US3936330A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Composition and method for inflation of passive restraint systems
Assignee: Dow Chemical Co
•
Filing: 1973-08-08
•
Granted: 1976-02-03
•
Expires: 1993-08-08
Abstract
Abstract Disclosed is a pyrotechnic composition and a method for the inflation of passive restraint systems, i.e., crash bags. The method utilizes gases produced by the ignition and burning of a pyrotechnic composition containing an alkali metal azide, a metal halide and an inorganic perchlorate.
Inventors
- 👤 Thomas E. Dergazarian
- 👤 George A. Lane
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-25 20:58
CPC Classifications
C; C06; C06D; C06D5/00; C06D5/06; C06B; C06B43/00
Claims Analysis
Total Claims: 21
Claim 1
Independent Claim
138 words
A composition which burns to produce gases which are rich in nitrogen and substantially free of elemental alkali metals, oxides of nitrogen and alkali metal oxides, which comprises: an intimate mixture of an alkali metal azide of the formula MN 3 , a metal halide of the formula RX n and an inorganic oxidizer corresponding to the formula A(ClO 4 ) m wherein M is an alkali metal; R is tin, zinc, cobalt, nickel, calcium or magnesium; X is chlorine, bromine or iodine, n is an integer representing the valence state of R; A is potassium, sodium, or magnesium and m is equal to the valence of A, said constituents provided in amounts so that upon burning of the composition, the combustion products are substantially free of oxides of nitrogen, elemental alkali metals, HCN and alkali metal oxides.
Claim 2
Dependent Claim
138 words
A composition which burns to produce gases which are rich in nitrogen and substantially free of elemental alkali metals, oxides of nitrogen and alkali metal oxides, which comprises: an intimate mixture of an alkali metal azide of the formula MN 3 , a metal halide of the formula RX n and an inorganic oxidizer corresponding to the formula A(ClO 4 ) m wherein M is an alkali metal; R is tin, zinc, cobalt, nickel, calcium or magnesium; X is chlorine, bromine or iodine, n is an integer representing the valence state of R; A is potassium, sodium, or magnesium and m is equal to the valence of A, said constituents provided in amounts so that upon burning of the composition, the combustion products are substantially free of oxides of nitrogen, elemental alkali metals, HCN and alkali metal oxides.
Claim 3
Dependent Claim
20 words
The composition of claim 1 including in addition up to about 5 percent by weight of a particulate metal fuel.
Claim 4
Dependent Claim
18 words
The composition of claim 1 including in addition up to about 2 percent by weight of particulate graphite.
Claim 5
Dependent Claim
48 words
The composition of claim 1 wherein said constituents are provided in the following amounts as percent by weight; MN 3 , about 48 to about 53 percent; RX n , about 32 to about 40 percent and A(ClO 4 ) m , about 10 to about 15 percent.
Claim 6
Dependent Claim
31 words
The composition of claim 4 including in addition up to about 5 percent by weight of a particulate metal selected from the group consisting of magnesium, aluminum, titanium, silicon or zinc.
Claim 7
Dependent Claim
17 words
The composition of claim 5 including in addition up to about 2 percent by weight of graphite.
Claim 8
Dependent Claim
15 words
The composition of claim 4 including up to about 2 percent by weight of graphite.
Claim 9
Dependent Claim
11 words
The composition of claim 4 wherein M is sodium or potassium.
Claim 10
Dependent Claim
59 words
The composition of claim 4 including in addition up to about 5 percent by weight of a particulate metal selected from the group consisting of magnesium, aluminum, titanium, silicon or zinc; up to about 2 percent by weight of graphite wherein all the constituents are provided in particulate form having a particle size of about 250 microns or less.
Claim 11
Dependent Claim
66 words
A pyrotechnic grain comprising: an intimate mixture of particles wherein said particles comprise, as percent by weight of the grain, sodium azide, about 50.7 percent; potassium perchlorate, about 12.2 percent; and magnesium chloride, about 37.1 percent, said grain being further characterized in that upon burning of the grain, the combustion products are substantially free of oxides of nitrogen, elemental alkali metals, HCN and alkali metal oxides.
