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US4731302A Expired / Lapsed US ⏱️ 0.0 years remaining

Hard coatings for mechanically and corrosively stressed elements

Assignee: Technische Hochschule Karl-Marx-Stadt
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Filing: 1986-10-06
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Granted: 1988-03-15
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Expires: 2006-10-06
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Abstract

Abstract Hard coatings for mechanically and corrosively stressed elements are applicable to arbitrarily chosen substrate materials. The mentioned elements can be tools, cutting inserts or bearings. Further, applications are possible in electronics and optics and also for decorative purposes. Hard coatings on the basis of carbon and boron nitride, produced by known techniques, are obtained which can be used in a wide field of application, exhibiting, besides a high hardness, maximum adhesion and good protection against wear and corrosion at high temperatures. The C and B/N coatings consist of amorphous network structures with short range orders similar to that of the hexagonal crystalline phases of carbon and boron nitride, have hydrogen concentrations between 5 atom-% and 50 atom-% and additional components consisting of metals and/or boron and or silicon and/or noble gases in the concentration range between 1 atom-% and 85 atom-%.

Inventors

  • 👤 Christian Weissmantel
  • 👤 Bernd Rau
  • 👤 Klaus Bewilogua
  • 👤 Dietmar Roth
  • 👤 Bernd Rother

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-02 14:14
CPC Classifications
C; C23; C23C; C23C28/00; C23C28/04; C23C28/046; C23C16/00; C23C16/22; C23C16/26; C23C16/30; C23C16/34; C23C16/342; C23C28/044; C23C30/00; C23C30/005

Claims Analysis

Total Claims: 18
Claim 1
Independent Claim 93 words
A hard coating for mechanically and corrosively stressed parts, such as tools, tool inserts, bearings or corrosively stressed modules, comprising a boron nitride layer having an amorphous network structure with an atomic short-range order similar to that of hexagonal crystalline phases, bound hydrogen in an amount of from 5 atom percent to 50 atom percent for stabilizing the structure, and an additional material selected form the group consisting of metals, boron, silicon, inert gases and mixtures thereof intercalated in the structure in an amount of from 1 atom percent to 50 atom percent.
Claim 2
Dependent Claim 93 words
A hard coating for mechanically and corrosively stressed parts, such as tools, tool inserts, bearings or corrosively stressed modules, comprising a boron nitride layer having an amorphous network structure with an atomic short-range order similar to that of hexagonal crystalline phases, bound hydrogen in an amount of from 5 atom percent to 50 atom percent for stabilizing the structure, and an additional material selected form the group consisting of metals, boron, silicon, inert gases and mixtures thereof intercalated in the structure in an amount of from 1 atom percent to 50 atom percent.
Claim 3
Dependent Claim 31 words
A hard coating as in claim 1, further comprising a substrate selected from the group consisting of hard metal, high-speed steel, aluminum, silicon, copper, brass, bronze, zinc, ceramics and rock salt.
Claim 4
Dependent Claim 25 words
A hard coating as in claim 1, deposited on a substrate and having an intermediate layer selected from the group consisting of TiN and Al.
Claim 5
Dependent Claim 24 words
A hard coating as in claim 1, deposited on a substrate by an ion-assisted technique using ion energies between 50 eV and 10,000 eV.
Claim 6
Dependent Claim 19 words
A hard coating as in claim 1, wherein the incorporated components exist in the coating as molecules and/or clusters.
Claim 7
Dependent Claim 23 words
A hard coating as in claim 1, wherein the constituents of the coating have a varying concentration through the thickness of the coating.
Claim 8
Dependent Claim 17 words
A hard coating as in claim 1, having a thickness of from 0.01 μm to 20 μm.
Claim 9
Dependent Claim 17 words
A hard coating as in claim 1, having a hardness of from 10 GPa to 60 GPa.
Claim 10
Dependent Claim 92 words
A hard coating for mechanically and corrosively stressed parts, such as tools, tool inserts, bearings or corrosively stressed modules, comprising a carbon layer having an amorphous network structure with an atomic short-range order similar to that of hexagonal crystalline phases, bound hydrogen in an amount of from 5 atom percent to 50 atom percent for stabilizing the structure, and an additional material selected from the group consisting of metals, boron, silicon, inert gases and mixtures thereof intercalated in the structure in an amount of from 1 atom percent to 50 atom percent.
Claim 11
Dependent Claim 92 words
A hard coating for mechanically and corrosively stressed parts, such as tools, tool inserts, bearings or corrosively stressed modules, comprising a carbon layer having an amorphous network structure with an atomic short-range order similar to that of hexagonal crystalline phases, bound hydrogen in an amount of from 5 atom percent to 50 atom percent for stabilizing the structure, and an additional material selected from the group consisting of metals, boron, silicon, inert gases and mixtures thereof intercalated in the structure in an amount of from 1 atom percent to 50 atom percent.
Claim 12
Dependent Claim 31 words
A hard coating as in claim 9, further comprising a substrate selected from the group consisting of hard metal, high-speed steel, aluminum, silicon, copper, brass, bronze, zinc, ceramics and rock salt.
Claim 13
Dependent Claim 25 words
A hard coating as in claim 9, deposited on a substrate and having an intermediate layer selected from the group consisting of TiN and Al.
Claim 14
Dependent Claim 24 words
A hard coating as in claim 9, deposited on a substrate by an ion-assisted technique using ion energies between 50 eV and 10,000 eV.
Claim 15
Dependent Claim 19 words
A hard coating as in claim 9, wherein the incorporated components exist in the coating as molecules and/or clusters.
Claim 16
Dependent Claim 23 words
A hard coating as in claim 9, wherein the constituents of the coating have a varying concentration through the thickness of the coating.
Claim 17
Dependent Claim 17 words
A hard coating as in claim 9, having a thickness of from 0.01 μm to 20 μm.
Claim 18
Dependent Claim 17 words
A hard coating as in claim 9, having a hardness of from 10 GPa to 60 GPa.

References Cited (Backward Citations)

US4645715A Cited
US4594294A Cited
US4522844A Cited
US4643951A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1991-03-15 1991-09-14 1992-03-15 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1995-03-15 1995-09-14 1996-03-15 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1999-03-15 1999-09-14 2000-03-15 $7700.00 Window Closed / Lapsed

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