Alcoholic solution of sulphonic acid-containing copolymer dyed with basic dye

Claim 2

A coloring material comprising a solution of an alcohol-soluble copolymer having a sulphonic acid group or a salt thereof, which is dyed with a basic dye, in a solvent comprising an alcohol as a main component; said copolymer being derived from (i) 0 1% to 40% by weight of at least one ethylenically unsaturated sulphonic acid or salt thereof selected from the group consisting of styrene-sulphonic acid, vinylbenzyl-sulphonic acid, vinyl-sulphonic acid, allyl-sulphonic acid, methallyl-sulphonic acid, acryloyloxyethyl-sulphonic acid, acryloyloxyethyl-sulphonic acid, methacryloyloxypropyl-sulphonic acid an 2-acrylamido-2-methylpropane-sulphonic acid, and the lithium, sodium, potassium or ammonim salts of said unsaturated sulphonic acids, and (ii) 60 to 99.9% by weight of at least one copolymerizable monomer composed of, based on the weight of the copolymerizable monomer, 60% to 100% by weight of at least one monomer selected from the group consisting of hydoxyethyl acrylate, hydroxyethyl methacrylate, hydroxyporpyl acrylate, hydroxyethyl methacrylate, polyethylene glycol monomethacrylate, ethyl acrylate, ethyl methacrylate, porpyl acrylate, porpyl methacrylate, butyl acrylate and butyl methacrylate, and 0% to 40% by weight of other copolymerizable monomer; and the concentration of said alcohol-soluble copolymer in the solution being in the range of 1% to 50% by weight.

Claim 3

A process for the preparation of coloring materials, which comprises the steps of: (a 1 ) polymerizing a monomer mixture of an ethylenically unsaturated sulphonic acid or salt thereof and a copolymerizable monomer in water and then adding a basic dye to the thus-obtained aqueous liquid of the formed polymer, or (a 2 ) carrying out said polymerization in the presence of a basic dye, and then (b) either dissolving (i) the thus-obtained aqueous liquid of the formed colored polymer or (ii) a colored polymer obtained by removing water from the thus-obtained aqueous liquid of the formed colored polymer in a solvent comprising an alcohol as a main component; said monomer mixture being composed of (i) 0.1% to 40% by weight of at least on ethylenically unsaturated sulphonic acid or a salt thereof selected from the group consisting of styrene-sulphonic acid, vinylbenzyl-sulphonic acid, vinyl-sulphonic acid, allyl-sulphonic acid, methallyl-sulphonic acid, acryloyloxyethyl-sulphonic acid, methacryloyloxypropoyl-sulphonic acid and 2-acrylamido-2-methyl-propane-sulphonic acid, and the lithium, sodium, potassium or ammonium salts of said unsaturated sulphonic acids, and (ii) 99.9% to 60% by weight of at least one copolymerizable monomer composed of, based on the weight of the copolymerizable monomer, 60% to 100% by weight of at least one monomer selected from the group consisting of hydroxyethyl acrylate, hydroxyethyl methacrylate, hydroxypropyl acrylate, hydroxypoopyl methacrylate, polyethylene glycol monomethacrylate, ethyl acrylate, ethyl methacrylate, propyl acrylate, propyl methacrylate, butyl acryalte and butyl methacrylate, and 0% to 40% by weight of other copolymerizable monomer.

Claim 4

A process for the preparation of coloring materials, which comprises the steps of: (a 1 ) polymerizing a monomer mixture of an ethylenically unsaturated sulphonic acid or salt thereof and a copolymerizable monomer in water and then adding a basic dye to the thus-obtained aqueous liquid of the formed polymer, or (a 2 ) carrying out said polymerization in the presence of a basic dye, and then (b) either dissolving (i) the thus-obtained aqueous liquid of the formed colored polymer or (ii) a colored polymer obtained by removing water from the thus-obtained aqueous liquid of the formed colored polymer in a solvent comprising an alcohol as a main component; said monomer mixture being composed of (i) 0.1% to 40% by weight of at least on ethylenically unsaturated sulphonic acid or a salt thereof selected from the group consisting of styrene-sulphonic acid, vinylbenzyl-sulphonic acid, vinyl-sulphonic acid, allyl-sulphonic acid, methallyl-sulphonic acid, acryloyloxyethyl-sulphonic acid, methacryloyloxypropoyl-sulphonic acid and 2-acrylamido-2-methyl-propane-sulphonic acid, and the lithium, sodium, potassium or ammonium salts of said unsaturated sulphonic acids, and (ii) 99.9% to 60% by weight of at least one copolymerizable monomer composed of, based on the weight of the copolymerizable monomer, 60% to 100% by weight of at least one monomer selected from the group consisting of hydroxyethyl acrylate, hydroxyethyl methacrylate, hydroxypropyl acrylate, hydroxypoopyl methacrylate, polyethylene glycol monomethacrylate, ethyl acrylate, ethyl methacrylate, propyl acrylate, propyl methacrylate, butyl acryalte and butyl methacrylate, and 0% to 40% by weight of other copolymerizable monomer.