Claim 12
Dependent Claim
66 words
A pyrotechnic grain comprising: an intimate mixture of particles wherein said particles comprise, as percent by weight of the grain, sodium azide, about 50.7 percent; potassium perchlorate, about 12.2 percent; and magnesium chloride, about 37.1 percent, said grain being further characterized in that upon burning of the grain, the combustion products are substantially free of oxides of nitrogen, elemental alkali metals, HCN and alkali metal oxides.
Claim 13
Dependent Claim
65 words
A pyrotechnic grain comprising, as percent by weight: about 49.7 percent NaN 3 , about 11.9 percent KClO 4 , about 36.4 percent MgCl 2 , about 1 percent magnesium and about 1 percent graphite, said grain being further characterized in that upon burning of the grain, the combustion products are substantially free of oxides of nitrogen, elemental alkali metals, HCN and alkali metal oxides.
Claim 14
Dependent Claim
65 words
A pyrotechnic grain comprising, as percent by weight: about 49.7 percent NaN 3 , about 11.9 percent KClO 4 , about 36.4 percent MgCl 2 , about 1 percent magnesium and about 1 percent graphite, said grain being further characterized in that upon burning of the grain, the combustion products are substantially free of oxides of nitrogen, elemental alkali metals, HCN and alkali metal oxides.
Claim 15
Dependent Claim
22 words
The composition of claim 11 wherein the individual constituents are in particulate form ranging in size from about 250 microns or less.
Claim 16
Independent Claim
138 words
A method of rapidly generating gases which are rich in nitrogen and substantially free of elemental alkali metals, alkali metal oxides and oxides of nitrogen which comprises: igniting an intimate mixture of an alkali metal azide of the formula MN 3 , a metal halide of the formula RX n and an inorganic oxidizer corresponding to the formula A(ClO 4 ) m wherein M is an alkali metal; R is tin, zinc, cobalt, nickel, calcium or magnesium; X is chlorine, bromine or iodine, n is an integer representing the valence state of R; A is potassium, sodium, or magnesium, and m is equal to the valence of A, said constituents provided in amounts so that upon burning of the composition, the combustion products are substantially free of oxides of nitrogen, elemental alkali metals, HCN and alkali metal oxides.
Claim 17
Independent Claim
138 words
A method of rapidly generating gases which are rich in nitrogen and substantially free of elemental alkali metals, alkali metal oxides and oxides of nitrogen which comprises: igniting an intimate mixture of an alkali metal azide of the formula MN 3 , a metal halide of the formula RX n and an inorganic oxidizer corresponding to the formula A(ClO 4 ) m wherein M is an alkali metal; R is tin, zinc, cobalt, nickel, calcium or magnesium; X is chlorine, bromine or iodine, n is an integer representing the valence state of R; A is potassium, sodium, or magnesium, and m is equal to the valence of A, said constituents provided in amounts so that upon burning of the composition, the combustion products are substantially free of oxides of nitrogen, elemental alkali metals, HCN and alkali metal oxides.
Claim 18
Dependent Claim
39 words
The method of claim 13 wherein the mixture of metal azide and metal halide is ignited while in fluid communication with an inflatable flexible container, thereby filling and inflating the container with combustion gases upon ignition of the mixture.
Claim 19
Dependent Claim
13 words
The method of claim 14 wherein said container is located in an automobile.
Claim 20
Dependent Claim
29 words
The method of claim 15 wherein the mixture comprises, as percent by weight, about 50.7 percent sodium azide, about 12.2 percent potassium perchlorate and about 37.1 percent magnesium chloride.
Claim 21
Dependent Claim
40 words
The method of claim 14 wherein said mixture comprises, as percent by weight, about 49.7 percent NaN 3 , about 11.9 percent KClO 4 , about 36.4 percent MgCl 2 , about 1 percent magnesium, and about 1 percent graphite.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1979-02-02 | 1979-08-04 | 1980-02-03 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1983-02-02 | 1983-08-04 | 1984-02-03 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1987-02-02 | 1987-08-04 | 1988-02-03 | $7700.00 | Window Closed / Lapsed |