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US4764576A
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Silicone-based coating composition for surface-releasing film
Assignee: Shin-Etsu Chemical Co Ltd
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Filing: 1987-08-25
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Granted: 1988-08-16
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Expires: 2007-08-25
Abstract
Abstract The inventive silicon-based coating composition provides an antistatic surface-releasing coating layer on a plastic film without the need of any antistatic undercoating. The coating composition comprises, in addition to the conventional ingredients in similar coating compositions including a vinyl-containing organopolysiloxane, an organohydrogenpolysiloxane and a platinum catalyst, a salt, e.g. nitrate and perchlorate, of a metal of the Ist, IInd or VIIIth Group of the Periodic Table and a specific organopolysiloxane having at least one per molecule of alkanolic pendant groups of the formula HO(CH2CH2O)nCH2CH2CH2-, in which n is 1 to 9.
Inventors
- 👤 Masahiko Ogawa
- 👤 Yasuaki Hara
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-08 15:02
CPC Classifications
C; C08; C08K; C08K5/00; C08K5/0008; C08K5/0075; C08K3/00; C08K3/01; C08K3/017; C08L; C08L83/00; C08L83/04; C08L83/10; C08L83/12
Claims Analysis
Total Claims: 9
Claim 1
Independent Claim
222 words
A silicone-based surface-releasing coating composition which comprises, as uniformly mixed together: (a) 100 parts by weight of an organopolysiloxane of which from 0.1 to 5% in number of the organic groups bonded to the silicon atoms are alkenyl groups, the remainder of the organic groups being monovalent hydrocarbon groups free from aliphatic unsaturation; (b) from 0.1 to 10 parts by weight of an organohydrogenpolysiloxane having, in a molecule, at least three hydrogen atoms directly bonded to the silicon atoms; (c) from 0.1 to 1.0 part by weight of a salt of a metal selected from the class consisting of metals belonging to the First, Second and Eighth Groups in the Periodic Table; (d) from 0.1 to 10 parts by weight of an organopolysiloxane represented by the general formula R.sup.1.sub.a R.sup.2.sub.3-a Si--O--SiR.sup.1 R.sup.2).sub.p)O--SiR.sup.2.sub.2).sub.q O--SiR.sup.1.sub.b R.sup.2.sub.3 -b, in which R 2 is a monovalent hydrocarbon group, the subscripts a and b are each zero, 1, 2 or 3, the subscripts p and q are each zero or a positive integer not exceeding 100, the total of p+q being not exceeding 100, with the proviso that a+b+p is at least 1, and R 1 is a group represented by the formula HO(CH.sub.2 CH.sub.2 O).sub.n CH.sub.2 CH.sub.2 CH.sub.2 --, n being a positive integer not exceeding 9; and (e) a catalytic amount of a platinum compound.
Claim 2
Dependent Claim
222 words
A silicone-based surface-releasing coating composition which comprises, as uniformly mixed together: (a) 100 parts by weight of an organopolysiloxane of which from 0.1 to 5% in number of the organic groups bonded to the silicon atoms are alkenyl groups, the remainder of the organic groups being monovalent hydrocarbon groups free from aliphatic unsaturation; (b) from 0.1 to 10 parts by weight of an organohydrogenpolysiloxane having, in a molecule, at least three hydrogen atoms directly bonded to the silicon atoms; (c) from 0.1 to 1.0 part by weight of a salt of a metal selected from the class consisting of metals belonging to the First, Second and Eighth Groups in the Periodic Table; (d) from 0.1 to 10 parts by weight of an organopolysiloxane represented by the general formula R.sup.1.sub.a R.sup.2.sub.3-a Si--O--SiR.sup.1 R.sup.2).sub.p)O--SiR.sup.2.sub.2).sub.q O--SiR.sup.1.sub.b R.sup.2.sub.3 -b, in which R 2 is a monovalent hydrocarbon group, the subscripts a and b are each zero, 1, 2 or 3, the subscripts p and q are each zero or a positive integer not exceeding 100, the total of p+q being not exceeding 100, with the proviso that a+b+p is at least 1, and R 1 is a group represented by the formula HO(CH.sub.2 CH.sub.2 O).sub.n CH.sub.2 CH.sub.2 CH.sub.2 --, n being a positive integer not exceeding 9; and (e) a catalytic amount of a platinum compound.
Claim 3
Dependent Claim
25 words
The silicone-based surface-releasing coating composition as claimed in claim 1 wherein the alkenyl group in the organopolysiloxane as the component (a) is a vinyl group.
Claim 4
Dependent Claim
61 words
The silicone-based surface-releasing coating composition as claimed in claim 1 wherein the organopolysiloxane as the component (a) is a diorganopolysiloxane represented by the general formula R.sub.3 Si--O--SiR.sub.2 --O).sub.r (SiViR--O).sub.s SiR.sub.3, in which Vi is a Vi is a vinyl group, R is a monovalent hydrocarbon group free from aliphatic unsaturation and the subscripts r and s are each a positive integer.
Claim 5
Dependent Claim
25 words
The silicone-based surface-releasing coating composition as claimed in claim 3 wherein at least 80% in number of the groups denoted by R are methyl groups.
Claim 6
Dependent Claim
37 words
The silicone-based surface-releasing coating composition as claimed in claim 1 wherein the metal in the component (c) is selected from the class consisting of lithium, sodium, copper, magnesium, calcium, strontium, barium, zinc, cadmium, iron, cobalt and nickel.
Claim 7
Dependent Claim
34 words
The silicone-based coating composition as claimed in claim 1 wherein the salt of a metal as the component (c) is selected from the class consisting of halide, nitrate, halogenate and perhalogenate of the metal.
Claim 8
Dependent Claim
26 words
The silicone-based surface-releasing coating composition as claimed in claim 6 wherein the salt of a metal as the component (c) is a perchlorate of the metal.
Claim 9
Dependent Claim
20 words
The silicone-based surface-releasing coating composition as claimed in claim 1 wherein the subscript n in the component (d) is 2.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1991-08-16 | 1992-02-15 | 1992-08-16 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1995-08-16 | 1996-02-15 | 1996-08-16 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1999-08-16 | 2000-02-15 | 2000-08-16 | $7700.00 | Window Closed / Lapsed |