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US4762558A
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US
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Production of reactive sintered nickel aluminide material
Assignee: Rensselaer Polytechnic Institute
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Filing: 1987-05-15
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Granted: 1988-08-09
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Expires: 2007-05-15
Abstract
Abstract Reactive sintering process for producing a shaped body containing the nickel aluminide compound Ni3Al, which comprises sintering a compacted shaped mass containing an intimate mixture of substances, e.g. including elemental nickel powder and elemental aluminum powder in a stoichiometric atomic ratio generally corresponding to the compound Ni3Al, by heating the mass, e.g. in a vacuum, to an elevated sintering temperature, e.g. 500-750 DEG C., sufficiently to initiate an exothermic reaction, and at a heating rate sufficiently for consequent progressive generation of a transient liquid below the melting point of the aluminum powder and at the corresponding eutectic temperature, and upon initiation of the exothermic reaction continuing the sintering sufficiently to form a densified shaped body containing the nickel aluminide compound Ni3Al, and having a porosity of at most about 8%, or alternatively having an essentially fully densified structure where the heating is carried out under simultaneously applied mechanical pressure for hot isostatic compaction of the compacted shaped mass.
Inventors
- 👤 Randall M. German
- 👤 Animesh Bose
- 👤 David Sims
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-31 17:37
CPC Classifications
C; C22; C22C; C22C1/00; C22C1/04; C22C1/0433; C22C1/0441; B; B22; B22F; B22F3/00; B22F3/23
Claims Analysis
Total Claims: 54
Claim 1
Independent Claim
142 words
Reactive sintering process for producing a shaped body of the nickel aluminide compound Ni 3 Al, which comprises sintering a compacted shaped mass containing an intimate mixture of elemental nickel powder and elemental aluminum powder in a stoichiometric atomic ratio generally corresponding to the compound Ni 3 Al, by heating the mass in a substantially dry inert atmosphere to an elevated sintering temperature sufficiently to initiate an exothermic reaction, and at a heating rate sufficiently for consequent progressive generation of a transient liquid below the melting point of the aluminum powder and at the corresponding eutectic temperature, and upon initiation of the exothermic reaction continuing the sintering for a total sintering time of at least about 2 seconds and sufficiently to form a densified shaped body containing the nickel aluminide compound Ni 3 Al having a porosity of at most about 8%.
Claim 2
Dependent Claim
142 words
Reactive sintering process for producing a shaped body of the nickel aluminide compound Ni 3 Al, which comprises sintering a compacted shaped mass containing an intimate mixture of elemental nickel powder and elemental aluminum powder in a stoichiometric atomic ratio generally corresponding to the compound Ni 3 Al, by heating the mass in a substantially dry inert atmosphere to an elevated sintering temperature sufficiently to initiate an exothermic reaction, and at a heating rate sufficiently for consequent progressive generation of a transient liquid below the melting point of the aluminum powder and at the corresponding eutectic temperature, and upon initiation of the exothermic reaction continuing the sintering for a total sintering time of at least about 2 seconds and sufficiently to form a densified shaped body containing the nickel aluminide compound Ni 3 Al having a porosity of at most about 8%.
Claim 3
Dependent Claim
19 words
Process of claim 1 wherein the mass is heated to a sintering temperature of at most about 750° C.
Claim 4
Dependent Claim
17 words
Process of claim 1 wherein the mass is heated to a sintering temperature of about 550°-750° C.
Claim 5
Dependent Claim
17 words
Process of claim 1 wherein the mass is heated at a heating rate of about 3-30 K./min.
Claim 6
Dependent Claim
20 words
Process of claim 1 wherein the nickel powder is present in an amount of about 84.0-88.0 wt.% of the mixture.
Claim 7
Dependent Claim
20 words
Process of claim 1 wherein the nickel powder is present in an amount of about 86.0-87.3 wt% of the mixture.
Claim 8
Dependent Claim
32 words
Process of claim 1 wherein the nickel powder is present in a particle size of about 3 μm and the aluminum powder is present in a particle size of about 3-30 μm.
Claim 9
Dependent Claim
25 words
Process of claim 1 wherein upon initiation of the exothermic reaction the sintering is continued for a holding time of at most about 10-15 minutes.
Claim 10
Dependent Claim
15 words
Process of claim 1 wherein the inert atmosphere is a vacuum, dry hydrogen, or argon.
Claim 11
Dependent Claim
20 words
Process of claim 1 wherein the mass has been compacted at a compaction pressure of at least about 100 MPa.
Claim 12
Dependent Claim
14 words
Process of claim 1 wherein the nickel powder and aluminum powder comprise unmilled particles.
Claim 13
Dependent Claim
21 words
Process of claim 1 wherein the nickel powder and aluminum powder comprise particles which have been milled to form agglomerated clusters.
Claim 14
Dependent Claim
16 words
Process of claim 1 wherein the total sintering time is at most about one half hour.
Claim 15
Dependent Claim
31 words
Process of claim 1 wherein the particle size of the nickel powder is operatively equal to or greater than the particle size of the aluminum powder in the compacted shaped mass.
