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Phosphor and fluorescent lamp using the same

Assignee: Toshiba Corp
•
Filing: 1987-04-09
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Granted: 1988-03-22
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Expires: 2007-04-09
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Abstract

Abstract According to the present invention, there is provided a phosphor represented by a general formula (Ba w Ca x Mg y Eu z )O.aAl 2 O 3 . bSiO 2 where 0.1≦w≦0.5, 0.0004≦x≦0.0020, 0.1≦y≦0.8, 0.03≦z≦0.10, w+x+y+z=1, 1.5≦a≦4.5, and 0.0005≦b≦0.0030. The present invention provides a blue-color light-emitting aluminate phosphor which has a high emission output and a low decrease in its emission intensity during use, and a fluorescent lamp using the same.

Inventors

  • 👤 Masahiko Yamakawa
  • 👤 Kenji Terashima

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-08 16:22
CPC Classifications
C; C09; C09K; C09K11/00; C09K11/08; C09K11/77; C09K11/7728; C09K11/7734; H; H01; H01J; H01J61/00; H01J61/02; H01J61/38; H01J61/42; H01J61/44; C09K11/7715; C09K11/7716; C09K11/7718; C09K11/7721; C09K11/77212; C09K11/7729; C09K11/7731; C09K11/77342; C09K11/77344; C09K11/7743; C09K11/7744; C09K11/7746; C09K11/7749; C09K11/77492; C09K11/7783; C09K11/7784; C09K11/7787

Claims Analysis

Total Claims: 5
Claim 1
Independent Claim 33 words
A blue emitting phosphor represented by a general formula (Ba w Ca x Mg y Eu z )O.aAl 2 O 3 . bSIO 2 where 0.1≦w≦0.5, 0.0004≦x≦0.0020, 0.1≦y≦0.8, 0.03≦z≦0.10, w+x+y+z=1, 1.5≦a≦4.5, and 0.0005≦b≦0.0030.
Claim 2
Dependent Claim 33 words
A blue emitting phosphor represented by a general formula (Ba w Ca x Mg y Eu z )O.aAl 2 O 3 . bSIO 2 where 0.1≦w≦0.5, 0.0004≦x≦0.0020, 0.1≦y≦0.8, 0.03≦z≦0.10, w+x+y+z=1, 1.5≦a≦4.5, and 0.0005≦b≦0.0030.
Claim 3
Dependent Claim 10 words
A phosphor according to claim 1, wherein 2.0≦a≦3.0, or 0.0006≦x≦0.0015.
Claim 4
Dependent Claim 168 words
A fluorescent lamp comprising a phosphor film on an inner surface of a glass bulb, wherein said phosphor film contains a mixture of: a blue emitting first phosphor represented by a general formula (Ba w Ca x Mg y Eu z )O.aAl 2 O 3 .bSiO 2 where 0.1≦w≦0.5, 0.0004≦x≦0.0020, 0.1≦y≦0.8, 0.03≦z≦0.10, w+x+y+z=1, 1.5≦a≦4.5, and 0.0005≦b≦0.0030; a green emitting second phosphor represented by a general formula Ln 2 O 3 .c(Mg 1-u Ca u )O.d[(Al 2 O 3 ) 1-v (SiO 2 ) v ] (where Ln is at least one element selected from the group consisting of lanthanum, gadolinium, yttrium, cerium, and terbium, and 1.5≦c≦5.0, 2.5≦d≦14.0, 0.001≦u≦0.005, and 0.0002≦v≦0.0010); and a red emitting third phosphor represented by a general formula (Y 1-t Eu t ) 2 O 3 (where 0.020≦t≦0.065), the first, second, and third phosphors being contained in ratios of 0.2 to 35% by weight, 35 to 60% by weight, and 30 to 60% by weight, respectively, with respect to 100% by weight of the mixture.
Claim 5
Dependent Claim 168 words
A fluorescent lamp comprising a phosphor film on an inner surface of a glass bulb, wherein said phosphor film contains a mixture of: a blue emitting first phosphor represented by a general formula (Ba w Ca x Mg y Eu z )O.aAl 2 O 3 .bSiO 2 where 0.1≦w≦0.5, 0.0004≦x≦0.0020, 0.1≦y≦0.8, 0.03≦z≦0.10, w+x+y+z=1, 1.5≦a≦4.5, and 0.0005≦b≦0.0030; a green emitting second phosphor represented by a general formula Ln 2 O 3 .c(Mg 1-u Ca u )O.d[(Al 2 O 3 ) 1-v (SiO 2 ) v ] (where Ln is at least one element selected from the group consisting of lanthanum, gadolinium, yttrium, cerium, and terbium, and 1.5≦c≦5.0, 2.5≦d≦14.0, 0.001≦u≦0.005, and 0.0002≦v≦0.0010); and a red emitting third phosphor represented by a general formula (Y 1-t Eu t ) 2 O 3 (where 0.020≦t≦0.065), the first, second, and third phosphors being contained in ratios of 0.2 to 35% by weight, 35 to 60% by weight, and 30 to 60% by weight, respectively, with respect to 100% by weight of the mixture.

References Cited (Backward Citations)

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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1991-03-22 1991-09-21 1992-03-22 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1995-03-22 1995-09-21 1996-03-22 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1999-03-22 1999-09-21 2000-03-22 $7700.00 Window Closed / Lapsed

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