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US4709987A Expired / Lapsed US ⏱️ 0.0 years remaining

Pressure and temperature insensitive glass and optical coatings and fibers therefrom

Assignee: United States Department of the Navy
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Filing: 1985-12-10
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Granted: 1987-12-01
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Expires: 2005-12-10
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Abstract

Abstract Pressure and temperature insensitive optical fibers are produced using a Ta2O5 based glass composition which has a high bulk modulus and a low thermal expansion coefficient. The glass composition can function as the cladding in the optical fiber or as a protective coating which surrounds the cladding thereby protecting the fiber from fluctuations in temperature and pressure.

Inventors

  • 👤 Douglas Blackburn
  • 👤 Albert Feldman
  • 👤 Nicholas Lagakos

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-28 03:44
CPC Classifications
G; G02; G02B; G02B6/00; G02B6/44; G02B6/4401; G02B6/4429; G02B6/4436; C; C03; C03C; C03C13/00; C03C13/04; C03C13/045; C03C13/046; G02B6/443

Claims Analysis

Total Claims: 27
Claim 1
Independent Claim 100 words
A glass composition suitable for use as a temperature and pressure insensitive protective layer for optical fibers, comprising: up to about 30 weight percent CaO; between about 15-25 weight percent Al 2 O 3 ; between about 5-15 weight percent MgO; up to about 15 weight percent TiO 2 ; up to about 10 weight percent ZrO 2 ; between about 20-35 weight percent SiO 2 ; up to about 10 weight percent B 2 O 3 ; between about 5-45 weight percent Ta 2 O 5 ; and up to about 40 weight percent Nb 2 O 5 .
Claim 2
Dependent Claim 100 words
A glass composition suitable for use as a temperature and pressure insensitive protective layer for optical fibers, comprising: up to about 30 weight percent CaO; between about 15-25 weight percent Al 2 O 3 ; between about 5-15 weight percent MgO; up to about 15 weight percent TiO 2 ; up to about 10 weight percent ZrO 2 ; between about 20-35 weight percent SiO 2 ; up to about 10 weight percent B 2 O 3 ; between about 5-45 weight percent Ta 2 O 5 ; and up to about 40 weight percent Nb 2 O 5 .
Claim 3
Dependent Claim 38 words
The glass composition of claim 1, comprising; about 20 weight percent Al 2 O 3 ; about 10 weight percent MgO; about 25 weight percent SiO 2 ; and about 45 weight percent Ta 2 O 5 .
Claim 4
Dependent Claim 50 words
The glass composition of claim 1, comprising; about 5 weight percent CaO; about 20 weight percent Al 2 O 3 ; about 10 weight percent MgO; about 10 weight percent TiO 2 ; about 25 weight percent SiO 2 ; and about 30 weight percent Ta 2 O 5 .
Claim 5
Dependent Claim 47 words
The glass composition of claim 1, comprising; about 20 weight percent Al 2 O 3 ; about 10 weight percent MgO; about 30 weight percent SiO 2 ; about 35 weight percent Ta 2 O 5 ; and about 5 weight percent B 2 O 3 .
Claim 6
Dependent Claim 45 words
The glass composition of claim 1, comprising; about 20 weight percent Al 2 O 3 ; about 10 weight percent MgO; about 5 weight percent TiO 2 ; about 35 weight percent SiO 2 : and about 30 weight percent Ta 2 O 5 .
Claim 7
Dependent Claim 107 words
An optical fiber, comprising: a solid cylindrical light-propagating core; a cladding concentrically surrounding said core; and a glass protective layer concentrically surrounding said cladding comprising up to about 30 weight percent CaO; between about 15-25 weight percent Al 2 O 3 ; between about 5-15 weight percent MgO; up to about 15 weight percent TiO 2 ; up to about 10 weight percent ZrO 2 ; between about 20-35 weight percent SiO 2 ; up to about 10 weight percent B 2 O 3 ; between about 5-45 weight percent Ta 2 O 5 ; and up to about 40 weight percent Nb 2 O 5 .
Claim 8
Dependent Claim 107 words
An optical fiber, comprising: a solid cylindrical light-propagating core; a cladding concentrically surrounding said core; and a glass protective layer concentrically surrounding said cladding comprising up to about 30 weight percent CaO; between about 15-25 weight percent Al 2 O 3 ; between about 5-15 weight percent MgO; up to about 15 weight percent TiO 2 ; up to about 10 weight percent ZrO 2 ; between about 20-35 weight percent SiO 2 ; up to about 10 weight percent B 2 O 3 ; between about 5-45 weight percent Ta 2 O 5 ; and up to about 40 weight percent Nb 2 O 5 .
Claim 9
Dependent Claim 18 words
The optical fiber of claim 6 having one or more substrate layers concentrically surrounding said glass protective layer.
Claim 10
Dependent Claim 16 words
The optical fiber of claim 6 having one or more substrate layers concentrically surrounding said cladding.
Claim 11
Dependent Claim 42 words
The optical fiber of claim 6 wherein said glass composition comprises: about 20 weight percent Al 2 O 3 ; about 10 weight percent MgO; about 25 weight percent SiO 2 ; and about 45 weight percent Ta 2 O 5 .
Claim 12
Dependent Claim 54 words
The optical fiber of claim 6 wherein said glass composition comprises: about 5 weight percent CaO; about 20 weight percent Al 2 O 3 ; about 10 weight percent MgO; about 10 weight percent TiO 2 ; about 25 weight percent SiO 2 ; and about 30 weight percent Ta 2 O 5 .
Claim 13
Dependent Claim 51 words