Claim 16
Dependent Claim
18 words
Process of claim 1 wherein at least one additional phase material is incorporated in the compacted shaped mass.
Claim 17
Dependent Claim
19 words
Process of claim 15 wherein the additional phase material includes at least one of ceramic particles, whiskers or fibers.
Claim 18
Dependent Claim
15 words
Process of claim 15 wherein the additional phase material includes at least one alloying ingredient.
Claim 19
Dependent Claim
18 words
Process of claim 17 wherein the alloying ingredient includes at least one of boron, chromium, hafnium and iron.
Claim 20
Dependent Claim
17 words
Process of claim 18 wherein the alloying ingredient is in the form of elemental metal fine particles.
Claim 21
Dependent Claim
24 words
Process of claim 18 wherein the alloying ingredient is in the form of fine particles of a prealloy of the alloying ingredient with nickel.
Claim 22
Dependent Claim
30 words
Process of claim 1 wherein the densified shape body is recovered and thereafter annealed by heat treatment in a substantially dry inert atmosphere to homogenize further the corresponding microstructure thereof.
Claim 23
Dependent Claim
192 words
Reactive sintering process for producing a shaped body of the nickel aluminide compound Ni 3 Al, which comprises sintering a compacted shaped mass of an initmate mixture of unmilled elemental nickel powder in a particle size of less than about 3 μm and unmilled elemental aluminum powder in a particle size of about 15 μm, in a stoichiometric atomic ratio generally corresponding to the compound Ni 3 Al and in which the nickel powder is present in an amount of about 85.5-87.5 wt.% of the mixture, by heating the mass in a substantially dry inert atmosphere to an elevated sintering temperature of about 550°-750° C. sufficiently to initiate an exothermic reaction, and at a heating rate of at least 3 K./min. for consequent progressive generation of a transient liquid below the melting point of the aluminum powder and at the corresponding eutectic temperature, and upon initiation of the exothermic reaction continuing the sintering for a total sintering time of at least about 2 seconds and at most about 10-15 minutes, to form a densified shaped body containing the nickel aluminide compound Ni 3 Al having a porosity of less than about 8%.
Claim 24
Dependent Claim
192 words
Reactive sintering process for producing a shaped body of the nickel aluminide compound Ni 3 Al, which comprises sintering a compacted shaped mass of an initmate mixture of unmilled elemental nickel powder in a particle size of less than about 3 μm and unmilled elemental aluminum powder in a particle size of about 15 μm, in a stoichiometric atomic ratio generally corresponding to the compound Ni 3 Al and in which the nickel powder is present in an amount of about 85.5-87.5 wt.% of the mixture, by heating the mass in a substantially dry inert atmosphere to an elevated sintering temperature of about 550°-750° C. sufficiently to initiate an exothermic reaction, and at a heating rate of at least 3 K./min. for consequent progressive generation of a transient liquid below the melting point of the aluminum powder and at the corresponding eutectic temperature, and upon initiation of the exothermic reaction continuing the sintering for a total sintering time of at least about 2 seconds and at most about 10-15 minutes, to form a densified shaped body containing the nickel aluminide compound Ni 3 Al having a porosity of less than about 8%.
Claim 25
Dependent Claim
9 words
Shaped body produced by the process of claim 1.
Claim 26
Dependent Claim
9 words
Shaped body produced by the process of claim 22.
Claim 27
Dependent Claim
25 words
Shaped body of claim 23 wherein said body contains ordered Ni 3 Al and is ductile, having an elongation in the range of about 1%.
Claim 28
Dependent Claim
25 words
Shaped body of claim 24 wherein said body contains ordered Ni 3 Al and is ductile, having an elongation in the range of about 1%.
Claim 29
Dependent Claim
146 words
Hot isostatic reactive sintering process for producing a fully dense shaped body of the nickel aluminide compound Ni 3 Al, which comprises cold isostatically compacting an intimate mixture of elemental nickel powder and elemental aluminum powder in a stoichiometric atomic ratio generally corresponding to the compound Ni 3 Al to form a compacted shaped mass, sealing the compacted shaped mass in a container which has been evacuated to form a sealed container containing the compacted shaped mass under vacuum, and hot isostatically compacting the mass by simultaneously heating and pressing the sealed container sufficiently to initiate an exothermic reaction and generate a transient liquid below the melting point of the aluminum powder and at the corresponding eutectic temperature, and upon initiation of the exothermic reaction continuing the heating and pressing sufficiently to form a fully densified shaped body containing the nickel aluminide compound Ni 3 Al.
Claim 30
Dependent Claim
146 words
Hot isostatic reactive sintering process for producing a fully dense shaped body of the nickel aluminide compound Ni 3 Al, which comprises cold isostatically compacting an intimate mixture of elemental nickel powder and elemental aluminum powder in a stoichiometric atomic ratio generally corresponding to the compound Ni 3 Al to form a compacted shaped mass, sealing the compacted shaped mass in a container which has been evacuated to form a sealed container containing the compacted shaped mass under vacuum, and hot isostatically compacting the mass by simultaneously heating and pressing the sealed container sufficiently to initiate an exothermic reaction and generate a transient liquid below the melting point of the aluminum powder and at the corresponding eutectic temperature, and upon initiation of the exothermic reaction continuing the heating and pressing sufficiently to form a fully densified shaped body containing the nickel aluminide compound Ni 3 Al.
