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US3931040A Expired / Lapsed US ⏱️ 0.0 years remaining

Gas generating composition

Assignee: RTX Corp
•
Filing: 1973-08-09
•
Granted: 1976-01-06
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Expires: 1993-08-09
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Abstract

Abstract A solid composition capable of self-sustained combustion to produce gaseous nitrogen and nonvolatile solids as its combustion products comprises a mixture of a first metal azide and the oxide or salt of a second metal which second metal is below the first metal in the electrochemical series and which is capable of being substituted by the first metal in the oxide or salt. Many combinations of various components may be used, but some care is required to select only those combinations in which the solid products are nonvolatile at the temperatures encountered during the combustion. A representative system employes iron oxide and sodium azide according to the following reactions: Fe.sub.2 O.sub.3 +6NaN.sub.3 →2Fe+3Na.sub.2 O+9N.sub.2 ↑ Another embodiment of the invention generates mixtures of nitrogen and other gases such as carbon dioxide, carbon monoxide and/or water particularly suitable for use in lasers. This is accomplished by adding to the mixture materials which react or decompose into the desired gases. If carbon monoxide or carbon dioxide is the desired additional gas, a metal carbonate may be used as the salt in the above reaction.

Inventors

  • 👤 Jack D. Breazeale

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-02 11:43
CPC Classifications
C; C06; C06D; C06D5/00; C06B; C06B35/00; H; H01; H01S; H01S3/00; H01S3/09; H01S3/095

Claims Analysis

Total Claims: 16
Claim 1
Independent Claim 102 words
A gaseous nitrogen generating composition comprising a mixture of a metal azide and a material selected from the group consisting of: Fe 2 O 3 , AlF 3 , Al 2 O 3 +Fe 2 O 3 , B 2 O 3 , CuCl, CuO, Fe 3 O 4 , MnO 2 , SiO 2 , TiO 2 and mixtures thereof, said materials being oxides and salt of elements lower in the electrochemical series of the elements than the metal component of the azide and being capable of liberating sufficient heat upon exothermic reaction with said azide to maintain a self-sustained combustion.
Claim 2
Dependent Claim 102 words
A gaseous nitrogen generating composition comprising a mixture of a metal azide and a material selected from the group consisting of: Fe 2 O 3 , AlF 3 , Al 2 O 3 +Fe 2 O 3 , B 2 O 3 , CuCl, CuO, Fe 3 O 4 , MnO 2 , SiO 2 , TiO 2 and mixtures thereof, said materials being oxides and salt of elements lower in the electrochemical series of the elements than the metal component of the azide and being capable of liberating sufficient heat upon exothermic reaction with said azide to maintain a self-sustained combustion.
Claim 3
Dependent Claim 19 words
The composition of claim 1 wherein said metal azide is selected from the group consisting of alkali metal azides.
Claim 4
Dependent Claim 22 words
The composition of claim 2 further comprising a material selected from the group consisting of carbon-nitrogen compounds, metal oxalates and metal carbonates.
Claim 5
Dependent Claim 57 words
The composition of claim 3 wherein said carbon-nitrogen compounds, metal oxalates and metal carbonates are selected from the group consisting of tetracyanoethylene, Li 2 C 2 O 4 , Na 2 C 2 O 4 , MgC 2 O 4 , CaCO 3 , FeCO 3 , MgCO 3 , MgCa(CO 3 ) 2 and mixtures thereof.
Claim 6
Dependent Claim 36 words
The composition of claim 4 further comprising an oxidizing agent selected from the group consisting of NaNO 3 , NaClO 4 , LiNO 3 , LiClO 4 , NaClO 3 , Mg(ClO 4 ) 2 .
Claim 7
Dependent Claim 30 words
The composition of claim 4 further comprising a material selected from the group consisting of FeO(OH), Mg(ClO 4 ) 2 .6H 2 O, (COOH) 2 .2H 2 O and oxamide.
Claim 8
Dependent Claim 35 words
The composition of claim 6 further comprising a material selected from the group consisting of NaNO 3 , NaClO 4 , LiNO 3 , LiClO 4 , NaClO 3 and Mg(ClO 4 ) 2 .
Claim 9
Dependent Claim 20 words
The composition of claim 1 wherein said azide is sodium azide and said material is Fe 2 O 3 .
Claim 10
Dependent Claim 16 words
The composition of claim 1 wherein said azide is sodium azide and said material is CuCl.
Claim 11
Dependent Claim 24 words
The composition of claim 1 wherein said azide is sodium azide and said material is Al 2 O 3 +Fe 2 O 3 .
Claim 12
Dependent Claim 18 words
The composition of claim 1 wherein said azide is sodium azide and said material is SiO 2 .
Claim 13
Dependent Claim 16 words
The composition of claim 1 wherein said azide is sodium azide and said material is CuO.
Claim 14
Dependent Claim 20 words
The composition of claim 1 wherein said azide is sodium azide and said material is B 2 O 3 .
Claim 15
Dependent Claim 10 words
The composition of claim 1 further comprising a fiberous binder.
Claim 16
Dependent Claim 10 words
The composition of claim 7 further comprising a fiberous binder.

References Cited (Backward Citations)

US3741585A Cited
US3773351A Cited
US3814694A Cited
US3779823A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1979-01-05 1979-07-07 1980-01-06 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1983-01-05 1983-07-07 1984-01-06 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1987-01-05 1987-07-07 1988-01-06 $7700.00 Window Closed / Lapsed

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