US4766027A — Method for making a ceramic multilayer structure …

Claim 1

Independent Claim 37 words

A thick film copper paste composition comprising an admixture of finely divided particles of metallic copper dispersed in a liquid organic medium comprising n-butyl methacrylate dissolved in an organic solvent in which other non-cellulosic polymers are insoluble.

Claim 2

Dependent Claim 37 words

A thick film copper paste composition comprising an admixture of finely divided particles of metallic copper dispersed in a liquid organic medium comprising n-butyl methacrylate dissolved in an organic solvent in which other non-cellulosic polymers are insoluble.

Claim 3

Dependent Claim 12 words

The composition of claim 1 in which the organic solvent is terpineol.

Claim 4

Dependent Claim 113 words

A multilayer electronic element comprising a plurality of patterned conductive layers of thick film copper paste comprising an admixture of finely divided particles, metallic copper dispersed in a liquid organic medium comprising n-butyl methacrylate dissolved in an organic solvent in which other acrylic polymers are insoluble, each of which layers is sandwiched between green ceramic layers comprising finely divided particles of ceramic dielectric material and nonreducing low melting glass dispersed in a solid matrix of thermoplastic acrylic polymer binder which has been fired in a buffered low oxygen containing atmosphere to effect the volatilizable of the organic medium of the thick film copper paste and the polymer matrix of the green ceramic layers.

Claim 5

Dependent Claim 113 words

A multilayer electronic element comprising a plurality of patterned conductive layers of thick film copper paste comprising an admixture of finely divided particles, metallic copper dispersed in a liquid organic medium comprising n-butyl methacrylate dissolved in an organic solvent in which other acrylic polymers are insoluble, each of which layers is sandwiched between green ceramic layers comprising finely divided particles of ceramic dielectric material and nonreducing low melting glass dispersed in a solid matrix of thermoplastic acrylic polymer binder which has been fired in a buffered low oxygen containing atmosphere to effect the volatilizable of the organic medium of the thick film copper paste and the polymer matrix of the green ceramic layers.

Claim 6

Independent Claim 232 words

A method of making an hermetic flux-sintered ceramic multilayer element having internal copper conductors using green ceramic layers comprising finely divided particles of ceramic dielectric material and nonreducing low melting glass dispersed in a solid matrix of thermoplastic acrylic polymer binder and a thick film copper conductive paste comprising finely divided particles of copper metal dispersed in a liquid organic medium comprising a non-cellulosic polymer binder dissolved in an organic solvent which is a nonsolvent for the thermoplastic polymer binder in the green ceramic layers, comprising the sequential steps of a. applying a pattern of conductive paste to an unpatterned surface of a first green ceramic layer; b. applying an unpatterned green ceramic layer to the patterned side of the first green ceramic layer; c. applying a pattern of conductive paste to an unpatterned surface of a further green ceramic layer; d. applying the patterned side of the further green ceramic layer of step c. to an outer surface of the composite structure of step b. to form a multilayer structure comprising a plurality of conductive pattern layers sandwiched between layers of green ceramic; e. optionally repeating the sequence of steps c. and d., and f. heating the composite structure of steps d. and e. in a buffered low oxygen-containing atmosphere for a time and at a temperature sufficient completely to remove the organics without oxidizing the copper in the conductive paste.

Claim 7

Independent Claim 232 words

A method of making an hermetic flux-sintered ceramic multilayer element having internal copper conductors using green ceramic layers comprising finely divided particles of ceramic dielectric material and nonreducing low melting glass dispersed in a solid matrix of thermoplastic acrylic polymer binder and a thick film copper conductive paste comprising finely divided particles of copper metal dispersed in a liquid organic medium comprising a non-cellulosic polymer binder dissolved in an organic solvent which is a nonsolvent for the thermoplastic polymer binder in the green ceramic layers, comprising the sequential steps of a. applying a pattern of conductive paste to an unpatterned surface of a first green ceramic layer; b. applying an unpatterned green ceramic layer to the patterned side of the first green ceramic layer; c. applying a pattern of conductive paste to an unpatterned surface of a further green ceramic layer; d. applying the patterned side of the further green ceramic layer of step c. to an outer surface of the composite structure of step b. to form a multilayer structure comprising a plurality of conductive pattern layers sandwiched between layers of green ceramic; e. optionally repeating the sequence of steps c. and d., and f. heating the composite structure of steps d. and e. in a buffered low oxygen-containing atmosphere for a time and at a temperature sufficient completely to remove the organics without oxidizing the copper in the conductive paste.

