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US4726906A Expired / Lapsed US ⏱️ 0.0 years remaining

Polymers for use as filtration control aids in drilling muds

Assignee: ECC SPECIALTY CHEMICALS Inc
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Filing: 1986-12-04
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Granted: 1988-02-23
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Expires: 2006-12-04
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Abstract

Abstract The instant invention is directed to a polymer, having an intrinsic viscosity of 1.0 to 7.0, preferably 1.5 to 5.0, dl/g in 1.0 M NaCl, prepared from: (A) 2.5 to 45%, by weight, of at least one unsaturated carboxylic acid, or its salt; (B) 5.0 to 85%, by weight, of at least one unsaturated sulfonic acid, or its salt; (C) 2.5 to 15%, by weight, of at least one unsaturated cationic-containing monomer; and (D) 0 to 90%, by weight, of at least one unsaturated non-ionic monomer. The instant invention is also directed to the polymer in combination with an aqueous clay dispersion and the use of the admixture as a filtration aid in drilling muds.

Inventors

  • 👤 Shih-Ruey T. Chen
  • 👤 Christine A. Costello
  • 👤 Gary F. Matz

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-02 08:25
CPC Classifications
C; C08; C08F; C08F228/00; C08F220/00; C08F220/02; C08F220/04; C08F246/00; C09; C09K; C09K8/00; C09K8/02; C09K8/04; C09K8/14; C09K8/18; C09K8/22; C09K8/24

Claims Analysis

Total Claims: 5
Claim 1
Independent Claim 137 words
An aqueous drilling fluid comprising: (i) an aqueous clay dispersion; and (ii) a polymer, having an intrinsic viscosity of 1.0 to 7.0 dl/g in 1.0 M NaCl, prepared from: (A) 25 to 35%, by weight, of at least one unsaturated carboxylic acid selected from the group consisting of acrylic acid, methacrylic acid and their salts; (B) 25 to 40%, by weight, of at least one unsaturated sulfonic acid selected from the group consisting of 2-acrylamido-2-methylpropyl sulfonic acid, 2-methacrylamido-2-methylpropyl sulfonic acid, and their salts; (C) 5 to 10%, by weight, of at least one unsaturated cationic containing monomer selected from the group consisting of dimethyldiallyl ammonium chloride, dimethyldiallyl ammonium chloride and methacryloyloxyethyl trimethyl ammonium chloride; and (D) 15 to 45%, by weight, of at least one unsaturated non-ionic monomer selected from the group consisting of acrylamide and methacrylamide.
Claim 2
Dependent Claim 137 words
An aqueous drilling fluid comprising: (i) an aqueous clay dispersion; and (ii) a polymer, having an intrinsic viscosity of 1.0 to 7.0 dl/g in 1.0 M NaCl, prepared from: (A) 25 to 35%, by weight, of at least one unsaturated carboxylic acid selected from the group consisting of acrylic acid, methacrylic acid and their salts; (B) 25 to 40%, by weight, of at least one unsaturated sulfonic acid selected from the group consisting of 2-acrylamido-2-methylpropyl sulfonic acid, 2-methacrylamido-2-methylpropyl sulfonic acid, and their salts; (C) 5 to 10%, by weight, of at least one unsaturated cationic containing monomer selected from the group consisting of dimethyldiallyl ammonium chloride, dimethyldiallyl ammonium chloride and methacryloyloxyethyl trimethyl ammonium chloride; and (D) 15 to 45%, by weight, of at least one unsaturated non-ionic monomer selected from the group consisting of acrylamide and methacrylamide.
Claim 3
Dependent Claim 23 words
The aqueous drilling fluid of claim 1, wherein said polymer has an intrinsic viscosity of 1.5 to 5.0 dl/g in 1.0 M NaCl.
Claim 4
Independent Claim 161 words
A method for drilling a well in a subterranean formation, comprising circulating into the well, during drilling, an aqueous drilling fluid, the improvement wherein said aqueous drilling fluid comprises: (i) an aqueous clay dispersion; and (ii) a polymer, having an intrinsic viscosity of 1.0 to 7.0 dl/g in 1.0 M NaCl, prepared from: (A) 25 to 35%, by weight, of at least one unsaturated carboxylic acid selected from the group consisting of acrylic acid, methacrylic acid and their salts; (B) 25 to 40%, by weight, of at least one unsaturated sulfonic acid selected from the group consisting of 2-acrylamido-2-methylpropyl sulfonic acid, 2-methacrylamido-2-methylpropyl sulfonic acid, and their salts; (C) 5 to 10%, by weight, of at least one unsaturated cationic containing monomer selected from the group consisting of dimethyldiallyl ammonium chloride, dimethyldiallyl ammonium chloride and methacryloyloxyethyl trimethyl ammonium chloride; and (D) 15 to 45%, by weight, of at least one unsaturated non-ionic monomer selected from the group consisting of acrylamide and methacrylamide.
Claim 5
Independent Claim 161 words
A method for drilling a well in a subterranean formation, comprising circulating into the well, during drilling, an aqueous drilling fluid, the improvement wherein said aqueous drilling fluid comprises: (i) an aqueous clay dispersion; and (ii) a polymer, having an intrinsic viscosity of 1.0 to 7.0 dl/g in 1.0 M NaCl, prepared from: (A) 25 to 35%, by weight, of at least one unsaturated carboxylic acid selected from the group consisting of acrylic acid, methacrylic acid and their salts; (B) 25 to 40%, by weight, of at least one unsaturated sulfonic acid selected from the group consisting of 2-acrylamido-2-methylpropyl sulfonic acid, 2-methacrylamido-2-methylpropyl sulfonic acid, and their salts; (C) 5 to 10%, by weight, of at least one unsaturated cationic containing monomer selected from the group consisting of dimethyldiallyl ammonium chloride, dimethyldiallyl ammonium chloride and methacryloyloxyethyl trimethyl ammonium chloride; and (D) 15 to 45%, by weight, of at least one unsaturated non-ionic monomer selected from the group consisting of acrylamide and methacrylamide.

References Cited (Backward Citations)

US4147681A Cited
US4293427A Cited
US4505828A Cited
US4305860A Cited
US4455240A Cited
US4471097A Cited
US4536292A Cited
US4626362A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1991-02-22 1991-08-24 1992-02-23 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1995-02-22 1995-08-24 1996-02-23 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1999-02-22 1999-08-24 2000-02-23 $7700.00 Window Closed / Lapsed

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