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US4758487A Expired / Lapsed US ⏱️ 0.0 years remaining

Electrostatographic imaging members with amorphous boron

Assignee: Xerox Corp
•
Filing: 1986-11-24
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Granted: 1988-07-19
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Expires: 2006-11-24
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Abstract

Abstract Disclosed is a photoresponsive imaging member comprised of certain hydrogenated, or halogenated amorphous boron.

Inventors

  • 👤 Milan Stolka
  • 👤 Damodar M. Pai

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-27 04:18
CPC Classifications
G; G03; G03G; G03G5/00; G03G5/02; G03G5/04; G03G5/08; G03G5/082; G03G5/08214

Claims Analysis

Total Claims: 43
Claim 1
Independent Claim 44 words
A photoresponsive imaging member comprised of a single photogenerating layer of hydrogenated amorphous boron with a band gap of from about 1 to about 3 electron volts, or halogenated amorphous boron with a band gap of from about 1 to about 3 electron volts.
Claim 2
Dependent Claim 44 words
A photoresponsive imaging member comprised of a single photogenerating layer of hydrogenated amorphous boron with a band gap of from about 1 to about 3 electron volts, or halogenated amorphous boron with a band gap of from about 1 to about 3 electron volts.
Claim 3
Dependent Claim 27 words
A photoresponsive imaging member in accordance with claim 1 wherein the halogenated amorphous boron has a band gap of from about 1 to about 3 electron volts.
Claim 4
Dependent Claim 23 words
A photoresponsive imaging member in accordance with claim 1 wherein there is selected a mixture of hydrogenated amorphous boron and halogenated amorphous boron.
Claim 5
Dependent Claim 15 words
A photoresponsive imaging member in accordance with claim 1 further including therein a supporting substrate.
Claim 6
Dependent Claim 37 words
A photoresponsive imaging member in accordance with claim 4 further including therein a supporting substrate and in contact therewith hydrogenated and/or halogenated amorphous boron with a band gap of from about 1 to about 3 electron volts.
Claim 7
Dependent Claim 27 words
A photoresponsive imaging member in accordance with claim 5 wherein the hydrogenated amorphous boron has a band gap of from about 1.4 to about 3 electron volts.
Claim 8
Dependent Claim 15 words
A photoresponsive imaging member in accordance with claim 5 wherein the supporting substrate is aluminum.
Claim 9
Dependent Claim 40 words
A photoresponsive imaging member in accordance with claim 5 wherein the amorphous boron has a ratio of 80 percent by weight of single bonds linking the boron atoms, and 20 percent by weight of double bonds linking the boron atoms.
Claim 10
Dependent Claim 43 words
A photoresponsive imaging member comprised of a single photogenerating layer of a supporting substrate, amorphous boron selected from the group consisting of hydrogenated amorphous boron and halogenated amorphous boron each with a band gap of from about 1 to about 3 electron volts.
Claim 11
Dependent Claim 43 words
A photoresponsive imaging member comprised of a single photogenerating layer of a supporting substrate, amorphous boron selected from the group consisting of hydrogenated amorphous boron and halogenated amorphous boron each with a band gap of from about 1 to about 3 electron volts.
Claim 12
Dependent Claim 26 words
A photoresponsive imaging member in accordance with claim 9 wherein the amorphous boron is of a band gap of from 1 to about 3 electron volts.
Claim 13
Dependent Claim 18 words
A photoresponsive imaging member in accordance with claim 9 wherein the overcoating layer is comprised of amorphous carbon.
Claim 14
Dependent Claim 18 words
A photoresponsive imaging member in accordance with claim 9 wherein the overcoating is silicon nitride or silicon carbide.
Claim 15
Dependent Claim 64 words
A photoresponsive imaging member comprised of a supporting substrate, a photogenerating layer of amorphous boron, and an overcoating layer wherein the amorphous boron is present in a transitional gradient with from about 10 atomic percent to about 30 atomic percent of hydrogen present in a direction from the supporting substrate to the interface situated between the amorphous boron photoconductive layer and the overcoating layer.
Claim 16
Dependent Claim 64 words
A photoresponsive imaging member comprised of a supporting substrate, a photogenerating layer of amorphous boron, and an overcoating layer wherein the amorphous boron is present in a transitional gradient with from about 10 atomic percent to about 30 atomic percent of hydrogen present in a direction from the supporting substrate to the interface situated between the amorphous boron photoconductive layer and the overcoating layer.
Claim 17
Dependent Claim 26 words
A photoresponsive imaging member in accordance with claim 13 wherein the amorphous boron is of a band gap of from 1 to about 3 electron volts.
Claim 18
Dependent Claim 22 words
A photoresponsive imaging member in accordance with claim 13 wherein the overcoating is comprised of silicon nitride, silicon carbide, or amorphous carbon.
Claim 19
Dependent Claim 63 words
A photoresponsive imaging member comprised of a photogenerating hydrogenated amorphous boron layer with a band gap of from about 1 to about 3 electron volts, and in contact therewith a photogenerating layer of hydrogenated amorphous silicon wherein said layer is of a thickness of from about 5 to about 25 microns and contains from about 5 to about 30 atomic percent of hydrogen.
Claim 20
Dependent Claim 63 words
A photoresponsive imaging member comprised of a photogenerating hydrogenated amorphous boron layer with a band gap of from about 1 to about 3 electron volts, and in contact therewith a photogenerating layer of hydrogenated amorphous silicon wherein said layer is of a thickness of from about 5 to about 25 microns and contains from about 5 to about 30 atomic percent of hydrogen.
Claim 21
Dependent Claim 18 words
A photoresponsive imaging member in accordance with claim 16 wherein there is further included therein a supporting substrate.
