US4752370A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Supported membrane/electrode structure combination wherein catalytically active particles are coated onto the membrane
Assignee: Dow Chemical Co
•
Filing: 1986-12-19
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Granted: 1988-06-21
•
Expires: 2006-12-19
Abstract
Abstract The invention is a membrane/electrode combination having an electrically conductive screen which has a first and a second face. The first face is substantially flat and the screen has a plurality of openings passing through it. The openings connect the first and the second faces of the screen and occupy up to about 75% of the surface area of each face of the electrically conductive screen. There is also an ion exchange membrane film having a first and a second face. The first face of the membrane film is attached to the first face of the electrically conductive screen, thereby leaving portions of the first face of the membrane film exposed through the openings in the electrically conductive screen. A plurality of catalytically active particles are disposed on the exposed portions of the first face of the membrane film and are in electrical and physical contact with the membrane and with the electrically conductive screen.
Inventors
- 👤 James W. McMichael
- 👤 Robert D. Door
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-25 22:52
CPC Classifications
H; H01; H01M; H01M4/00; H01M4/86; H01M4/90; H01M4/9091; C; C25; C25B; C25B9/00; C25B9/17; C25B9/19; C25B9/23; H01M4/92; H01M4/928; H01M8/00; H01M8/10; H01M8/1016; H01M8/1018; H01M8/102; H01M8/1023; H01M8/1039; Y; Y02; Y02E; Y02E60/00; Y02E60/30; Y02E60/50
Claims Analysis
Total Claims: 26
Claim 1
Independent Claim
153 words
A membrane/electrode combination comprising: (a) an electrically conductive screen having a first and a second face, wherein at least the first face is substantially flat, said screen having a plurality of openings passing therethrough and connecting the first and the second faces of the screen, said openings occupying up to about 75 % of the surface area of each face of the electrically conductive screen; (b) an ion exchange membrane film having a first and a second face, wherein the first face of the membrane film is attached to the first face of the electrically conductive screen, thereby leaving portions of the first face of the membrane film exposed through the openings in the electrically conductive screen; (c) a plurality of catalytically active particles disposed only on the exposed portions of the first face of the membrane film and in electrical and physcial contact with the membrane and with the electrically conductive screen.
Claim 2
Dependent Claim
153 words
A membrane/electrode combination comprising: (a) an electrically conductive screen having a first and a second face, wherein at least the first face is substantially flat, said screen having a plurality of openings passing therethrough and connecting the first and the second faces of the screen, said openings occupying up to about 75 % of the surface area of each face of the electrically conductive screen; (b) an ion exchange membrane film having a first and a second face, wherein the first face of the membrane film is attached to the first face of the electrically conductive screen, thereby leaving portions of the first face of the membrane film exposed through the openings in the electrically conductive screen; (c) a plurality of catalytically active particles disposed only on the exposed portions of the first face of the membrane film and in electrical and physcial contact with the membrane and with the electrically conductive screen.
Claim 3
Dependent Claim
13 words
The membrane/electrode combination of claim 1 wherein the electrically conductive screen is metallic.
Claim 4
Dependent Claim
16 words
The membrane/electrode combination of claim 1 wherein the electrically conductive screen is an electroformed metallic screen.
Claim 5
Dependent Claim
20 words
The membrane/electrode combination of claim 1 wherein the electrically conductive screen has from about 40 to about 60% open area.
Claim 6
Dependent Claim
20 words
The membrane/electrode combination of claim 1 wherein the electrically conductive screen has from about 45 to about 55% open area.
Claim 7
Dependent Claim
15 words
The membrane/electrode combination of claim 1 wherein the screen is nonporous around its peripheral edges.
Claim 8
Dependent Claim
34 words
The membrane/electrode combination of claim 1 wherein the thickness of the screen does not exceed the thickness of a layer of the membrane to which the screen is attached by more than about 25%.
Claim 9
Dependent Claim
29 words
The membrane/electrode combination of claim 1 wherein the thickness of the screen does not exceed the thickness of a layer of the membrane to which the screen is attached.
Claim 10
Dependent Claim
35 words
The membrane/electrode combination of claim 1 wherein the width of the plurality of catalytically active particles disposed on the exposed portions of the first face of the membrane film does not exceed about one centimeter.
Claim 11
Dependent Claim
37 words
The membrane/electrode combination of claim 1 wherein the pattern of the catalytically active particles disposed on the exposed portions of the first face of the membrane film has a width that does not exceed about one-half centimeter.
Claim 12
Dependent Claim
39 words
The membrane/electrode combination of combinaiton of claim 1 wherein the pattern of the catalytically active particles disposed on the exposed portions of the first face of the membrane film has a width that does not exceed about 0.2 centimeter.
Claim 13
Dependent Claim
29 words
The membrane/electrode combination of claim 1 wherein the openings in the screen are one or more shapes selected from the group consisting of circles, oblongs, squares, triangles, and rectangles.
