US4734141A
Expired / Lapsed
US
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Crash bag propellant compositions for generating high quality nitrogen gas
Assignee: Hercules LLC
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Filing: 1987-03-27
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Granted: 1988-03-29
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Expires: 2007-03-27
Abstract
Abstract A crash bag propellant composition and method for generating non-toxic nitrogen gas comprising an azide salt and an oxidant component in which metal oxides are substantially replaced with one or more bi-metallic complexes containing copper or iron in combination with chromium, molybdenum or tungsten.
Inventors
- 👤 Richard V. Cartwright
- 👤 Steven J. Hardwick
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-25 11:00
CPC Classifications
C; C06; C06B; C06B35/00; C06D; C06D5/00; C06D5/06
Claims Analysis
Total Claims: 34
Claim 1
Independent Claim
100 words
A method for improving the stability and speed of azide/oxidizer containing propellant compositions comprising replacing metal oxides within the oxidizer component with an active amount of a metal complex represented by the formula M.sub.(a) M.sub.(b).sup.l X.sub.(c) wherein M is defined as copper or iron; M l is defined as chromium, molybdenum or tungsten; X is defined as an electronegative element selected from the group consisting of oxygen, sulfur, and chlorine; (a) has a value within the range of about 1-5; (b) has a value within the range of about 0.7-3.0; and (c) has a value within the range of 4-12.
Claim 2
Independent Claim
100 words
A method for improving the stability and speed of azide/oxidizer containing propellant compositions comprising replacing metal oxides within the oxidizer component with an active amount of a metal complex represented by the formula M.sub.(a) M.sub.(b).sup.l X.sub.(c) wherein M is defined as copper or iron; M l is defined as chromium, molybdenum or tungsten; X is defined as an electronegative element selected from the group consisting of oxygen, sulfur, and chlorine; (a) has a value within the range of about 1-5; (b) has a value within the range of about 0.7-3.0; and (c) has a value within the range of 4-12.
Claim 3
Dependent Claim
54 words
The method of claim 1, wherein the metal complex is represented by the formula M.sub.(a).sup.ll M.sub.(b).sup.lll O.sub.(c) in which M ll is defined as copper or iron; M lll is defined as chromium or molybdenum; (c) has a value within the range of about 4-12; and the ratio of (b)/(a) does not exceed 2.
Claim 4
Dependent Claim
31 words
The method of claim 2, wherein the azide component of the propellant composition is sodium azide or potassium azide and the metal complex is represented by the formula. Cu.sub.4.41 Cr.sub.0.77 O.sub.5.00.
Claim 5
Dependent Claim
31 words
The method of claim 2, wherein the azide component of the propellant composition is sodium azide or potassium azide and the metal complex is represented by the formula Cu.sub.2.20 Cr.sub.2.85 O.sub.7.00.
Claim 6
Dependent Claim
27 words
The method of claim 2, wherein the azide component is sodium azide or potassium azide and the metal complex is represented by the formula Cu.sub.2.93 Cr.sub.2.85 O.sub.7.00.
Claim 7
Dependent Claim
31 words
The method of claim 2, wherein the azide component of the propellant composition is sodium azide or potassium azide and the metal complex is represented by the formula Cu Mo O.sub.4.00.
Claim 8
Dependent Claim
30 words
The method of claim 1, wherein the azide component of the propellant composition is sodium azide or potassium azide and the metal complex is represented by the formula Fe WO.sub.4.00.
Claim 9
Dependent Claim
31 words
The method of claim 2, wherein the azide component of the propellant composition is sodium azide or potassium azide; and the metal complex is represented by the formula Fe.sub.2 Mo.sub.3 O.sub.12.00.
Claim 10
Dependent Claim
96 words
A gas-generating propellant composition comprising, in combination, (a) an alkali or alkaline earth metal azide component, and (b) an active amount of an oxidizer complex of the formula M.sub.(a) M.sub.(b).sup.l X.sub.(c) wherein M is defined as copper or iron; M l is defined as chromium, molybdenum or tungsten; X is defined as an electronegative element selected from the group consisting of oxygen, sulfur, and chlorine; (a) has a value within the range of about 1-5; (b) has a value within the range of about 0.7-3.0; and (c) has a value within the range of about 4-12.
