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US4728716A Expired / Lapsed US ⏱️ 0.0 years remaining

Polycarbonate exhibiting improved impact properties containing divalent residue of polymerized alkadiene monomer

Assignee: General Electric Co
•
Filing: 1985-11-12
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Granted: 1988-03-01
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Expires: 2005-11-12
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Abstract

Abstract An aromatic carbonate resin comprised of: (i) at least one recurring structural unit represented by the formula ##STR1## (ii) at least one recurring structural unit selected from structural units represented by the formulae ##STR2## wherein R is independently selected from halogen, monovalent hydrocarbon, and monovalent hydrocarbonoxy radicals; W is selected from divalent hydrocarbon radicals, --O--, --S--, --S--S--, ##STR3## A is a divalent residue of at least one conjugated alkadiene and has a weight average molecular weight of at least about 600, m is independently selected from integers having a value of from 0 to 4, and b is either zero or one. The carbonate resin contains an amount of (ii) at least effective to improve the impact properties thereof.

Inventors

  • 👤 Victor Mark, deceased
  • 👤 legal representative Ester H. Mark
  • 👤 Edward N. Peters

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-05 09:09
CPC Classifications
C; C08; C08G; C08G64/00; C08G64/04; C08G64/06

Claims Analysis

Total Claims: 19
Claim 1
Independent Claim 108 words
An aromatic carbonate resin comprised of: (i) at least one recurring structural unit represented by the formula ##STR18## and (ii) at least one recurring structural unit selected from structural units represented by the formulae ##STR19## or mixtures thereof; wherein R is independently selected from halogen, monovalent hydrocarbon radicals, or monovalent hydrocarbonoxy radicals, W is selected from divalent hydrocarbon radicals, --O--, --S--, --S--S--, ##STR20## A is the divalent residue of at least one polymerized conjugated alkadiene and has a weight average molecular weight of at least about 600, m is independently selected from integers having a value of from 0 to 4, and b is either zero or one.
Claim 2
Dependent Claim 108 words
An aromatic carbonate resin comprised of: (i) at least one recurring structural unit represented by the formula ##STR18## and (ii) at least one recurring structural unit selected from structural units represented by the formulae ##STR19## or mixtures thereof; wherein R is independently selected from halogen, monovalent hydrocarbon radicals, or monovalent hydrocarbonoxy radicals, W is selected from divalent hydrocarbon radicals, --O--, --S--, --S--S--, ##STR20## A is the divalent residue of at least one polymerized conjugated alkadiene and has a weight average molecular weight of at least about 600, m is independently selected from integers having a value of from 0 to 4, and b is either zero or one.
Claim 3
Dependent Claim 20 words
The resin of claim 1 which contains an amount of (ii) at least effective to improve the impact properties thereof.
Claim 4
Dependent Claim 27 words
The resin of claim 2 wherein said amount of (ii) is at least about 1.0 weight percent, based on the total amounts of (i) and (ii) present.
Claim 5
Dependent Claim 15 words
The resin of claim 3 wherein said amount is at least about 2 weight percent.
Claim 6
Dependent Claim 15 words
The resin of claim 4 wherein said amount is at least about 3 weight percent.
Claim 7
Dependent Claim 15 words
The resin of claim 5 wherein said amount is at least about 4 weight percent.
Claim 8
Dependent Claim 21 words
The resin of claim 1 which contains an amount of (ii) effective to impart to said resin rubbery and elastomeric properties.
Claim 9
Dependent Claim 47 words
The resin of claim 1 wherein said conjugated alkadiene is a monomer represented by the formula ##STR21## wherein R 1 -R 6 are independently selected from hydrogen, halogen, or alkyl radicals, with the proviso that not more than two of R 1 -R 6 are halogen radicals.
Claim 10
Dependent Claim 18 words
The resin of claim 8 wherein R 1 -R 6 are independently selected from hydrogen or alkyl radicals.
Claim 11
Dependent Claim 16 words
The resin of claim 9 wherein said alkadiene is selected from 1,3-butadiene, 2-methyl-1,3-butadiene, or mixtures thereof.
Claim 12
Dependent Claim 19 words
The resin of claim 1 wherein (ii) is at least one recurring structural unit represented by the formula ##STR22##
Claim 13
Dependent Claim 9 words
The resin of claim 11 wherein b is one.
Claim 14
Dependent Claim 9 words
The resin of claim 11 wherein W is 2,2-propylidene.
Claim 15
Dependent Claim 9 words
The resin of claim 13 wherein m is zero.
Claim 16
Dependent Claim 19 words
The resin of claim 1 wherein (ii) is at least one recurring structural unit represented by the formula ##STR23##
Claim 17
Dependent Claim 9 words
The resin of claim 15 wherein b is one.
Claim 18
Dependent Claim 9 words
The resin of claim 16 wherein W is 2,2-propylidene.
Claim 19
Dependent Claim 9 words
The resin of claim 17 wherein m is zero.

References Cited (Backward Citations)

GB912898A Cited
US4381358A Cited
US4415722A Cited
US4501875A Cited
US4526956A Cited
US4476294A Cited
US4504649A Cited
US4579903A Cited
US4628081A Cited
US4677183A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1991-03-01 1991-08-31 1992-03-01 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1995-03-01 1995-08-31 1996-03-01 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1999-03-01 1999-08-31 2000-03-01 $7700.00 Window Closed / Lapsed

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