Claim 8

Independent Claim 230 words

A method of making an hermetic flux-sintered ceramic multilayer element having internal copper conductors using green ceramic layers, comprising finely divided particles of ceramic dielectric material and nonreducing low-melting glass dispersed in a solid matrix of thermoplastic acrylic polymer binder and a thick film copper conductive paste comprising finely divided particles of copper metal dispersed in a liquid organic medium comprising a non-cellulosic binder dissolved in an organic solvent which is a nonsolvent for the thermoplastic polymer binder in the green ceramic layers, comprising the sequential steps of a. applying a pattern of conductive paste to an unpatterned surface of a first green ceramic layer; b. applying an unpatterned green ceramic layer to the patterned side of the first green ceramic layer; c. applying a pattern of conductive paste to an unpatterned outer surface of the composite structure of step b.; d. applying an unpatterned green ceramic layer to a patterned outer surface of the composite structure of step c. to form a multilayer structure comprising a plurality of conductive pattern layers sandwiched between layers of green ceramic, and e. repeating the sequence of steps c. and d. and f. heating the composite structure of steps c. and d. in a buffered low oxygen-containing atmosphere for a time and at a temperature and oxygen partial pressure sufficient completely to remove the organics without oxidizing the copper in the conductive paste.

Claim 9

Independent Claim 230 words

A method of making an hermetic flux-sintered ceramic multilayer element having internal copper conductors using green ceramic layers, comprising finely divided particles of ceramic dielectric material and nonreducing low-melting glass dispersed in a solid matrix of thermoplastic acrylic polymer binder and a thick film copper conductive paste comprising finely divided particles of copper metal dispersed in a liquid organic medium comprising a non-cellulosic binder dissolved in an organic solvent which is a nonsolvent for the thermoplastic polymer binder in the green ceramic layers, comprising the sequential steps of a. applying a pattern of conductive paste to an unpatterned surface of a first green ceramic layer; b. applying an unpatterned green ceramic layer to the patterned side of the first green ceramic layer; c. applying a pattern of conductive paste to an unpatterned outer surface of the composite structure of step b.; d. applying an unpatterned green ceramic layer to a patterned outer surface of the composite structure of step c. to form a multilayer structure comprising a plurality of conductive pattern layers sandwiched between layers of green ceramic, and e. repeating the sequence of steps c. and d. and f. heating the composite structure of steps c. and d. in a buffered low oxygen-containing atmosphere for a time and at a temperature and oxygen partial pressure sufficient completely to remove the organics without oxidizing the copper in the conductive paste.

Claim 10

Independent Claim 219 words

A method for making an hermetic flux-sintered ceramic multilayer element having internal copper electrodes comprising the sequential steps of: a. to an unpatterned surface of a first greeen ceramic layer comprised of finely divided particles of ceramic dielectric material dispersed in a solid matrix of thermoplastic acrylic polymer binder, applying a pattern of thick film conductive paste comprising finely divided particles of copper metal dispersed in a liquid organic medium comprising a non-cellulosic polymer binder dissolved in an organic solvent which is a nonsolvent for the thermoplastic polymer binder of the green ceramic tape; b. applying an unpatterned green ceramic layer to the patterned side of the first green ceramic layer; c. applying a pattern of conductive paste to an unpatterned surface of a further green ceramic layer; d. applying the patterned side of the further green ceramic layer of step c. to an outer surface of the composite structure of step b. to form a multilayer structure comprising a plurality of conductive pattern layers sandwiched between layers of green ceramic; e. optionally repeating the sequence of steps c. and d., and f. heating the composite structure of steps d. and e. in a buffered low oxygen-containing atmosphere for a time and at a temperature sufficient completely to remove the organics without oxidizing the copper in the conductive paste.

Claim 11

Independent Claim 219 words

A method for making an hermetic flux-sintered ceramic multilayer element having internal copper electrodes comprising the sequential steps of: a. to an unpatterned surface of a first greeen ceramic layer comprised of finely divided particles of ceramic dielectric material dispersed in a solid matrix of thermoplastic acrylic polymer binder, applying a pattern of thick film conductive paste comprising finely divided particles of copper metal dispersed in a liquid organic medium comprising a non-cellulosic polymer binder dissolved in an organic solvent which is a nonsolvent for the thermoplastic polymer binder of the green ceramic tape; b. applying an unpatterned green ceramic layer to the patterned side of the first green ceramic layer; c. applying a pattern of conductive paste to an unpatterned surface of a further green ceramic layer; d. applying the patterned side of the further green ceramic layer of step c. to an outer surface of the composite structure of step b. to form a multilayer structure comprising a plurality of conductive pattern layers sandwiched between layers of green ceramic; e. optionally repeating the sequence of steps c. and d., and f. heating the composite structure of steps d. and e. in a buffered low oxygen-containing atmosphere for a time and at a temperature sufficient completely to remove the organics without oxidizing the copper in the conductive paste.

Claim 12

Independent Claim 218 words

A method for making an hermetic flux-sintered ceramic multilayer element having internal copper electrodes comprising the sequential steps of: a. to an unpatterned surface of a first green ceramic layer comprised of finely divided particles of ceramic dielectric material dispersed in a solid matrix of thermoplastic acrylic polymer binder, applying a pattern of thick film conductive paste comprising finely divided particles of copper metal dispersed in a liquid organic medium comprising a non-cellulosic polymer binder dissolved in an organic solvent which is a nonsolvent for the thermoplastic polymer binder of the green ceramic tape; b. applying an unpatterned green ceramic layer to the patterned side of the first green ceramic layer; c. applying a pattern of conductive paste to an unpatterned outer surface of the composite structure of step b.; d. applying an unpatterned green ceramic layer to a patterned outer surface of the composite structure of step c. to form a multilayer structure comprising a plurality of conductive pattern layers sandwiched between layers of green ceramic; e. repeating the sequence of steps c. and d.; and f. heating the composite structure of steps c. and d. in a buffered low oxygen-containing atmosphere for a time and at a temperature and oxygen partial pressure sufficient completely to remove the organics without oxidizing the copper in the conductive paste.