Claim 14
Dependent Claim
14 words
The membrane/electrode combination of claim 1 wherein the openings in the screen are circles.
Claim 15
Dependent Claim
50 words
The membrane/electrode combination of claim 1 wherein the plurality of catalytically active particles are selected from the group consisting of oxides ruthenium, iridium, rhodium, platinum, palladium, either alone or in combination with an oxide of a film-forming metal and cobalt oxide either alone or in combination with other metal oxides.
Claim 16
Dependent Claim
13 words
The membrane/electrode combination of claim 1 wherein the membrane is a fluorocarbon-type material.
Claim 17
Dependent Claim
13 words
The membrane/electrode combination of claim 1 wherein the membrane is a hydrocarbon-type material.
Claim 18
Dependent Claim
14 words
The membrane/electrode combination of claim 15 wherein the membrane is in its thermoplastic state.
Claim 19
Dependent Claim
262 words
The membrane/electrode combination of claim 15 wherein the membrane is a copolymer of a first type monomer and a second type monomer, wherein first type of monomer is represented by the general formula: CF.sub.2 ═CZZ' (I) where: Z and Z' are independently selected from the group consisting of --H, --Cl, --F, or --CF 3 ; and the second type of monomer consists of one or more monomers selected from compounds represented by the general formula: Y--(CF.sub.2).sub.a -(CFR.sub.f).sub.b --CF.sub.f').sub.c --O--[CF(CF.sub.2 X)--CF.sub.2 --O].sub.n --CF═CF.sub.2 (II) where: Y is selected from the group consisting of --SO 2 Z, --CN, --COZ, and C(R 3 f)(R 4 f)OH; Z is --I, --Br, --Cl, --F, --OR, or --NR 1 R 2 ; R is a branched or linear alkyl radical having from 1 to about 10 carbon atoms or an aryl radical; R 3 f and R 4 f are independently selected from the group consisting of perfluoroalkyl radicals having from 1 to about 10 carbon atoms; R 1 and R 2 are independently selected from the group consisting of --H, a branched or linear alkyl radical having from 1 to about 10 carbon atoms or an aryl radical; a is 0-6; b is 0-6; c is 0 or 1; provided a+b+c is not equal to 0; X is --Cl, --Br, --F, or mixtures thereof when n is 0 to 6; and R f and R f' are independently selected from the group consisting of --F, --Cl, perfluoroalkyl radicals having from 1 to about 10 carbon atoms and fluorochloroalkyl radicals having from 1 to about 10 carbon atoms.
Claim 20
Dependent Claim
39 words
The membrane/electrode combination of claim 18 wherein Y is --SO 2 F or --COOCH 3 ; n is 0 or 1; R f and R f' are --F; X is --Cl or --F; and a+b+c is 2 or 3.
Claim 21
Dependent Claim
110 words
The membrane/electrode combination of claim 18 wherein the copolymer also includes a third type of monomer selected from the compounds represented by the general formula: Y'--(CFR.sub.2).sub.a '--CFR.sub.f).sub.b '--CFR.sub.f').sub.c' --O--[CF(CF(CF.sub.2 X')--CF.sub.2 --O].sub.n' --CF═CF.sub.2 (III) where: Y' is --F, --Cl or Br; a' and b' are independently 0-3; c is 0 or 1; provided a'+b'+c' is not equal to 0; n' is 0-6; R f and R f' are independently selected from the group consisting of --Br, --Cl, --F, perfluoroalkyl radicals having from about 1 to about 10 carbon atoms, and chloroperfluoroalkyl radicals having from 1 to about 10 carbon atoms; and X' is --F, --Cl, --Br, or mixtures thereof when n'>1.
Claim 22
Dependent Claim
20 words
The membrane/electrode combination of claim 1 wherein an ionomer is distributed among the catalytically active particles to bond them together.
Claim 23
Dependent Claim
18 words
The membrane/electrode combination of claim 1 wherein an electrically conductive metal is distributed among the catalytically active particles.
Claim 24
Dependent Claim
24 words
The membrane/electrode combination of claim 22 wherein the electrically conductive particles are selected from the group consisting of silver, nickel, tantalum, platinum, and gold.
Claim 25
Dependent Claim
24 words
The membrane/electrode combination of claim 1 wherein the catalytically active particles are in a layer having a thickness as low as about 20 microns.
Claim 26
Dependent Claim
24 words
The membrane/electrode combination of claim 1 wherein the catalytically active particles are in a layer having a thickness as low as about 5 microns.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1991-06-21 | 1991-12-21 | 1992-06-21 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1995-06-21 | 1995-12-21 | 1996-06-21 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1999-06-21 | 1999-12-21 | 2000-06-21 | $7700.00 | Window Closed / Lapsed |