Claim 5

A process for the preparation of coloring materials, which comprises the steps of: (a 1 ) polymerizing a monomer mixture of an ethylenically unsaturated sulphonic acid or salt thereof and a copolymerizable monomer in a solvent comprising an alcohol and a main component and then adding a basic dye to the obtained polymer solution, or (a 2 ) carrying out said polymerization in the presence of a basic dye; said monomer mixture being composed of (i) 0.1% to 40% by weight of at least one ethylenically unsaturated sulphonic acid or salt thereof selected from the group consisting of styrene-sulphonic acid, vinylbenzyl-sulphonic acid, vinyl-sulphonic acid, allyl-sulphonic acid, methallyl-sulphonic acid, acryloyloxyethyl-sulphonic acid, methacryloyloxypropyl-sulphonic acid and 2-acrylamido-2-methyl-propane-sulphonic acid, and the lithium sodium, potassium or ammonium salts of said unsaturated sulphonic acids and (ii) 99.9% to 60% by weight of at least one copolymerizable monomer composed of, based on the weight of the copolymerizable monomer, 60% to 100% by weight of at least one monome selected from the group consisting of hydroxyethyl acrylate, hydroxyethyl methacrylate, polyethylene glycol monomethacrylate, ethyl acrylate, ethyl methacrylate, propyl acrylate, propyl methacrylate, butyl acrylate and butyl methacrylate, and 0% to 40% by weight of other copolymerizable monomer.

Claim 6

A process for the preparation of coloring materials, which comprises the steps of: (a 1 ) polymerizing a monomer mixture of an ethylenically unsaturated sulphonic acid or salt thereof and a copolymerizable monomer in a solvent comprising an alcohol and a main component and then adding a basic dye to the obtained polymer solution, or (a 2 ) carrying out said polymerization in the presence of a basic dye; said monomer mixture being composed of (i) 0.1% to 40% by weight of at least one ethylenically unsaturated sulphonic acid or salt thereof selected from the group consisting of styrene-sulphonic acid, vinylbenzyl-sulphonic acid, vinyl-sulphonic acid, allyl-sulphonic acid, methallyl-sulphonic acid, acryloyloxyethyl-sulphonic acid, methacryloyloxypropyl-sulphonic acid and 2-acrylamido-2-methyl-propane-sulphonic acid, and the lithium sodium, potassium or ammonium salts of said unsaturated sulphonic acids and (ii) 99.9% to 60% by weight of at least one copolymerizable monomer composed of, based on the weight of the copolymerizable monomer, 60% to 100% by weight of at least one monome selected from the group consisting of hydroxyethyl acrylate, hydroxyethyl methacrylate, polyethylene glycol monomethacrylate, ethyl acrylate, ethyl methacrylate, propyl acrylate, propyl methacrylate, butyl acrylate and butyl methacrylate, and 0% to 40% by weight of other copolymerizable monomer.

Claim 7

A coloring material according to claim 1, wherein the alcohol is at least one member selected from methyl alcohol, ethyl alcohol, n-propyl alcohol, iso-propyl alcohol, n-butyl alcohol, sec-butyl alcohol, tert-butyl alcohol, isobutyl alcohol, ethylene glycol, diethylene glycol, propylene glycol, glycerol, and monomethyl ethers and monoethyl ethers of said polyhydric alcohols.

Claim 8

A process according to claim 2, wherein, in the step of (a 1 ), a basic dye is added to the aqueous liquid of the formed polymer at a pH value of 2 to 7.

Claim 9

A process according to claim 2 wherein said polymerization (a 2 ) is carried out at a pH value of 2 to 7.

Claim 10

A process according to claim 3 wherein, in the step of (a 1 ), a basic dye is added to the polymer solution at a pH value of 2 to 7.

Claim 11

A process according to claim 3 wherein said polymerization (a 2 ) is carried out at a pH value of 2 to 7.