The optical fiber of claim 6 wherein said glass composition comprises: about 20 weight percent Al 2 O 3 ; about 10 weight percent MgO; about 30 weight percent SiO 2 ; about 35 weight percent Ta 2 O 5 ; and about 5 weight percent B 2 O 3 .
Claim 14
Dependent Claim 49 words
The optical fiber of claim 6 wherein said glass composition comprises: about 20 weight percent Al 2 O 3 ; about 10 weight percent MgO; about 5 weight percent TiO 2 ; about 35 weight percent SiO 2 ; and about 30 weight percent Ta 2 O 5 .
Claim 15
Dependent Claim 100 words
An optical fiber, comprising: a solid cylindrical light-propagating core; a cladding concentrically surrounding said core, said cladding comprising up to about 30 weight percent CaO; between about 15-25 weight percent Al 2 O 3 ; between about 5-15 weight percent MgO; up to about 15 weight percent TiO 2 ; up to about 10 weight percent ZrO 2 ; between about 20-35 weight percent SiO 2 ; up to about 10 weight percent B 2 O 3 ; between about 5-45 weight percent Ta 2 O 5 ; and up to about 40 weight percent Nb 2 O 5 .
Claim 16
Dependent Claim 100 words
An optical fiber, comprising: a solid cylindrical light-propagating core; a cladding concentrically surrounding said core, said cladding comprising up to about 30 weight percent CaO; between about 15-25 weight percent Al 2 O 3 ; between about 5-15 weight percent MgO; up to about 15 weight percent TiO 2 ; up to about 10 weight percent ZrO 2 ; between about 20-35 weight percent SiO 2 ; up to about 10 weight percent B 2 O 3 ; between about 5-45 weight percent Ta 2 O 5 ; and up to about 40 weight percent Nb 2 O 5 .
Claim 17
Dependent Claim 16 words
The optical fiber of claim 13 having one or more substrate layers concentrically surrounding said cladding.
Claim 18
Dependent Claim 42 words
The optical fiber of claim 13 wherein said glass composition comprises: about 20 weight percent Al 2 O 3 ; about 10 weight percent MgO; about 25 weight percent SiO 2 ; and about 45 weight percent Ta 2 O 5 .
Claim 19
Dependent Claim 54 words
The optical fiber of claim 13 wherein said glass composition comprises: about 5 weight percent CaO; about 20 weight percent Al 2 O 3 ; about 10 weight percent MgO; about 10 weight percent TiO 2 ; about 25 weight percent SiO 2 ; and about 30 weight percent Ta 2 O 5 .
Claim 20
Dependent Claim 51 words
The optical fiber of claim 13 wherein said glass composition comprises: about 20 weight percent Al 2 O 3 ; about 10 weight percent MgO; about 30 weight percent SiO 2 ; about 35 weight percent Ta 2 O 5 ; and about 5 weight percent B 2 O 3 .
Claim 21
Dependent Claim 49 words
The optical fiber of claim 13 wherein said glass composition comprises: about 20 weight percent Al 2 O 3 ; about 10 weight percent MgO; about 5 weight percent TiO 2 ; about 35 weight percent SiO 2 ; and about 30 weight percent Ta 2 O 5 .
Claim 22
Dependent Claim 102 words
A glass composition suitable for use as a temperature and pressure insensitive protective layer for optical fibers, consisting essentially of: up to about 30 weight percent CaO; between about 15-25 weight percnet Al 2 O 3 ; between about 5-15 weight percent MgO; up to about 15 weight percent TiO 2 ; up to about 10 weight percent ZrO 2 ; between about 20-35 weight percent SiO 2 ; up to about 10 weight percent B 2 O 3 ; between about 5-45 weight percent Ta 2 O 5 ; and up to about 40 weight percent Nb 2 O 5 .
Claim 23
Dependent Claim 102 words
A glass composition suitable for use as a temperature and pressure insensitive protective layer for optical fibers, consisting essentially of: up to about 30 weight percent CaO; between about 15-25 weight percnet Al 2 O 3 ; between about 5-15 weight percent MgO; up to about 15 weight percent TiO 2 ; up to about 10 weight percent ZrO 2 ; between about 20-35 weight percent SiO 2 ; up to about 10 weight percent B 2 O 3 ; between about 5-45 weight percent Ta 2 O 5 ; and up to about 40 weight percent Nb 2 O 5 .
Claim 24
Dependent Claim 40 words
The glass composition of claim 19, consisting essentially of: about 20 weight percent Al 2 O 3 ; about 10 weight percent MgO; about 25 weight percent SiO 2 ; and about 45 weight percent Ta 2 O 5 .
Claim 25
Dependent Claim 52 words
The glass composition of claim 19, consisting essentially of: about 5 weight percent CaO; about 20 weight percent Al 2 O 3 : about 10 weight percent MgO: about 10 weight percent TiO 2 ; about 25 weight percent SiO 2 ; and about 30 weight percent Ta 2 O 5 .
Claim 26
Dependent Claim 49 words
The glass composition of claim 19, consisting essentially of: about 20 weight percent Al 2 O 3 ; about 10 weight percent MgO; about 30 weight percent SiO 2 ; about 35 weight percent Ta 2 O 5 ; and about 5 weight persent B 2 O 3 .
Claim 27
Dependent Claim 47 words
The glass composition of claim 19, consisting essentially of: about 20 weight percent Al 2 O 3 ; about 10 weight percent MgO; about 5 weight percent TiO 2 ; about 35 weight percent SiO 2 ; and about 30 weight persent Ta 2 O 5 .

References Cited (Backward Citations)

US4427263A Cited
US4495298A Cited
US4482205A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1990-11-30 1991-06-01 1991-12-01 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1994-11-30 1995-06-01 1995-12-01 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1998-11-30 1999-06-01 1999-12-01 $7700.00 Window Closed / Lapsed

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