibiting a χ.sup.(2) susceptibility of at least about 3×10 -6 esu, an absence of interfering fluorescence in the wavelength range between about 0.3-3 μm, an optical loss less than about 0.1 decibel per kilometer, and a response time less than about 10 -13 second.
Claim 3
Dependent Claim 57 words
A nonlinear optical organic substrate exhibiting a χ.sup.(2) susceptibility of at least about 3×10 -6 esu, an absence of interfering fluorescence in the wavelength range between about 0.3-3 μm, an optical loss less than about 0.1 decibel per kilometer, a response time less than about 10 -13 second, and phase matching of fundamental and second harmonic frequencies.
Claim 4
Dependent Claim 57 words
A nonlinear optical organic substrate exhibiting a χ.sup.(2) susceptibility of at least about 3×10 -6 esu, an absence of interfering fluorescence in the wavelength range between about 0.3-3 μm, an optical loss less than about 0.1 decibel per kilometer, a response time less than about 10 -13 second, and phase matching of fundamental and second harmonic frequencies.
Claim 5
Dependent Claim 64 words
A nonlinear optical organic substrate exhibiting a χ.sup.(2) susceptibility of at least about 3×10 -6 esu, an absence of interfering fluorescence in the wavelength range between about 0.3-3 μm, an optical loss less than about 0.1 decibel per kilometer, a response time less than about 10 -13 second, phase matching of fundamental and second harmonic frequencies, and a dielectric constant less than about 5.
Claim 6
Dependent Claim 64 words
A nonlinear optical organic substrate exhibiting a χ.sup.(2) susceptibility of at least about 3×10 -6 esu, an absence of interfering fluorescence in the wavelength range between about 0.3-3 μm, an optical loss less than about 0.1 decibel per kilometer, a response time less than about 10 -13 second, phase matching of fundamental and second harmonic frequencies, and a dielectric constant less than about 5.
Claim 7
Dependent Claim 25 words
A nonlinear optical organic substrate in accordance with claim 3 wherein the substrate comprises a noncentrosymmetric configuration of aligned molecules having a diphenoquinodimethane conjugated structure.
Claim 8
Dependent Claim 21 words
A nonlinear optical organic substrate in accordance with claim 4 wherein the diphenoquinodimethane molecules are aligned in a host liquid medium.
Claim 9
Dependent Claim 21 words
A nonlinear optical organic substrate in accordance with claim 4 wherein the diphenoquinodimethane molecules are aligned in a host solid medium.
Claim 10
Dependent Claim 30 words
A nonlinear optical organic substrate in accordance with claim 4 wherein the aligned molecules correspond to the structure: ##STR10## where R is a substituent selected from hydrogen and alkyl groups.
Claim 11
Dependent Claim 30 words
A nonlinear optical organic substrate in accordance with claim 4 wherein the aligned molecules correspond to the structure: ##STR11## where R is a substituent selected from hydrogen and alkyl groups.
Claim 12
Dependent Claim 19 words
An optically transparent medium comprising a noncentrosymmetric or centrosymmetric array of molecules having a charge asymmetric diphenoquinodimethane conjugated structure.
Claim 13
Dependent Claim 19 words
An optically transparent medium comprising a noncentrosymmetric or centrosymmetric array of molecules having a charge asymmetric diphenoquinodimethane conjugated structure.
Claim 14
Dependent Claim 13 words
An optically transparent medium comprising a noncentrosymmetric or centrosymmetric configuration of 13,13-diamino-14,14-dicyanodiphenoquinodimethane molecules.
Claim 15
Dependent Claim 13 words
An optically transparent medium comprising a noncentrosymmetric or centrosymmetric configuration of 13,13-diamino-14,14-dicyanodiphenoquinodimethane molecules.
Claim 16
Dependent Claim 13 words
An optically transparent medium comprising a noncentrosymmetric or centrosymmetric configuration of 13,13-diamino-14,14-dicyano-4,5,9,10-tetrahydropyrenoquinodimethane molecules.
Claim 17
Dependent Claim 13 words
An optically transparent medium comprising a noncentrosymmetric or centrosymmetric configuration of 13,13-diamino-14,14-dicyano-4,5,9,10-tetrahydropyrenoquinodimethane molecules.
Claim 18
Dependent Claim 17 words
A nonlinear optical medium comprising a solid polymeric substrate having incorporated therein a distribution of 13,13-diamino-14,14-dicyanodiphenoquinodimethane molecules.
Claim 19
Dependent Claim 17 words
A nonlinear optical medium comprising a solid polymeric substrate having incorporated therein a distribution of 13,13-diamino-14,14-dicyanodiphenoquinodimethane molecules.
Claim 20
Dependent Claim 16 words
A nonlinear optical medium comprising a solid polymeric substrate having incorporated therein a distribution of 13,13-diamino-14,14-dicyano-4,5,9,10-tetrahydropyrenoquinodimethane.
Claim 21
Dependent Claim 16 words
A nonlinear optical medium comprising a solid polymeric substrate having incorporated therein a distribution of 13,13-diamino-14,14-dicyano-4,5,9,10-tetrahydropyrenoquinodimethane.

References Cited (Backward Citations)

US3371220A Cited
US3395329A Cited
US3895242A Cited
US3965375A Cited
US4199698A Cited
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US4428873A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1990-11-16 1991-05-18 1991-11-17 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1994-11-16 1995-05-18 1995-11-17 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1998-11-16 1999-05-18 1999-11-17 $7700.00 Window Closed / Lapsed

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