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Process for recovery of silver from spent, waste, acidic processing fluids

Assignee: EIDP Inc
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Filing: 1986-10-31
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Granted: 1988-04-26
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Expires: 2006-10-31
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Abstract

Abstract Process for recovery of silver from spent, waste acidic silver halide photographic processing fluid, e.g., fixer solution, comprising passing the fluid through finely divided iron, e.g., steel wool, contained in a vessel in the presence of a metal salt of copper or cadmium, e.g., copper(II)sulfate, copper chloride dihydrate, cadmium sulfate, etc. The ratio of iron to metal salt is 25 to 1 to 4 to 1. An apparatus for recovery of silver is also described.

Inventors

  • 👤 James E. Williams

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-07 17:40
CPC Classifications
C; C22; C22B; C22B11/00; C22B11/04; C22B11/042; C22B11/046; Y; Y02; Y02P; Y02P10/00; Y02P10/20

Claims Analysis

Total Claims: 8
Claim 1
Independent Claim 92 words
A process for the recovery of silver from spent, waste acidic silver halide photographic processing fluid which comprises passing the waste processing fluid through finely divided iron contained in a vessel and recovering the fluid containing substantially no dissolved silver, the improvement wherein the vessel contains a minor amount with respect to the amount of finely divided iron of a metal salt wherein the metal is taken from the group consisting of copper and cadmium, the ratio of finely divided iron to metal salt being 25 to 1 to 4 to 1.
Claim 2
Dependent Claim 92 words
A process for the recovery of silver from spent, waste acidic silver halide photographic processing fluid which comprises passing the waste processing fluid through finely divided iron contained in a vessel and recovering the fluid containing substantially no dissolved silver, the improvement wherein the vessel contains a minor amount with respect to the amount of finely divided iron of a metal salt wherein the metal is taken from the group consisting of copper and cadmium, the ratio of finely divided iron to metal salt being 25 to 1 to 4 to 1.
Claim 3
Dependent Claim 14 words
A process according to claim 1 wherein the metal of the salt is copper.
Claim 4
Dependent Claim 14 words
A process according to claim 1 wherein the metal of the salt is cadmium.
Claim 5
Dependent Claim 12 words
A process according to claim 2 wherein the metal salt is copper(II)sulfate.
Claim 6
Dependent Claim 13 words
A process according to claim 3 wherein the metal salt is cadmium sulfate.
Claim 7
Dependent Claim 13 words
A process according to claim 2 wherein the metal salt is copper(II)chloride dihydrate.
Claim 8
Dependent Claim 16 words
A process according to claim 1 wherein the iron is in the form of steel wool.

References Cited (Backward Citations)

US2216765A Cited
US3369801A Cited
FR2106962A5 Cited
US3705716A Cited
GB1353805A Cited
US3792845A Cited
US4213600A Cited
US4303441A Cited
US4441697A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1991-04-26 1991-10-26 1992-04-26 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1995-04-26 1995-10-26 1996-04-26 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1999-04-26 1999-10-26 2000-04-26 $7700.00 Window Closed / Lapsed

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