US4677161A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Curable organosiloxane compositions
Assignee: DuPont Toray Specialty Materials KK
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Filing: 1986-05-12
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Granted: 1987-06-30
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Expires: 2006-05-12
Abstract
Abstract This invention provides self-adhering polyorganosiloxane compositions that cure by a platinum-catalyzed hydrosilation reaction. The compositions include as the adhesion promoter a polysiloxane comprising diorganohydrogensiloxy, alkoxy and SiO4/2 units.
Inventors
- 👤 Toshio Suzuki
- 👤 Akihiko Shirahata
- 👤 Naohiro Muramoto
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-05 06:27
CPC Classifications
C; C08; C08L; C08L83/00; C08L83/04; C08G; C08G77/00; C08G77/04; C08G77/12; C08G77/20
Claims Analysis
Total Claims: 12
Claim 1
Independent Claim
230 words
A curable organosiloxane composition comprising (a) a polyorganosiloxane having an average unit formula R a SiO.sub.(4-a)/2, where R represents a monovalent hydrocarbon radical, with the proviso that at least two of the R radicals in each molecule are lower alkenyl, and the value of a is from 0.8 to 2.2, inclusive; (b) a polyorganohydrogensiloxane containing at least 2 silicon-bonded hydrogen atoms per molecule and which is substantially free of silicon-bonded alkoxy groups and alkenyl radicals, the quantity of polyorganohydrogensiloxane being sufficient to provide a molar ratio of silicon-bonded hydrogen atoms in ingredients (b) and (d) to the moles of alkenyl radicals in ingredient (a) of from 0.5:1 to 3.0:1, respectively; (c) a platinum-containing hydrosilation catalyst in an amount equivalent to from 0.1 to 100 ppm by weight of platinum, based on the combined weight of ingredients (a), (b) and (c); (d) from about 1 to 20%, based on the weight of ingredient (a), of a polysiloxane represented by the general formula (HR' 2 SiO 1/2 ) b (R"O 1/2 ) c (SiO 4/2 ) d where R' and R" represent monovalent hydrocarbon radicals containing from 1 to 3 carbon atoms, the value of b/c in said general formula is from 0.2 to 2, inclusive, the value of b+c)d in said general formula is from 0.4 to 4, inclusive, and d represents a number greater than 0 and less than 30.
Claim 2
Dependent Claim
230 words
A curable organosiloxane composition comprising (a) a polyorganosiloxane having an average unit formula R a SiO.sub.(4-a)/2, where R represents a monovalent hydrocarbon radical, with the proviso that at least two of the R radicals in each molecule are lower alkenyl, and the value of a is from 0.8 to 2.2, inclusive; (b) a polyorganohydrogensiloxane containing at least 2 silicon-bonded hydrogen atoms per molecule and which is substantially free of silicon-bonded alkoxy groups and alkenyl radicals, the quantity of polyorganohydrogensiloxane being sufficient to provide a molar ratio of silicon-bonded hydrogen atoms in ingredients (b) and (d) to the moles of alkenyl radicals in ingredient (a) of from 0.5:1 to 3.0:1, respectively; (c) a platinum-containing hydrosilation catalyst in an amount equivalent to from 0.1 to 100 ppm by weight of platinum, based on the combined weight of ingredients (a), (b) and (c); (d) from about 1 to 20%, based on the weight of ingredient (a), of a polysiloxane represented by the general formula (HR' 2 SiO 1/2 ) b (R"O 1/2 ) c (SiO 4/2 ) d where R' and R" represent monovalent hydrocarbon radicals containing from 1 to 3 carbon atoms, the value of b/c in said general formula is from 0.2 to 2, inclusive, the value of b+c)d in said general formula is from 0.4 to 4, inclusive, and d represents a number greater than 0 and less than 30.
Claim 3
Dependent Claim
38 words
A composition according to claim 1 where the alkenyl radical present in ingredient (a) is a vinyl radical, at least 75 percent of the R radicals are methyl and the value of a is from 1.95 to 2.05.
Claim 4
Dependent Claim
41 words
A composition according to claim 2 where ingredient (a) is a vinyl terminated polydimethylsiloxane exhibiting a viscosity of from 0.05 to 100 Pa.s at 25° C. and the viscosity of ingredient (b) is from 0.001 to 50 Pa.s at 25° C.
Claim 5
Dependent Claim
33 words
A composition according to claim 3 where ingredient (b) is a dimethylsiloxane/methylhydrogensiloxane copolymer or a copolymer corresponding to the formula [H(CH 3 ) 2 SiO 1/2 ] 14 (SiO 4/2 ) 9 .
Claim 6
Dependent Claim
38 words
A composition according to claim 3 where ingredient (c) is present in an amount equivalent to a platinum content of from 1 to 20 parts per million, based on the combined weight of ingredients (a), (b), and (c).
Claim 7
Dependent Claim
44 words
A composition according to claim 3 where R' is methyl, R" is methyl or ethyl, the value of d is from 3 to 20 and the concentration of ingredient (d) is from 1 to 8 parts by weight per 100 parts of ingredient (a).
Claim 8
Dependent Claim
55 words
A composition according to claim 6 where ingredient (d) is selected from the group consisting of [H(CH 3 ) 2 SiO 1/2 ] 9 (CH 3 O 1/2 ) 9 (SiO 4/2 ) 12 , and [H(CH 3 ) 2 SiO 1/2 ] 8 (CH 3 O 1/2 ) 14 (SiO 4/2 ) 14 .
Claim 9
Dependent Claim
32 words
A composition according to claim 7 where said composition contains an inhibitor for the curing reaction selected from the group consisting of acetylene compounds, alkenyl group-containing compounds, hydrazines, triazoles, phosphines and mercaptans.
Claim 10
Dependent Claim
11 words
A composition according to claim 8 where said inhibitor is 3-methyl-1-butyn-3-ol.
Claim 11
Dependent Claim
31 words
A composition according to claim 3 where ingredient (a) includes a polysiloxane corresponding to the formula [CH 2 ═CH(CH 3 ) 2 SiO 1/2 ] 8 (SiO 4/2 ) 4 .
Claim 12
Dependent Claim
13 words
A composition according to claim 3 containing finely divided silica as a filler.
References Cited (Backward Citations)
US3699072A
Cited
US3892707A
Cited
JPS5028309A
Cited
JPS575836B2
Cited
US4082726A
Cited
JPS5539258B2
Cited
US4196273A
Cited
JPS5458755A
Cited
JPS5458756A
Cited
US4329273A
Cited
US4332844A
Cited
US4535141A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1990-06-29 | 1990-12-29 | 1991-06-30 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1994-06-29 | 1994-12-29 | 1995-06-30 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1998-06-29 | 1998-12-29 | 1999-06-30 | $7700.00 | Window Closed / Lapsed |