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US4150321A Expired / Lapsed US ⏱️ 0.0 years remaining

Luminescent aluminates and mercury vapor discharge lamp containing the same

Assignee: US Philips Corp
•
Filing: 1978-01-13
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Granted: 1979-04-17
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Expires: 1998-01-13
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Abstract

Abstract Luminescent aluminate with magnetoplumbite crystal structure, activated by cerium, by cerium and terbium or by cerium and manganese. The aluminate comprises at least one of the elements B, Si and P in a quantity of 0.001 to 0.20 mole per mole of aluminate which results in improved properties of luminescence. These aluminates are preferably used in low-pressure mercury vapor discharge lamps.

Inventors

  • 👤 Cornelis W. A. Schetters
  • 👤 Marinus G. A. Tak
  • 👤 Abraham Sonneveld

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-02 20:19
CPC Classifications
C; C09; C09K; C09K11/00; C09K11/08; C09K11/77; C09K11/7766; C09K11/7774; C09K11/7715; C09K11/7721; C09K11/77744

Claims Analysis

Total Claims: 5
Claim 1
Independent Claim 192 words
A luminescent aluminate having a magnetoplumbite crystal structure and having a composition of either the formula La 1-p-q Ce p Tb q Me x Al 2y O 1 .5+x+3y ;zZ wherein Me is at least one element selected from the group consisting of Mg, Zn and Be, Z is at least one element selected from the group consisting of B, Si and P, up to 25 mol % of Al being replaceable by Ga and/or Sc and wherein 0 ≦ x ≦ 2 5 ≦ y ≦ 15 0.001 ≦ Z ≦ 0.20 0.005 ≦ p ≦ 0.90 0 ≦ q ≦ 0.60 or the formula A 1-p Ce p Me p Al 12-p O 19 ;zZ, wherein A is at least one element selected from the group consisting of Sr and Ca, Me is at least one element selected from the group consisting of Mg, Zn and Be, and Z is at least one element selected from the group consisting of B, Si and P, wherein up to 25 mole % of Al being replaceable by Ga and/or Sc and wherein 0.005 ≦ p ≦ 0.25 0.001 ≦ z ≦ 0.20.
Claim 2
Dependent Claim 192 words
A luminescent aluminate having a magnetoplumbite crystal structure and having a composition of either the formula La 1-p-q Ce p Tb q Me x Al 2y O 1 .5+x+3y ;zZ wherein Me is at least one element selected from the group consisting of Mg, Zn and Be, Z is at least one element selected from the group consisting of B, Si and P, up to 25 mol % of Al being replaceable by Ga and/or Sc and wherein 0 ≦ x ≦ 2 5 ≦ y ≦ 15 0.001 ≦ Z ≦ 0.20 0.005 ≦ p ≦ 0.90 0 ≦ q ≦ 0.60 or the formula A 1-p Ce p Me p Al 12-p O 19 ;zZ, wherein A is at least one element selected from the group consisting of Sr and Ca, Me is at least one element selected from the group consisting of Mg, Zn and Be, and Z is at least one element selected from the group consisting of B, Si and P, wherein up to 25 mole % of Al being replaceable by Ga and/or Sc and wherein 0.005 ≦ p ≦ 0.25 0.001 ≦ z ≦ 0.20.
Claim 3
Dependent Claim 32 words
The luminescent aluminate of claim 1 wherein in the first formula Me is Mg and p+q=1, 1 ≦ x ≦ 2, 5.5 ≦ y ≦ 11 and 0.10 ≦ p ≦ 0.80.
Claim 4
Dependent Claim 18 words
A luminescent aluminate of claim 1 wherein in the second formula A is Sr and Me is Mg.
Claim 5
Dependent Claim 33 words
A low pressure mercury vapor discharge lamp comprising an envelope, two electrodes at opposite ends of said envelope, and a luminescent aluminate of claim 1 disposed on the inner surface of said envelope.

References Cited (Backward Citations)

NL7214862A Cited
US3836477A Cited
DE2509563A1 Cited
US4003845A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1982-04-16 1982-10-16 1983-04-17 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1986-04-16 1986-10-16 1987-04-17 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1990-04-16 1990-10-16 1991-04-17 $7700.00 Window Closed / Lapsed

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