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Anisotropic compounds and liquid crystal mixtures

Assignee: Merck Patent GmbH
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Filing: 1984-09-10
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Granted: 1988-02-02
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Expires: 2004-09-10
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Abstract

Abstract New anisotropic compounds of the formula (1) are useful in liquid crystal mixtures for electrooptical displays; at least one of the end groups of the compounds (1) is an alkyl group which carries cyano or halogen in a terminal or non-terminal position. This offers advantages for longitudinal polarization and/or cross-polarization of the anisotropic compounds with the aid of the comparatively highly polarizing cyano or halogen substituents, in particular high clear points, low Δε/ε⊥ values and/or negative Δε values.

Inventors

  • 👤 Tuong Huynh-Ba
  • 👤 Maged A. Osman

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-27 13:20
CPC Classifications
C; C07; C07C; C07C255/00; C07C22/00; C07C22/02; C07C22/04; C07C43/00; C07C43/02; C07C43/18; C07C43/192; C07C43/20; C07C43/225; C07D; C07D237/00; C07D237/02; C07D237/06; C07D237/08; C07D237/10; C07D237/14; C09; C09K; C09K19/00; C09K19/04; C09K19/06; C09K19/08; C09K19/30; C09K19/3001; C09K19/32; C09K19/321; C09K19/34; C09K19/3441; C09K19/345; C09K19/3455; C09K19/3458

Claims Analysis

Total Claims: 8
Claim 1
Independent Claim 246 words
A compound of the formula ##STR22## wherein the rings A, B and C are identical or different, ring A is a cycloaliphatic radical of the formula (1a) or (1b) ##STR23## and the remaining rings B and C are (1a), (1b), (1c), (1d) or (1e), (1c), (1d) and (1e) being the aromatic radicals of the formulae ##STR24## X is cyano or halogen, Z 1 and Z 2 are identical or different and each is a covalent bond, --COO--, or --OOC--, S is 0 or 1; and R is alkyl, alkoxy, alkoxycarbonyl, alkylcarbonyloxy or alkylamino, the alkyl part of which in each case contains 1 to 12C atoms, or is a radical of the formula (1f) ##STR25## wherein the ring D is one of the rings defined for B and C, Z 3 has one of the meanings given for Z 1 and Z 2 and R 1 has one of the meanings given for R with the exception of the radical of the formula (1f), or when the ring adjacent to R is of the formula 1c, 1d or 1e, R can also be H, cyano or halogen; with provisos that (a) when an oxygen atom is bonded directly to one of the cycloaliphatic radicals of the formula (1a) or (1b) present in the molecule, then no other oxygen atom and no nitrogen atom is bonded directly to that cycloaliphatic radical; and (b) the molecule contains a total of at most one carboxyl group --COO-- or --OOC--.
Claim 2
Dependent Claim 246 words
A compound of the formula ##STR22## wherein the rings A, B and C are identical or different, ring A is a cycloaliphatic radical of the formula (1a) or (1b) ##STR23## and the remaining rings B and C are (1a), (1b), (1c), (1d) or (1e), (1c), (1d) and (1e) being the aromatic radicals of the formulae ##STR24## X is cyano or halogen, Z 1 and Z 2 are identical or different and each is a covalent bond, --COO--, or --OOC--, S is 0 or 1; and R is alkyl, alkoxy, alkoxycarbonyl, alkylcarbonyloxy or alkylamino, the alkyl part of which in each case contains 1 to 12C atoms, or is a radical of the formula (1f) ##STR25## wherein the ring D is one of the rings defined for B and C, Z 3 has one of the meanings given for Z 1 and Z 2 and R 1 has one of the meanings given for R with the exception of the radical of the formula (1f), or when the ring adjacent to R is of the formula 1c, 1d or 1e, R can also be H, cyano or halogen; with provisos that (a) when an oxygen atom is bonded directly to one of the cycloaliphatic radicals of the formula (1a) or (1b) present in the molecule, then no other oxygen atom and no nitrogen atom is bonded directly to that cycloaliphatic radical; and (b) the molecule contains a total of at most one carboxyl group --COO-- or --OOC--.
Claim 3
Dependent Claim 9 words
A compound of claim 1 wherein s is 0.
Claim 4
Dependent Claim 12 words
A compound of claim 1 wherein R and R 1 are alkyl.
Claim 5
Dependent Claim 30 words
A compound of claim 1 wherein R is cyano, fluorine or chlorine and the ring bonded directly to R is an aromatic radical of the formula (1c), (1d) or (1e).
Claim 6
Dependent Claim 25 words
A compound of claim 1 wherein at least one of the bridge members Z 1 , Z 2 or Z 3 is a covalent bond.
Claim 7
Dependent Claim 20 words
A compound of claim 1 wherein the rings A and B are radicals of the formula (1a), (1b) or (1c).
Claim 8
Dependent Claim 11 words
A compound of claim 1 wherein halo is F or Cl.

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1991-02-01 1991-08-03 1992-02-02 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1995-02-01 1995-08-03 1996-02-02 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1999-02-01 1999-08-03 2000-02-02 $7700.00 Window Closed / Lapsed

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