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US4337211A Expired / Lapsed US ⏱️ 0.0 years remaining

Fluorocarbon ethers having substituted halogen site(s) and process to prepare

Assignee: Dow Chemical Co
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Filing: 1980-06-11
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Granted: 1982-06-29
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Expires: 2000-06-11
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Abstract

Abstract Novel perhalofluoro ethers and methods for preparing the same having generic formula, ##STR1## wherein a=0 or an integer greater than O; b=0 or an integer greater than O; n=zero or an integer greater than zero; R f and R' f are each independently selected from the group consisting of F, perfluoroalkyl and fluorochloroalkyl; X=F, Cl or Br; X'=Cl or Br; Y is an acid group or a group easily convertible to an acid group; Z=F, Cl, Br, OH, NRR' or OA; R and R' are independently selected from the group consisting of hydrogen, an alkyl having one or more than one carbon atom and aryl; A=alkali metal, quaternary nitrogen, or R.

Inventors

  • 👤 Bobby R. Ezzell
  • 👤 William P. Carl
  • 👤 William A. Mod

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-26 00:05
CPC Classifications
C; C07; C07C; C07C41/00; C07F; C07F9/00; C07F9/02; C07F9/28; C07F9/38; C07F9/40; C07F9/4003; C07F9/4006; C07C309/00; C07C51/00; C07C51/58; C07C69/00; C07C69/66; C07C69/67

Claims Analysis

Total Claims: 18
Claim 1
Independent Claim 157 words
As a composition of matter the compounds represented by the general formula: ##STR43## where a=an integer from, and including, 0 to 3; b=an integer from, and including, 0 to 3; m=an integer from, and including 0 to 6; n=an integer from and including 0 to 6; R f and R f ' are each independently selected from the group consisting of F, Cl, perfluoroalkyl and fluorochloroalkyl; X=F, Cl, Br, or mixtures thereof when n>1; X'=Cl, Br, or mixtures thereof; Y is selected from the group consisting of ##STR44## Z' is F, Cl, Br, OH, NRR' or OA R and R' are independently selected from the group consisting of hydrogen, an alkyl having one or more than one carbon atom and an aryl; Z=F, Cl, Br, OH, NRR' or OA; R and R' are independently selected from the group consisting of hydrogen, an alkyl having one or more carbon atom and aryl; A=alkali metal, quaterary ammonium or R.
Claim 2
Dependent Claim 157 words
As a composition of matter the compounds represented by the general formula: ##STR43## where a=an integer from, and including, 0 to 3; b=an integer from, and including, 0 to 3; m=an integer from, and including 0 to 6; n=an integer from and including 0 to 6; R f and R f ' are each independently selected from the group consisting of F, Cl, perfluoroalkyl and fluorochloroalkyl; X=F, Cl, Br, or mixtures thereof when n>1; X'=Cl, Br, or mixtures thereof; Y is selected from the group consisting of ##STR44## Z' is F, Cl, Br, OH, NRR' or OA R and R' are independently selected from the group consisting of hydrogen, an alkyl having one or more than one carbon atom and an aryl; Z=F, Cl, Br, OH, NRR' or OA; R and R' are independently selected from the group consisting of hydrogen, an alkyl having one or more carbon atom and aryl; A=alkali metal, quaterary ammonium or R.
Claim 3
Dependent Claim 7 words
The compounds of claim 1 where X=Cl.
Claim 4
Dependent Claim 7 words
The compounds of claim 1 where X'=Cl.
Claim 5
Dependent Claim 11 words
The compounds of claim 1 where X=F and n is 1-6.
Claim 6
Dependent Claim 9 words
The compounds of claim 1 where X=F and X'=Cl.
Claim 7
Dependent Claim 9 words
The compounds of claim 1 where Y=Z'SO 2 .
Claim 8
Dependent Claim 7 words
The compounds of claim 1 where Y=COZ'.
Claim 9
Dependent Claim 9 words
The compounds of claims 6 or 7 where X=Cl.
Claim 10
Dependent Claim 9 words
The compounds of claims 6 or 7 where X'=Cl.
Claim 11
Dependent Claim 11 words
The compounds of claims 6 or 7 where X=Cl and X'=Cl.
Claim 12
Dependent Claim 11 words
The compounds of claims 1, 3, 6 and 7 where n=0.
Claim 13
Dependent Claim 14 words
The compounds of claims 1, 2, 3, 4, 5, 6 and 7 where m=0.
Claim 14
Dependent Claim 9 words
The compounds of claim 1 where n=0 and m=0.
Claim 15
Dependent Claim 7 words
The compounds of claim 13 where X'=Cl.
Claim 16
Dependent Claim 9 words
The compounds of claim 1 where n=1 and m=0.
Claim 17
Dependent Claim 7 words
The compounds of claim 15 where X=Cl.
Claim 18
Dependent Claim 7 words
The compounds of claim 16 where X'=Cl.

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1985-06-28 1985-12-28 1986-06-29 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1989-06-28 1989-12-28 1990-06-29 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1993-06-28 1993-12-28 1994-06-29 $7700.00 Window Closed / Lapsed

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