Claim 31
Dependent Claim
19 words
Process of claim 27 wherein the mass is heated to a sintering temperature of at most about 750° C.
Claim 32
Dependent Claim
17 words
Process of claim 27 wherein the mass is heated to a sintering temperature of about 550°-750° C.
Claim 33
Dependent Claim
17 words
Process of claim 27 wherein the mass is heated at a heating rate of about 3-30 K./min.
Claim 34
Dependent Claim
20 words
Process of claim 27 wherein the nickel powder is present in an amount of about 84.0-88.0 wt.% of the mixture.
Claim 35
Dependent Claim
20 words
Process of claim 27 wherein the nickel powder is present in an amount of about 86.0-87.3 wt.% of the mixture.
Claim 36
Dependent Claim
32 words
Process of claim 27 wherein the nickel powder is present in a particle size of about 3 μm and the aluminum powder is present in a particle size of about 3-30 μm.
Claim 37
Dependent Claim
21 words
Process of claim 27 wherein the mass has been cold compacted at a compaction pressure of at least about 100 MPa.
Claim 38
Dependent Claim
14 words
Process of claim 27 wherein the nickel powder and aluminum powder comprise unmilled particles.
Claim 39
Dependent Claim
21 words
Process of claim 27 wherein the nickel powder and aluminum powder comprise particles which have been milled to form agglomerated clusters.
Claim 40
Dependent Claim
31 words
Process of claim 27 wherein the particle size of the nickel powder is operatively equal to or greater than the particle size of the aluminum powder in the compacted shaped mass.
Claim 41
Dependent Claim
18 words
Process of claim 27 wherein at least one additional phase material is incorporated in the compacted shaped mass.
Claim 42
Dependent Claim
19 words
Process of claim 38 wherein the additional phase material includes at least one of ceramic particles, whiskers of fibers.
Claim 43
Dependent Claim
15 words
Process of claim 38 wherein the additional phase material includes at least one alloying ingredient.
Claim 44
Dependent Claim
18 words
Process of claim 40 wherein the alloying ingredient includes at least one of boron, chromium, hafnium and iron.
Claim 45
Dependent Claim
17 words
Process of claim 41 wherein the alloying ingredient is in the form of elemental metal fine particles.
Claim 46
Dependent Claim
24 words
Process of claim 41 wherein the alloying ingredient is in the form of fine particles of a prealloy of the alloying ingredient with nickel.
Claim 47
Dependent Claim
17 words
Process of claim 27 wherein the container is a stainless steel container which is sealed by welding.
Claim 48
Dependent Claim
35 words
Process of claim 27 wherein the container is heated to a temperature of about 750° C. and pressed under a mechanical force of about 100 MPa for a holding time of about one half hour.
Claim 49
Dependent Claim
9 words
Shaped body produced by the process of claim 27.
Claim 50
Dependent Claim
110 words
Process which comprises sintering a compacted shaped mass of an intimate mixture including powder particles containing nickel and powder particles of elemental aluminum in a stoichiometric atomic ratio of the nickel and aluminum in the mixture generally corresponding to the compound Ni 3 Al, by heating the mass in a substantially dry inert negative pressure environment to an elevated sintering temperature sufficiently to initiate an exothermic reaction and generate a transient liquid below the melting point of the aluminum and at the corresponding eutectic temperature, and upon initiation of the exothermic reaction continuing the heating sufficiently to form a densified shaped body containing the nickel aluminide compound Ni 3 Al.
Claim 51
Dependent Claim
110 words
Process which comprises sintering a compacted shaped mass of an intimate mixture including powder particles containing nickel and powder particles of elemental aluminum in a stoichiometric atomic ratio of the nickel and aluminum in the mixture generally corresponding to the compound Ni 3 Al, by heating the mass in a substantially dry inert negative pressure environment to an elevated sintering temperature sufficiently to initiate an exothermic reaction and generate a transient liquid below the melting point of the aluminum and at the corresponding eutectic temperature, and upon initiation of the exothermic reaction continuing the heating sufficiently to form a densified shaped body containing the nickel aluminide compound Ni 3 Al.
Claim 52
Dependent Claim
32 words
Process of claim 47 wherein the heating is carried out without applying mechanical pressure to the mass, whereby to form a densified shaped body having a porosity of at most about 8%.
Claim 53
Dependent Claim
30 words
Process of claim 47 wherein the heating is carried out under simultaneously applied mechanical pressure for hot isostatic compaction of the mass, whereby to form a fully densified shaped body.
Claim 54
Dependent Claim
9 words
Shaped body produced by the process of claim 47.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1991-08-09 | 1992-02-08 | 1992-08-09 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1995-08-09 | 1996-02-08 | 1996-08-09 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1999-08-09 | 2000-02-08 | 2000-08-09 | $7700.00 | Window Closed / Lapsed |