Patent US4723005A successfully refreshed from Google Patents.
US4723005A
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Anisotropic compounds and liquid crystal mixtures
Assignee: Merck Patent GmbH
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Filing: 1984-09-10
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Granted: 1988-02-02
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Expires: 2004-09-10
Abstract
Abstract New anisotropic compounds of the formula (1) are useful in liquid crystal mixtures for electrooptical displays; at least one of the end groups of the compounds (1) is an alkyl group which carries cyano or halogen in a terminal or non-terminal position. This offers advantages for longitudinal polarization and/or cross-polarization of the anisotropic compounds with the aid of the comparatively highly polarizing cyano or halogen substituents, in particular high clear points, low Δε/ε⊥ values and/or negative Δε values.
Inventors
- 👤 Tuong Huynh-Ba
- 👤 Maged A. Osman
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-27 13:20
CPC Classifications
C; C07; C07C; C07C255/00; C07C22/00; C07C22/02; C07C22/04; C07C43/00; C07C43/02; C07C43/18; C07C43/192; C07C43/20; C07C43/225; C07D; C07D237/00; C07D237/02; C07D237/06; C07D237/08; C07D237/10; C07D237/14; C09; C09K; C09K19/00; C09K19/04; C09K19/06; C09K19/08; C09K19/30; C09K19/3001; C09K19/32; C09K19/321; C09K19/34; C09K19/3441; C09K19/345; C09K19/3455; C09K19/3458
Claims Analysis
Total Claims: 8
Claim 1
Independent Claim
246 words
A compound of the formula ##STR22## wherein the rings A, B and C are identical or different, ring A is a cycloaliphatic radical of the formula (1a) or (1b) ##STR23## and the remaining rings B and C are (1a), (1b), (1c), (1d) or (1e), (1c), (1d) and (1e) being the aromatic radicals of the formulae ##STR24## X is cyano or halogen, Z 1 and Z 2 are identical or different and each is a covalent bond, --COO--, or --OOC--, S is 0 or 1; and R is alkyl, alkoxy, alkoxycarbonyl, alkylcarbonyloxy or alkylamino, the alkyl part of which in each case contains 1 to 12C atoms, or is a radical of the formula (1f) ##STR25## wherein the ring D is one of the rings defined for B and C, Z 3 has one of the meanings given for Z 1 and Z 2 and R 1 has one of the meanings given for R with the exception of the radical of the formula (1f), or when the ring adjacent to R is of the formula 1c, 1d or 1e, R can also be H, cyano or halogen; with provisos that (a) when an oxygen atom is bonded directly to one of the cycloaliphatic radicals of the formula (1a) or (1b) present in the molecule, then no other oxygen atom and no nitrogen atom is bonded directly to that cycloaliphatic radical; and (b) the molecule contains a total of at most one carboxyl group --COO-- or --OOC--.
Claim 2
Dependent Claim
246 words
A compound of the formula ##STR22## wherein the rings A, B and C are identical or different, ring A is a cycloaliphatic radical of the formula (1a) or (1b) ##STR23## and the remaining rings B and C are (1a), (1b), (1c), (1d) or (1e), (1c), (1d) and (1e) being the aromatic radicals of the formulae ##STR24## X is cyano or halogen, Z 1 and Z 2 are identical or different and each is a covalent bond, --COO--, or --OOC--, S is 0 or 1; and R is alkyl, alkoxy, alkoxycarbonyl, alkylcarbonyloxy or alkylamino, the alkyl part of which in each case contains 1 to 12C atoms, or is a radical of the formula (1f) ##STR25## wherein the ring D is one of the rings defined for B and C, Z 3 has one of the meanings given for Z 1 and Z 2 and R 1 has one of the meanings given for R with the exception of the radical of the formula (1f), or when the ring adjacent to R is of the formula 1c, 1d or 1e, R can also be H, cyano or halogen; with provisos that (a) when an oxygen atom is bonded directly to one of the cycloaliphatic radicals of the formula (1a) or (1b) present in the molecule, then no other oxygen atom and no nitrogen atom is bonded directly to that cycloaliphatic radical; and (b) the molecule contains a total of at most one carboxyl group --COO-- or --OOC--.
Claim 3
Dependent Claim
9 words
A compound of claim 1 wherein s is 0.
Claim 4
Dependent Claim
12 words
A compound of claim 1 wherein R and R 1 are alkyl.
Claim 5
Dependent Claim
30 words
A compound of claim 1 wherein R is cyano, fluorine or chlorine and the ring bonded directly to R is an aromatic radical of the formula (1c), (1d) or (1e).
Claim 6
Dependent Claim
25 words
A compound of claim 1 wherein at least one of the bridge members Z 1 , Z 2 or Z 3 is a covalent bond.
Claim 7
Dependent Claim
20 words
A compound of claim 1 wherein the rings A and B are radicals of the formula (1a), (1b) or (1c).
Claim 8
Dependent Claim
11 words
A compound of claim 1 wherein halo is F or Cl.
References Cited (Backward Citations)
US4027950A
Cited
US3983049A
Cited
DE2544577A1
Cited
GB1596011A
Cited
US4293434A
Cited
US4393231A
Cited
US4348324A
Cited
US4330426A
Cited
US4311610A
Cited
US4344856A
Cited
US4361494A
Cited
US4363767A
Cited
EP0047877A2
Cited
JPS5750933A
Cited
JPS5754137A
Cited
US4400293A
Cited
DD155063A1
Cited
JPS5799542A
Cited
GB2092169A
Cited
JPS57108056A
Cited
US4564694A
Cited
EP0058981A2
Cited
US4583826A
Cited
GB2111993A
Cited
US4572794A
Cited
US4514317A
Cited
DE3302218A1
Cited
US4510069A
Cited
US4550981A
Cited
US4565425A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1991-02-01 | 1991-08-03 | 1992-02-02 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1995-02-01 | 1995-08-03 | 1996-02-02 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1999-02-01 | 1999-08-03 | 2000-02-02 | $7700.00 | Window Closed / Lapsed |