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2,2-difluoropropionic acid derivatives

Assignee: Daikin Industries Ltd
•
Filing: 1984-12-20
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Granted: 1988-01-12
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Expires: 2004-12-20
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Abstract

Abstract 2,2,3-trifluoropropionyl fluoride is prepared by opening the ring of tetrafluorooxetane in the presence of a catalyst. Analogously, a novel 2,2-difluoropropionic acid derivative of the formula: XCH.sub.2 CF.sub.2 COY (I) wherein X is chlorine, bromine, iodine, a group of the formula: R.sub.1 O-- (II) or R.sub.2 COO-- (III) wherein R 1 R 2 are each an aliphaic or halogenated aliphatic hydrocarbon group having 1 to 8 carbon atoms or an aromatic hydrocarbon group having 6 to 8 carbon atoms optionally bearing at least one substituent, or a group of the formula: X'CH.sub.2 CF.sub.2 CF.sub.2 O-- (IV) wherein X' is fluorine, chlorine, bromine, iodine, the group of the formula: R 1 O--or R 2 COO--; and Y is fluorine or a group of the formula: --OR.sub.3 (V) wherein R 3 is an aliphatic or halogenated aliphatic hydrocarbon group having 1 to 8 carbon atoms except a perfluorohydrocarbon group or an aromatic hydrocarbon group having 6 to 8 carbon atoms optionally bearing at least one substituent or of the formula : --OCH.sub.2 R.sub.f (V') wherein R f is an aliphatic perfluorohydrocarbon having 1 to 7 carbon atoms is prepared.

Inventors

  • 👤 Yohnosuke Ohsaka
  • 👤 Takashi Tohzuka
  • 👤 Shoji Takaki
  • 👤 Yoshio Negishi
  • 👤 Satoru Kohno

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-02 17:40
CPC Classifications
C; C07; C07C; C07C53/00; C07C51/00; C07C51/58

Claims Analysis

Total Claims: 9
Claim 1
Independent Claim 96 words
A 2,2-difluoropropionic acid derivative of the formula: XCH.sub.2 CF.sub.2 COY wherein X is bromine, iodine, a group of the formula: R.sub.1 O-- or R.sub.2 COO-- wherein R 1 and R 2 are each an aliphatic or halogenated aliphatic hydrocarbon group having 1 to 8 carbon atoms or an aromatic hydrocarbon group selected from the group consisting of phenyl, toluyl, trifluoromethylphenyl, chlorophenyl, and bromophenyl, or a group of the formula: X'CH.sub.2 CF.sub.2 CF.sub.2 O-- wherein X' is fluorine, chlorine, bromine, iodine, the group of the formula: R 1 O-- and R 2 COO--; and Y is fluorine.
Claim 2
Dependent Claim 96 words
A 2,2-difluoropropionic acid derivative of the formula: XCH.sub.2 CF.sub.2 COY wherein X is bromine, iodine, a group of the formula: R.sub.1 O-- or R.sub.2 COO-- wherein R 1 and R 2 are each an aliphatic or halogenated aliphatic hydrocarbon group having 1 to 8 carbon atoms or an aromatic hydrocarbon group selected from the group consisting of phenyl, toluyl, trifluoromethylphenyl, chlorophenyl, and bromophenyl, or a group of the formula: X'CH.sub.2 CF.sub.2 CF.sub.2 O-- wherein X' is fluorine, chlorine, bromine, iodine, the group of the formula: R 1 O-- and R 2 COO--; and Y is fluorine.
Claim 3
Dependent Claim 18 words
A derivative according to claim 1, wherein X is selected from the group consisting of bromine and iodine.
Claim 4
Dependent Claim 21 words
A derivative according to claim 1, wherein X is the group of the formula: R.sub.1 O-- (II) or R.sub.2 COO-- (III).
Claim 5
Dependent Claim 19 words
A derivative according to claim 1, wherein X is a group of the formula: X'CH.sub.2 CF.sub.2 CF.sub.2 O-- (IV).
Claim 6
Dependent Claim 147 words
A 2,2-difluoropropionic acid derivative of the formula: XCH.sub.2 CF.sub.2 COY wherein X is X'CH 2 CF 2 CF 2 O-- wherein X' is fluorine, chlorine, bromine, iodine, the group of the formula: R 1 O-- or R 2 COO--, wherein R 1 and R 2 are each an aliphatic or halogenated aliphatic hydrocarbon group having 1 to 8 carbon atoms or an aromatic hydrocarbon group selected from the group consisting of phenyl, toluyl, trifluoromethylphenyl, chlorophenyl, and bromophenyl, and Y is fluorine or a group of the formula: --OR.sub.3 wherein R 3 is an aliphatic or halogenated aliphatic hydrocarbon group having 1 to 8 carbon atoms, except a perfluorohydrocarbon group, or an aromatic hydrocarbon group selected from the group consisting of phenyl, toluyl, trifluoromethylphenyl, chlorophenyl, and bromophenyl, or a group of the formula: --OCH.sub.2 R.sub.f wherein R f is an aliphatic perfluorohydrocarbon having 1 to 7 carbon atoms.
Claim 7
Dependent Claim 147 words
A 2,2-difluoropropionic acid derivative of the formula: XCH.sub.2 CF.sub.2 COY wherein X is X'CH 2 CF 2 CF 2 O-- wherein X' is fluorine, chlorine, bromine, iodine, the group of the formula: R 1 O-- or R 2 COO--, wherein R 1 and R 2 are each an aliphatic or halogenated aliphatic hydrocarbon group having 1 to 8 carbon atoms or an aromatic hydrocarbon group selected from the group consisting of phenyl, toluyl, trifluoromethylphenyl, chlorophenyl, and bromophenyl, and Y is fluorine or a group of the formula: --OR.sub.3 wherein R 3 is an aliphatic or halogenated aliphatic hydrocarbon group having 1 to 8 carbon atoms, except a perfluorohydrocarbon group, or an aromatic hydrocarbon group selected from the group consisting of phenyl, toluyl, trifluoromethylphenyl, chlorophenyl, and bromophenyl, or a group of the formula: --OCH.sub.2 R.sub.f wherein R f is an aliphatic perfluorohydrocarbon having 1 to 7 carbon atoms.
Claim 8
Dependent Claim 10 words
A derivative according to claim 5, wherein Y is fluorine.
Claim 9
Dependent Claim 17 words
A derivative according to claim 5, wherein Y is --OR 3 or --OCH 2 R f .

References Cited (Backward Citations)

US2010154A Cited
US2678953A Cited
US3950160A Cited

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