Claim 11
Dependent Claim
96 words
A gas-generating propellant composition comprising, in combination, (a) an alkali or alkaline earth metal azide component, and (b) an active amount of an oxidizer complex of the formula M.sub.(a) M.sub.(b).sup.l X.sub.(c) wherein M is defined as copper or iron; M l is defined as chromium, molybdenum or tungsten; X is defined as an electronegative element selected from the group consisting of oxygen, sulfur, and chlorine; (a) has a value within the range of about 1-5; (b) has a value within the range of about 0.7-3.0; and (c) has a value within the range of about 4-12.
Claim 12
Dependent Claim
68 words
A nitrogen gas-generating propellant composition of claim 9, wherein the azide component is an alkali or alkaline earth metal azide component; and the oxidizer complex has the formula: M.sub.(a).sup.ll M.sub.(b).sup.lll O.sub.(c) in which M ll is defined as copper or iron; M lll is defined as chromium or molybdenum; (c) has a value within the range of about 4-12; and the ratio of (b)/(a) does not exceed 2.
Claim 13
Dependent Claim
27 words
The nitrogen gas-generating propellant of claim 11, wherein the azide component is sodium azide or potassium azide; and the oxidizer complex has the formula Cu.sub.4.41 Cr.sub.0.77 O.sub.5.00.
Claim 14
Dependent Claim
28 words
The nitrogen gas-generating propellant composition of claim 10, wherein the azide component is sodium azide or potassium azide and the oxidizer complex has the formula Cu.sub.2.20 Cr.sub.2.85 O.sub.7.00.
Claim 15
Dependent Claim
27 words
The nitrogen gas-generating propellant composition of claim 10, wherein the azide component is sodium or potassium azide, and the oxidizer complex has the formula Cu.sub.2.93 Cr.sub.2.85 O.sub.7.00.
Claim 16
Dependent Claim
27 words
The nitrogen gas-generating propellant composition of claim 10, wherein the azide component is sodium or potassium azide, and the oxidizer complex has the formula Cu Mo O.sub.4.00.
Claim 17
Dependent Claim
26 words
The nitrogen gas-generating propellant composition of claim 9, wherein the azide component is sodium or potassium azide, and the oxidizer complex has the formula Fe WO.sub.4.00.
Claim 18
Dependent Claim
27 words
The nitrogen gas-generating propellant composition of claim 10, wherein the azide component is sodium or potassium azide, and the oxidizer complex has the formula Fe.sub.2 Mo.sub.3 O.sub.12.00.
Claim 19
Dependent Claim
16 words
The propellant composition of claim 9 containing at least one of a binder and a lubricant.
Claim 20
Dependent Claim
16 words
The propellant composition of claim 10 containing at least one of a binder and a lubricant.
Claim 21
Dependent Claim
16 words
The propellant composition of claim 11 containing at least one of a binder and a lubricant.
Claim 22
Dependent Claim
16 words
The propellant composition of claim 12 containing at least one of a binder and a lubricant.
Claim 23
Dependent Claim
16 words
The propellant composition of claim 13 containing at least one of a binder and a lubricant.
Claim 24
Dependent Claim
16 words
The propellant composition of claim 14 containing at least one of a binder and a lubricant.
Claim 25
Dependent Claim
16 words
The propellant composition of claim 15 containing at least one of a binder and a lubricant.
Claim 26
Dependent Claim
16 words
The propellant composition of claim 16 containing at least one of a binder and a lubricant.
Claim 27
Dependent Claim
120 words
A safety crash bag device comprising, in combination, an inflatable bag of desired shape receivably connected to a gas-generating means charged with an active amount of gas-generating propellant composition as defined in claim 9, and in proximity to means for ignition arranged in potential firing attitude with respect to said gas-generating propellant; and impact detecting means functionally connected to said detonating means for firing of said detonating means upon exposure to an impact of predetermined severity; wherein an impacting force on said impact detecting means effects a firing sequence through said means for ignition of said gas-generating propellant, essentially producing inert nitrogen gas in said gas-generating means, and passing said gas to said inflatable bag to create a shock-absorbing barrier.
Claim 28
Dependent Claim
118 words
A safety crash bag device comprising, in combination, an inflatable bag of desired shape receivably connected to a gas-generating means charged with an active amount of gas-generating propellant composition as defined in claim 10, and in proximity to means for ignition arranged in potential firing attitude with respect to said gas-generating propellant; and impact-detecting means functionally connected to said detonating means for firing of said detonating means upon exposure to an impact of predetermined severity; wherein an impacting force on said impact-detecting means effects a firing sequence through said means for ignition of said gas-generating propellant, essentially producing inert nitrogen gas in said gas-generating means, and passing said gas to said inflatable bag to create a shock-absorbing barrier.
