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US4713312A Expired / Lapsed US ⏱️ 0.0 years remaining

Imaging system employing photosensitive microcapsules containing 3-substituted coumarins and other photobleachable sensitizers

Assignee: Eastman Kodak Co
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Filing: 1986-12-10
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Granted: 1987-12-15
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Expires: 2006-12-10
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Abstract

Abstract Imaging systems employing photosensitive microcapsules having improved film speed are disclosed wherein the microcapsules contain a photosensitive composition in which the photoinitiator system includes a photobleachable sensitizer such as a 3-substituted coumarin compound; the invention is particularly useful in providing self-contained imaging systems which are sensitive at 390-500 nm but which can be photobleached to reduce background yellow; an imaging process including a photobleaching step following exposure and development is also disclosed.

Inventors

  • 👤 Paul C. Adair
  • 👤 Gary F. Hillenbrand
  • 👤 Paul D. Davis

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-09 21:40
CPC Classifications
G; G03; G03F; G03F7/00; G03F7/002; Y; Y10; Y10T; Y10T428/00; Y10T428/29; Y10T428/2982; Y10T428/2984; Y10T428/2985

Claims Analysis

Total Claims: 9
Claim 1
Independent Claim 232 words
An imaging sheet useful in forming full color images comprising a support having on a surface thereof a layer containing three sets of microcapsules having distinct sensitivities and containing respectively cyan, magenta, and yellow image-forming agents; one of said three sets of microcapsules being blue light-sensitive and including in the internal phase thereof a free radical addition polymerizable material and a photoinitiator system including a photobleachable sensitizer, said sensitizer being bleachable upon exposure to radiation in the wavelength range of 390 to 500 nm and being represented by formula (I): ##STR10## wherein Q is --Z--R 1 , Z is carbonyl, R 1 is a hydroxyl group, an alkenyl group, an alkoxy group, an alkyl group, an aryl group, a carboxyclic group or a heterocyclic group; R 2 , R 3 , R 4 and R 5 each independently represent hydrogen, an alkoxy group, a dialkylamino group, a halogen atom, an acyloxy group, a nitro group, a 5- or 6-membered heterocyclic group, or a group having the formula (II): ##STR11## wherein R 9 is an alkylene group; R 6 is hydrogen, an alkyl group or an aryl group; and wherein two or three of R 2 , R 3 , R 4 and R 5 and the nuclear carbon atoms to which they are attached can together form a fused ring or fused ring system, each ring being a 5- or 6-membered ring.
Claim 2
Dependent Claim 232 words
An imaging sheet useful in forming full color images comprising a support having on a surface thereof a layer containing three sets of microcapsules having distinct sensitivities and containing respectively cyan, magenta, and yellow image-forming agents; one of said three sets of microcapsules being blue light-sensitive and including in the internal phase thereof a free radical addition polymerizable material and a photoinitiator system including a photobleachable sensitizer, said sensitizer being bleachable upon exposure to radiation in the wavelength range of 390 to 500 nm and being represented by formula (I): ##STR10## wherein Q is --Z--R 1 , Z is carbonyl, R 1 is a hydroxyl group, an alkenyl group, an alkoxy group, an alkyl group, an aryl group, a carboxyclic group or a heterocyclic group; R 2 , R 3 , R 4 and R 5 each independently represent hydrogen, an alkoxy group, a dialkylamino group, a halogen atom, an acyloxy group, a nitro group, a 5- or 6-membered heterocyclic group, or a group having the formula (II): ##STR11## wherein R 9 is an alkylene group; R 6 is hydrogen, an alkyl group or an aryl group; and wherein two or three of R 2 , R 3 , R 4 and R 5 and the nuclear carbon atoms to which they are attached can together form a fused ring or fused ring system, each ring being a 5- or 6-membered ring.
Claim 3
Dependent Claim 14 words
The imaging sheet of claim 1 wherein said microcapsule has a discrete capsule wall.
Claim 4
Dependent Claim 18 words
The imaging sheet of claim 2 wherein said free radical addition polymerizable material is an ethylenically unsaturated compound.
Claim 5
Dependent Claim 18 words
The imaging sheet of claim 3 wherein said sensitizer is substituted at the 7-position by a dialkylamino group.
Claim 6
Dependent Claim 26 words
The imaging sheet of claim 4 wherein R 1 is selected from the group consisting of an alkenyl group, a thienyl group, or a cinnamoyl group.
Claim 7
Dependent Claim 19 words
The imaging sheet of claim 5 wherein said photoinitiator system additionally includes an N,N-dialkylaniline compound as a hydrogen donor.
Claim 8
Dependent Claim 38 words
The imaging sheet of claim 6 wherein said imaging sheet additionally includes a developer material co-deposited with said microcapsules on the surface thereof, said developer being capable of reacting with said image-forming agent and forming a visible image.
Claim 9
Dependent Claim 26 words
The imaging sheet of claim 1 wherein said sensitizer is selected from the group consisting of 7-diethylamine-5',7'-dimethoxy-3,3'-carbonylbiscoumarin; 3,3'-carbonylbis(5,7-dimethoxycoumarin); 7-diethylamino-3,3'-carbonylbiscoumarin; 7-diethylamino-7'-methoxy-3,3'-carbonylbiscoumarin; 7-diethylamino-7'-dimethylamino-3,3'-carbonylbiscoumarin; 7-diethylamino-3-thenoylcoumarin; 3-(2-coumariloyl)-7-diethylaminocoumarin; 3-cinnamoyl-7-diethylaminocoumarin; and 3[(4-dimethylamino)-cinnamoyl-7-diethylaminocoumarin.

References Cited (Backward Citations)

US3533797A Cited
US4147552A Cited
US4268667A Cited
US4399209A Cited
US4440846A Cited
US4416966A Cited
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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1990-12-14 1991-06-15 1991-12-15 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1994-12-14 1995-06-15 1995-12-15 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1998-12-14 1999-06-15 1999-12-15 $7700.00 Window Closed / Lapsed

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