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US4759900A Expired / Lapsed US ⏱️ 0.0 years remaining

Inhibition of radioactive cobalt deposition in water-cooled nuclear reactors

Assignee: General Electric Co
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Filing: 1986-08-27
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Granted: 1988-07-26
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Expires: 2006-08-27
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Abstract

Abstract Deposition of radioactive cobalt on the interior surfaces of a water-cooled nuclear reactor is inhibited or substantially prevented by the continuous injection of zinc oxide to the reactor water. The zinc oxide may be prepared in the form of a paste, a slurry, or a preformed aqueous solution.

Inventors

  • 👤 George E. Peterson
  • 👤 Randall N. Robinson
  • 👤 Carl P. Ruiz

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-02 21:52
CPC Classifications
G; G21; G21C; G21C17/00; G21C17/02; G21C17/022; G21C17/0225; G21C19/00; G21C19/28; Y; Y02; Y02E; Y02E30/00; Y02E30/30; Y10; Y10S; Y10S376/00; Y10S376/90; Y10S376/904

Claims Analysis

Total Claims: 30
Claim 1
Independent Claim 38 words
A method for inhibiting the deposition of radioactive cobalt in a water-bearing vessel of a water-cooled nuclear reactor, said method comprising: adding zinc oxide to water entering said water-bearing vessel, continuously during operation of said water-cooled nuclear reactor.
Claim 2
Independent Claim 38 words
A method for inhibiting the deposition of radioactive cobalt in a water-bearing vessel of a water-cooled nuclear reactor, said method comprising: adding zinc oxide to water entering said water-bearing vessel, continuously during operation of said water-cooled nuclear reactor.
Claim 3
Dependent Claim 34 words
A method in accordance with claim 1 in which the amount of zinc oxide added is selected to achieve a concentration of about 1 to about 1,000 ppb zinc oxide in said water-bearing vessel.
Claim 4
Dependent Claim 34 words
A method in accordance with claim 1 in which the amount of zinc oxide added is selected to achieve a concentration of about 10 to about 100 ppb zinc oxide in said water-bearing vessel.
Claim 5
Dependent Claim 36 words
A method in accordance with claim 1 in which said zinc oxide is added in the form of a member selected from the group consisting of a water-based slurry, a water-based paste and a water-based solution.
Claim 6
Dependent Claim 34 words
A method in accordance with claim 1 comprising adding said zinc oxide to a conduit selected from the group consisting of a recirculation water line and a feedwater line discharging into said water-bearing vessel.
Claim 7
Dependent Claim 21 words
A method in accordance with claim 5 comprising adding said zinc oxide to a recirculation loop branching off of said conduit.
Claim 8
Dependent Claim 53 words
A method in accordance with claim 5 in which flow through said conduit is maintained by a pump in said conduit, and said method comprises adding said zinc oxide to a recirculation loop drawing water from the discharge side of said pump and returning said water to the feed side of said pump.
Claim 9
Independent Claim 44 words
A method for inhibiting the deposition of radioactive cobalt in a water-bearing vessel of a water-cooled nuclear reactor, said method comprising: adding a paste comprised of zinc oxide and water to water entering said water-bearing vessel, continuously during operation of said water-cooled nuclear reactor.
Claim 10
Independent Claim 44 words
A method for inhibiting the deposition of radioactive cobalt in a water-bearing vessel of a water-cooled nuclear reactor, said method comprising: adding a paste comprised of zinc oxide and water to water entering said water-bearing vessel, continuously during operation of said water-cooled nuclear reactor.
Claim 11
Dependent Claim 26 words
A method in accordance with claim 8 in which the amount of zinc oxide in said paste is from about 25% to about 95% by weight.
Claim 12
Dependent Claim 25 words
A method in accordance with claim 8 in which the amount of zinc oxide in said paste is about 40% to about 80% by weight.
Claim 13
Dependent Claim 62 words
A method in accordance with claim 8 comprising adding said paste to a conduit supplying water to said water-bearing vessel at a flow rate maintained by a pump in said conduit, by mixing said paste with water passing through a recirculation loop drawing water from the discharge side of said pump and returning said water to the feed side of said pump.
Claim 14
Dependent Claim 60 words
A method in accordance with claim 11 in which said mixing of said paste with said water passing through said recirculation loop is achieved by continuously injecting said paste into said recirculation loop at an injection point therein from a motor-driven hydraulic cylinder, and passing said paste through a static mixer in said recirculation loop downstream of said injection point.
Claim 15
Independent Claim 107 words