Claim 13

Independent Claim 218 words

A method for making an hermetic flux-sintered ceramic multilayer element having internal copper electrodes comprising the sequential steps of: a. to an unpatterned surface of a first green ceramic layer comprised of finely divided particles of ceramic dielectric material dispersed in a solid matrix of thermoplastic acrylic polymer binder, applying a pattern of thick film conductive paste comprising finely divided particles of copper metal dispersed in a liquid organic medium comprising a non-cellulosic polymer binder dissolved in an organic solvent which is a nonsolvent for the thermoplastic polymer binder of the green ceramic tape; b. applying an unpatterned green ceramic layer to the patterned side of the first green ceramic layer; c. applying a pattern of conductive paste to an unpatterned outer surface of the composite structure of step b.; d. applying an unpatterned green ceramic layer to a patterned outer surface of the composite structure of step c. to form a multilayer structure comprising a plurality of conductive pattern layers sandwiched between layers of green ceramic; e. repeating the sequence of steps c. and d.; and f. heating the composite structure of steps c. and d. in a buffered low oxygen-containing atmosphere for a time and at a temperature and oxygen partial pressure sufficient completely to remove the organics without oxidizing the copper in the conductive paste.

Claim 14

Dependent Claim 18 words

The method of either claim 6 or 7 in which the green ceramic layers are ceramic green tapes.

Claim 15

Dependent Claim 19 words

The method of either claim 6 or 7 in which the green ceramic layers are deposited by wet processing.

Claim 16

Dependent Claim 18 words

The method of either claim 6 or 7 in which the non-cellulosic polymer binder is an acrylic polymer.

Claim 17

Dependent Claim 31 words

The method of either claim 6 or 7 in step a. of which the conductive paste is applied to a substrate comprising a plurality of laminated layers of green ceramic layers.

Claim 18

Dependent Claim 42 words

The method of either claim 6 or 7 in which at least one layer of unpatterned green ceramic is interposed by application upon the unpatterned outer surface of the composite structure of step b. prior to applying the conductive paste pattern thereon.

Claim 19

Dependent Claim 18 words

The method of claim 6 or 7 wherein the multilayer structure is a substrate for mounting electronic components.

Claim 20

Dependent Claim 15 words

The method of claim 6 or 7 wherein the multilayer structure is a ceramic capacitor.

Claim 21

Dependent Claim 20 words

The method of claim 6 or 7 wherein the multilayer structure is a substrate having internal capacitor and resistor layers.

Claim 22

Dependent Claim 54 words

The method of claim 6 or 7 wherein said finely divided ceramic dielectric material is selected from Al 2 O 3 , SiO 2 , MgO, ZnO and mixtures and compounds thereof, and alkaline metal titanates such as BaTiO 3 , SrTiO 3 , CaTiO 3 and MgTiO 3 and mixtures and compounds thereof.

Claim 23

Dependent Claim 64 words

The method of claim 6 or 7 wherein the low melting flux consists essentially of a glass forming oxide selected from B 2 O 3 , SiO 2 , GeO 2 , P 2 O 5 and precursors and mixtures thereof, and modifying oxides selected from Li 2 O, ZnO, Al 2 O 3 , BaO, CaO, MgO, SrO and precursors and mixtures thereof.

Claim 24

Dependent Claim 30 words

The method of claim 6 or 7 wherein the thermoplastic organic binder in the green ceramic layers is selected from a methyl methacrylate, ethyl methacrylate, methyl acrylate and mixtures thereof.

Claim 25

Dependent Claim 16 words

The method of claim 5 wherein the acrylic binder in the copper paste is butyl methacrylate.

Claim 26

Dependent Claim 19 words

The method of claim 6 or 7 wherein the solvent for the binder in the copper paste is terpineol.

Claim 27

Dependent Claim 51 words

The method of claim 6 wherein the dry buffered gas mixture is N 2 +CO 2 +H 2 , the ratio of N 2 to CO 2 +H 2 being not more than 10, and the ratio of CO 2 to H 2 being in the range of 10 to 150.

Claim 28

Dependent Claim 23 words

The method of claim 6 wherein the temperature is 850-1080 C. and the heating and soak time is not more than 5 hours.

Annuity Stage	Window Opens	Payment Deadline	Surcharge Period Until	Estimated Fee	Status
3.5 Years (Year 4)	1991-08-23	1992-02-22	1992-08-23	$2000.00	Window Closed / Lapsed
7.5 Years (Year 8)	1995-08-23	1996-02-22	1996-08-23	$3760.00	Window Closed / Lapsed
11.5 Years (Year 12)	1999-08-23	2000-02-22	2000-08-23	$7700.00	Window Closed / Lapsed

Method for making a ceramic multilayer structure having internal copper conductors

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