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US4363767A Expired / Lapsed US ⏱️ 0.0 years remaining

Esters of 4-[2,2-dicyano-ethenyl]-phenols

Assignee: Samsung SDI Co Ltd
•
Filing: 1980-10-03
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Granted: 1982-12-14
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Expires: 2000-10-03
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Abstract

Abstract The invention relates to liquid-crystalline nematic mixtures which are used in electro-optical components, as well as to methods for their preparation. The object of the invention is liquid-crystalline mixtures for electro-optical arrangements possessing high positive electrical anisotropy at a high clarification point, as well as methods for their preparation. According to the invention, liquid-crystalline nematic mixtures are used, wherein at least one component is a 1,4-disubstituted benzene derivative and the other compound is an ester of 4-[2,2-dicyano-ethenyl]-phenol of the general formula ##STR1## wherein R 1 denotes added groups of various characters such as alkyl or alkoxy for example, X is aromatic, cycloaliphatic or a heterocyclic ring system such as phenyl or cyclohexyl for example; and Y is a connector such as carbonyloxy, azomethine, azoxy. These are prepared by reaction with reactive acid derivatives, particularly acid chlorides, or by a Knoevenagel-condensation by reacting respective 4-subst.-benzoic acid-[4-formyl-phenyl esters] or 4-alkyl-cyclohexanecarboxylic acid-[4-formyl-phenyl esters] with malonic acid dinitrile.

Inventors

  • 👤 Dietrich Demus
  • 👤 Wolfgang Weissflog
  • 👤 Horst Zaschke
  • 👤 Rudolf Wolff
  • 👤 Horst Kresse

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-24 23:20
CPC Classifications
C; C07; C07C; C07C255/00; C09; C09K; C09K19/00; C09K19/04; C09K19/42

Claims Analysis

Total Claims: 14
Claim 1
Independent Claim 22 words
An ester of a 4-(2,2-dicyano-ethenyl)phenol of the formula ##STR19## wherein R 1 =C 2 H 5 or C 6 H 13 .
Claim 2
Dependent Claim 22 words
An ester of a 4-(2,2-dicyano-ethenyl)phenol of the formula ##STR19## wherein R 1 =C 2 H 5 or C 6 H 13 .
Claim 3
Dependent Claim 53 words
An ester of a 4-(2,2-dicyano-ethenyl)phenol of the formula ##STR20## wherein R 1 =C 6 H 13 , C 4 H 9 O, C 5 H 11 O, C 6 H 13 O, C 9 H 19 O, C 4 H 9 COO, C 6 H 13 COO, or C 6 H 13 OCOO.
Claim 4
Dependent Claim 53 words
An ester of a 4-(2,2-dicyano-ethenyl)phenol of the formula ##STR20## wherein R 1 =C 6 H 13 , C 4 H 9 O, C 5 H 11 O, C 6 H 13 O, C 9 H 19 O, C 4 H 9 COO, C 6 H 13 COO, or C 6 H 13 OCOO.
Claim 5
Dependent Claim 13 words
The compound of claim 2 which is a compound of the formula ##STR21##
Claim 6
Dependent Claim 13 words
The compound of claim 2 which is a compound of the formula ##STR22##
Claim 7
Dependent Claim 13 words
The compound of claim 2 which is a compound of the formula ##STR23##
Claim 8
Dependent Claim 13 words
The compound of claim 2 which is a compound of the formula ##STR24##
Claim 9
Dependent Claim 13 words
The compound of claim 2 which is a compound of the formula ##STR25##
Claim 10
Dependent Claim 13 words
The compound of claim 2 which is a compound of the formula ##STR26##
Claim 11
Dependent Claim 13 words
The compound of claim 2 which is a compound of the formula ##STR27##
Claim 12
Dependent Claim 13 words
The compound of claim 2 which is a compound of the formula ##STR28##
Claim 13
Dependent Claim 13 words
The compound of claim 1 which is a compound of the formula ##STR29##
Claim 14
Dependent Claim 13 words
The compound of claim 1 which is a compound of the formula ##STR30##

References Cited (Backward Citations)

US4147655A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1985-12-13 1986-06-14 1986-12-14 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1989-12-13 1990-06-14 1990-12-14 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1993-12-13 1994-06-14 1994-12-14 $7700.00 Window Closed / Lapsed

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