A method for inhibiting the deposition of radioactive cobalt in a water-bearing vessel of a water-cooled nuclear reactor, said method comprising: (a) drawing water from a conduit supplying water to said water-bearing vessel and passing said drawn water through a recirculation loop discharging back into said conduit, continuously during the operation of said water-cooled nuclear reactor; and (b) continuously during said operation, injecting into said recirculation loop a paste comprised of zinc oxide at about 40% to about 80% by weight in water at an injection point at a rate selected to achieve a zinc oxide concentration of about 10 to about 100 ppb in said conduit.
Claim 16
Independent Claim 107 words
A method for inhibiting the deposition of radioactive cobalt in a water-bearing vessel of a water-cooled nuclear reactor, said method comprising: (a) drawing water from a conduit supplying water to said water-bearing vessel and passing said drawn water through a recirculation loop discharging back into said conduit, continuously during the operation of said water-cooled nuclear reactor; and (b) continuously during said operation, injecting into said recirculation loop a paste comprised of zinc oxide at about 40% to about 80% by weight in water at an injection point at a rate selected to achieve a zinc oxide concentration of about 10 to about 100 ppb in said conduit.
Claim 17
Independent Claim 42 words
A method for inhibiting the deposition of radioactive cobalt in a water-bearing vessel of a water-cooled nuclear reactor, said method comprising: adding an aqueous solution of zinc oxide to water entering said water-bearing vessel, continously during operation of said water-cooled nuclear reactor.
Claim 18
Independent Claim 42 words
A method for inhibiting the deposition of radioactive cobalt in a water-bearing vessel of a water-cooled nuclear reactor, said method comprising: adding an aqueous solution of zinc oxide to water entering said water-bearing vessel, continously during operation of said water-cooled nuclear reactor.
Claim 19
Dependent Claim 37 words
A method in accordance with claim 14 in which said aqueous solution is formed by passing a stream of water drawn from said water entering said water-bearing vessel through a receptacle containing said zinc oxide retained therein.
Claim 20
Dependent Claim 20 words
A method in accordance with claim 15 in which said solid zinc oxide is a bed of zinc oxide particles.
Claim 21
Dependent Claim 17 words
A method in accordance with claim 16 in which said zinc oxide particles are sintered zinc oxide.
Claim 22
Dependent Claim 61 words
A method in accordance with claim 14 in which said aqueous solution is formed in a recirculation loop branching off of a conduit supplying said water to said water-bearing vessel, said recirculation loop containing a bed of sintered zinc oxide particles, and said aqueous solution is formed by passing a stream of water drawn from said conduit through said recirculation loop.
Claim 23
Dependent Claim 50 words
A method in accordance with claim 18 in which the flow rate through said conduit is controlled by a pump, and said recirculation loop is positioned to draw water from a point at the discharge side of said pump and to discharge water at the feed side of said pump.
Claim 24
Independent Claim 43 words
A method for inhibiting the deposition of radioactive cobalt in a water-bearing vessel of a water-cooled nuclear reactor, said method comprising: adding a slurry of zinc oxide in water to water entering said water-bearing vessel, continuously during operation of said water-cooled nuclear reactor.
Claim 25
Independent Claim 43 words
A method for inhibiting the deposition of radioactive cobalt in a water-bearing vessel of a water-cooled nuclear reactor, said method comprising: adding a slurry of zinc oxide in water to water entering said water-bearing vessel, continuously during operation of said water-cooled nuclear reactor.
Claim 26
Dependent Claim 25 words
A method in accordance with claim 20 in which the zinc oxide content of said slurry is from about 0.1% to about 20% by weight.
Claim 27
Dependent Claim 25 words
A method in accordance with claim 20 in which the zinc oxide content of said slurry is from about 1% to about 5% by weight.
Claim 28
Dependent Claim 19 words
A method in accordance with claim 20 in which said zinc oxide in said slurry is fumed zinc oxide.
Claim 29
Dependent Claim 41 words
A method in accordance with claim 20 in which the rate of addition of said slurry to said water is selected to produce a zinc oxide content in the water of said water-bearing vessel of about 1 to about 1,000 ppb.
Claim 30
Dependent Claim 41 words
A method in accordance with claim 20 in which the rate of addition of said slurry to said water is selected to produce a zinc oxide content in the water of said water-bearing vessel of about 10 to about 100 ppb.

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1991-07-26 1992-01-25 1992-07-26 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1995-07-26 1996-01-25 1996-07-26 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1999-07-26 2000-01-25 2000-07-26 $7700.00 Window Closed / Lapsed

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