Claim 22
Dependent Claim 21 words
A photoresponsive imaging member in accordance with claim 16 wherein the amorphous boron has a band gap of 2 electron volts.
Claim 23
Dependent Claim 23 words
A photoresponsive imaging member in accordance with claim 16 wherein the photogenerating layer is comprised of an amorphous hydrogenated silicon and germanium alloy.
Claim 24
Dependent Claim 19 words
A photoresponsive imaging member in accordance with claim 16 wherein the photogenerating layer is doped with phosphorous or boron.
Claim 25
Dependent Claim 26 words
A photoresponsive imaging member in accordance with claim 16 wherein the amorphous silicon photogenerating layer is situated between a supporting substrate and the amorphous boron layer.
Claim 26
Dependent Claim 35 words
A photoresponsive imaging member in accordance with claim 16 wherein the amorphous boron layer is situated between the amorphous silicon photogenerating layer and a supporting substrate, and the member further includes thereover an overcoating layer.
Claim 27
Dependent Claim 27 words
A photoresponsive imaging member in accordance with claim 1 wherein hydrogen is present in an amount of from about 1 atomic percent to about 30 atomic percent.
Claim 28
Dependent Claim 27 words
A photoresponsive imaging member in accordance with claim 3 wherein hydrogen is present in an amount of from about 5 atomic percent to about 30 atomic percent.
Claim 29
Dependent Claim 27 words
A photoresponsive imaging member in accordance with claim 4 wherein hydrogen is present in an amount of from about 5 atomic percent to about 30 atomic percent.
Claim 30
Dependent Claim 27 words
A photoresponsive imaging member in accordance with claim 5 wherein hydrogen is present in an amount of from about 5 atomic percent to about 30 atomic percent.
Claim 31
Dependent Claim 32 words
A method of imaging which comprises generating a latent electrostatic image on the photoresponsive imaging member of claim 1; subsequently developing this image; and transferring the developed image to a suitable substrate.
Claim 32
Dependent Claim 20 words
A method of imaging in accordance with claim 32 wherein the photoresponsive imaging member is comprised of fluorinated amorphous boron.
Claim 33
Dependent Claim 27 words
A method of imaging in accordance with claim 27 wherein the photoresponsive imaging member is comprised of a mixture of amorphous hydrogenated boron and amorphous halogenated boron.
Claim 34
Dependent Claim 41 words
A method of imaging in accordance with claim 27 wherein the imaging member is comprised of a supporting substrate, and in contact therewith hydrogenated and/or fluorinated amorphous boron with a band gap of from about 1.4 to about 3 electron volts.
Claim 35
Dependent Claim 24 words
A method of imaging in accordance with claim 27 wherein there is further included in the imaging member a photogenerating layer of amorphous silicon.
Claim 36
Dependent Claim 16 words
A method of imaging in accordance with claim 27 wherein the selected supporting substrate is aluminum.
Claim 37
Dependent Claim 70 words
A photoresponsive imaging member consisting essentially of a supporting substrate, a photogenerating charge transport layer comprised of hydrogenated amorphous boron of from about 5 to about 30 atomic percent of hydrogen or halogen, which layer is with a thickness of from about 5 to about 25 microns; and wherein said hydrogenated amorphous boron or halogenated amorphous boron has a band gap of from about 1 to about 3 electron volts.
Claim 38
Dependent Claim 70 words
A photoresponsive imaging member consisting essentially of a supporting substrate, a photogenerating charge transport layer comprised of hydrogenated amorphous boron of from about 5 to about 30 atomic percent of hydrogen or halogen, which layer is with a thickness of from about 5 to about 25 microns; and wherein said hydrogenated amorphous boron or halogenated amorphous boron has a band gap of from about 1 to about 3 electron volts.
Claim 39
Dependent Claim 18 words
A photoresponsive imaging member in accordance with claim 33 wherein the band gap is about 2 electron volts.
Claim 40
Dependent Claim 87 words
A photoresponsive imaging member consisting essentially of a supporting substrate, a photoconductive layer comprised of hydrogenated amorphous boron or halogenated amorphous boron in a thickness of from about 5 to about 25 microns, each with a band gap of from about 1 to about 3 electron volts; and wherein the hydrogen or halogen is present in a gradient in an amount of from 0 percent in close proximity to supporting substrate, and extending to an amount of about 30 percent at the interface between the photoconductive layer.
Claim 41
Dependent Claim 87 words
A photoresponsive imaging member consisting essentially of a supporting substrate, a photoconductive layer comprised of hydrogenated amorphous boron or halogenated amorphous boron in a thickness of from about 5 to about 25 microns, each with a band gap of from about 1 to about 3 electron volts; and wherein the hydrogen or halogen is present in a gradient in an amount of from 0 percent in close proximity to supporting substrate, and extending to an amount of about 30 percent at the interface between the photoconductive layer.
Claim 42
Dependent Claim 28 words
A photoresponsive imaging member in accordance with claim 35 wherein the hydrogen or halogen is present in an amount of from about 5 to about 15 atomic percent.
Claim 43
Dependent Claim 30 words
A photoresponsive imaging member in accordance with claim 33 wherein the thickness of the hydrogenated amorphous boron or halogenated amorphous boron layer is from about 5 to about 25 microns.

References Cited (Backward Citations)

US4330182A Cited
US4330182B1 Cited
JPS57115558A Cited
US4525442A Cited
JPS5857135A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1991-07-19 1992-01-18 1992-07-19 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1995-07-19 1996-01-18 1996-07-19 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1999-07-19 2000-01-18 2000-07-19 $7700.00 Window Closed / Lapsed

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