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Reaction sintered cermet

Assignee: Corning Inc
•
Filing: 1987-06-19
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Granted: 1988-05-24
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Expires: 2007-06-19
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Abstract

Abstract Cermet body formed by reaction sintering at pressures ranging from subatmospheric to superatmospheric of admixed and shaped particulate exothermic reactants, which have maximum particle size substantially not greater than 150 mu m and can be elements, compounds, intermetallic compounds and/or alloys, in stoichiometric proportions to substantially form 40-95 mole percent of first phase or phases being boride, nitride, silicide, sulfide or combination thereof of one or more of the elements of Groups 2a, 3a exclusive of B, 4a, 2b, 3b including lanthanide and actinide series elements, 4b, 5b, 6b, 7b and 8, and 5-60 mole percent of second phase or phases being metal, alloy, intermetallic compound or combination thereof of one or more of the elements of Groups 3a exclusive of B, 4a, 2b, 4b, 5b, 6b, 7b, iron, cobalt and nickel, wherein the maximum grain size of the first phase or phases is substantially not greater than 10 mu m and which body contains 0 to 4 weight percent oxygen.

Inventors

  • 👤 Thomas P. DeAngelis

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-03 04:50
CPC Classifications
C; C04; C04B; C04B35/00; C04B35/515; C04B35/58; C04B35/5805; C04B35/58064; C04B35/58071; B; B22; B22F; B22F3/00; B22F3/23; C04B35/5158; C04B35/58085; C04B35/58092; C04B35/581; C04B35/622; C04B35/626; C04B35/63; C04B35/632; C04B35/64; C04B35/645; C04B35/65; C22; C22C; C22C1/00; C22C1/04; C22C1/05; C22C1/051; C22C1/053; C25; C25C; C25C3/00; C25C3/06; C25C3/08

Claims Analysis

Total Claims: 20
Claim 1
Independent Claim 233 words
A reaction sintered cermet body consisting of a fine-grained, homogeneous, intimate interdispersion of: (a) 40-95 mole percent of first phase or phases having a maximum grain size substantially not greater than 10 μm and being boride, nitride, silicide, sulfide or combination thereof of one or more of the elements of Groups 2a, 3a exclusive of B, 4a, 2b, 3b including lanthanide and actinide series elements, 4b, 5b, 6b, 7b and 8; (b) 5-60 mole percent of second phase or phases being metal, alloy, intermetallic compound or combination thereof of one or more of the elements of Groups 3a exclusive of B, 4a, 2b, 4b, 5b, 6b, 7b, iron, cobalt and nickel; and (c) optionally diluent selected from nonreacted portion of reactants forming the first and second phases and preformed material that is the same as the first and/or second phases; which body contains 0 to 4 weight percent oxygen and is prepared by the process comprising: (d) admixing particulate exothermic reactants of maximum particle size substantially not greater than 150 μm and being elements, compounds, intermetallic compounds, alloys or combination thereof in stoichiometric proportions to substantially form the first and second phases, and (e) shaping and heating the admixture to form the reaction sintered body, and heating being done in nonreactive atmosphere and at temperature at which the reaction and sintering occurs between the reactants to substantially form the first and second phases.
Claim 2
Dependent Claim 233 words
A reaction sintered cermet body consisting of a fine-grained, homogeneous, intimate interdispersion of: (a) 40-95 mole percent of first phase or phases having a maximum grain size substantially not greater than 10 μm and being boride, nitride, silicide, sulfide or combination thereof of one or more of the elements of Groups 2a, 3a exclusive of B, 4a, 2b, 3b including lanthanide and actinide series elements, 4b, 5b, 6b, 7b and 8; (b) 5-60 mole percent of second phase or phases being metal, alloy, intermetallic compound or combination thereof of one or more of the elements of Groups 3a exclusive of B, 4a, 2b, 4b, 5b, 6b, 7b, iron, cobalt and nickel; and (c) optionally diluent selected from nonreacted portion of reactants forming the first and second phases and preformed material that is the same as the first and/or second phases; which body contains 0 to 4 weight percent oxygen and is prepared by the process comprising: (d) admixing particulate exothermic reactants of maximum particle size substantially not greater than 150 μm and being elements, compounds, intermetallic compounds, alloys or combination thereof in stoichiometric proportions to substantially form the first and second phases, and (e) shaping and heating the admixture to form the reaction sintered body, and heating being done in nonreactive atmosphere and at temperature at which the reaction and sintering occurs between the reactants to substantially form the first and second phases.
Claim 3
Dependent Claim 17 words
The body of claim 1 which is prepared by the shaping and heating being separate sequential steps.
Claim 4
Dependent Claim 20 words
The body of claim 1 which is prepared by the shaping and heating being substantially simultaneous steps of hot pressing.
Claim 5
Dependent Claim 35 words
The body of claim 1 wherein the mean grain size of the first phase or phases is not greater than 6 μm and the mean particle size of the reactants is less than 100 μm.
Claim 6
Dependent Claim 38 words
The body of claim 4 wherein the maximum grain size of the first phase or phases is substantially not greater than 5 μm and the maximum particle size of the reactants is substantially not greater than 44 μm.
Claim 7
Dependent Claim 23 words
The body of claim 5 wherein the maximum grain size of the first phase or phases is substantially not greater than 2 μm.
Claim 8
Dependent Claim 21 words
The body of claim 6 wherein the mean grain size of the first phase or phases is less than 1 μm.
Claim 9
Dependent Claim 38 words
The body of claim 1 having the first phase or phases being boride, nitride, silicide, sulfide or combination thereof of one or more of the elements of Groups 4b, 5b and 6b, having the second phase being Al.
Claim 10
Dependent Claim 23 words
The body of claim 8 having the first phase or phases being diboride of one or more of the elements of Group 4b.
Claim 11
Dependent Claim 25 words
The body of claim 1 having 45-95 mole percent of the first phase or phases and 5-55 mole percent of the second phase or phases.
Claim 12
Dependent Claim 20 words
The body of claim 10 which is prepared by the shaping and heating being substantially simultaneous steps of hot pressing.
Claim 13
Dependent Claim 35 words
The body of claim 11 wherein the mean grain size of the first phase or phases is not greater than 6 μm and the mean particle size of the reactants is less than 100 μm.
Claim 14
Dependent Claim 39 words
The body of claim 12 having the first phase or phases being boride, nitride, silicide, sulfide or combination thereof of one or more of the elements of Groups 4b, 5b and 6b, and having the second phase being Al.
Claim 15
Dependent Claim 23 words
The body of claim 13 wherein the maximum grain size of the first phase or phases is substantially not greater than 2 μm.
Claim 16
Dependent Claim 21 words
The body of claim 14 wherein the mean grain size of the first phase or phases is less than 1 μm.
Claim 17
Dependent Claim 23 words
The body of claim 15 having the first phase or phases being diboride of one or more of the elements of Group 4b.
Claim 18
Dependent Claim 24 words
The body of claim 16 wherein the Al at least partially separating the grains of diboride is in thin layers less than about 1000Å.
Claim 19
Dependent Claim 12 words
The body claim 17 having a first phase of TiB 2 .
Claim 20
Dependent Claim 28 words
The method of forming the body of claim 1 comprising: (a) admixing the particulate reactants, and (b) shaping and heating the admixture to form the reaction sintered body.

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1991-05-24 1991-11-23 1992-05-24 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1995-05-24 1995-11-23 1996-05-24 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1999-05-24 1999-11-23 2000-05-24 $7700.00 Window Closed / Lapsed

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