Claim 29
Dependent Claim
118 words
A safety crash bag device comprising, in combination, an inflatable bag of desired shape receivably connected to a gas-generating means charged with an active amount of gas-generating propellant composition as defined in claim 11, and in proximity to means for ignition arranged in potential firing attitude with respect to said gas-generating propellant; and impact-detecting means functionally connected to said detonating means for firing of said detonating means upon exposure to an impact of predetermined severity; wherein an impacting force on said impact-detecting means effects a firing sequence through said means for ignition of said gas-generating propellant, essentially producing inert nitrogen gas in said gas-generating means, and passing said gas to said inflatable bag to create a shock-absorbing barrier.
Claim 30
Dependent Claim
118 words
A safety crash bag device comprising, in combination, an inflatable bag of desired shape receivably connected to a gas-generating means charged with an active amount of gas-generating propellant composition as defined in claim 12, and in proximity to means for ignition arranged in potential firing attitude with respect to said gas-generating propellant; and impact-detecting means functionally connected to said detonating means for firing of said detonating means upon exposure to an impact of predetermined severity; wherein an impacting force on said impact-detecting means effects a firing sequence through said means for ignition of said gas-generating propellant, essentially producing inert nitrogen gas in said gas-generating means, and passing said gas to said inflatable bag to create a shock-absorbing barrier.
Claim 31
Dependent Claim
119 words
A safety crash bag device comprising, in combination, an inflatable bag of desired shape receivably connected to a gas-generating means charged with an active amount of gas-generating propellant composition as defined in claim 13, and in proximity to means for ignition arranged in potential firing attitude with respect to said gas-generating propellant; and impact-detecting means functionally connected to said detonating means for firing of said detonating means upon exposure to an impact of predetermined severity; wherein an impacting force on said impact-detecting means effects a firing sequence through said means for ignition of said gas-generating propellant, essentially producing inert nitrogen gas in said gas generating means, and passing said gas to said inflatable bag to create a shock-absorbing barrier.
Claim 32
Dependent Claim
119 words
A safety crash bag device comprising, in combination, an inflatable bag of desired shape receivably connected to a gas-generating means charged with an active amount of gas-generating propellant composition as defined in claim 14, and in proximity to means for ignition arranged in potential firing attitude with respect to said gas-generating propellant; and impact-detecting means functionally connected to said detonating means for firing of said detonating means upon exposure to an impact of predetermined severity; wherein an impacting force on said impact-detecting means effects a firing sequence through said means for ignition of said gas-generating propellant, essentially producing inert nitrogen gas in said gas generating means, and passing said gas to said inflatable bag to create a shock-absorbing barrier.
Claim 33
Dependent Claim
119 words
A safety crash bag device comprising, in combination, an inflatable bag of desired shape receivably connected to a gas-generating means charged with an active amount of gas-generating propellant composition as defined in claim 15, and in proximity to means for ignition arranged in potential firing attitude with respect to said gas-generating propellant; and impact-detecting means functionally connected to said detonating means for firing of said detonating means upon exposure to an impact of predetermined severity; wherein an impacting force on said impact-detecting means effects a firing sequence through said means for ignition of said gas-generating propellant, essentially producing inert nitrogen gas in said gas generating means, and passing said gas to said inflatable bag to create a shock-absorbing barrier.
Claim 34
Dependent Claim
119 words
A safety crash bag device comprising, in combination, an inflatable bag of desired shape receivably connected to a gas-generating means charged with an active amount of gas-generating propellant composition as defined in claim 16, and in proximity to means for ignition arranged in potential firing attitude with respect to said gas-generating propellant; and impact-detecting means functionally connected to said detonating means for firing of said detonating means upon exposure to an impact of predetermined severity; wherein an impacting force on said impact-detecting means effects a firing sequence through said means for ignition of said gas-generating propellant, essentially producing inert nitrogen gas in said gas generating means, and passing said gas to said inflatable bag to create a shock-absorbing barrier.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1991-03-29 | 1991-09-28 | 1992-03-29 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1995-03-29 | 1995-09-28 | 1996-03-29 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1999-03-29 | 1999-09-28 | 2000-03-29 | $7700.00 | Window Closed / Lapsed |