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US4696758A Expired / Lapsed US ⏱️ 0.0 years remaining

Gas mixtures for the vapor deposition of semiconductor material

Assignee: United Solar Systems Corp
•
Filing: 1986-10-06
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Granted: 1987-09-29
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Expires: 2006-10-06
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Abstract

Abstract Precursor gaseous mixtures from which to glow discharge deposit wide and narrow band gap semiconductor alloy material, said material characterized by improved photoconductivity and stability and improved resistance to photodegradation. There is also specifically disclosed a method of fabricating a narrow band gap semiconductor which method does not suffer from the effects of differential depletion of the components of the precursor gaseous mixture.

Inventors

  • 👤 Stanford R. Ovshinsky
  • 👤 Subhendu Guha
  • 👤 Prem Nath
  • 👤 Chi Chung Yang
  • 👤 Jeffrey Fournier
  • 👤 James Kulman

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-29 21:05
CPC Classifications
H; H10; H10P; H10P14/00; H10P14/20; H10P14/29; H10P14/2901; H10P14/2922; H10P14/24; H10P14/2923; H10P14/32; H10P14/3202; H10P14/3204; H10P14/3211; H10P14/3242; H10P14/3244; H10P14/3251; H10P14/34; H10P14/3402; H10P14/3404; H10P14/3411; H10P14/3438; H10P14/3441; H10P14/3442; H10P14/3444

Claims Analysis

Total Claims: 10
Claim 1
Independent Claim 93 words
A gaseous precursor mixture from which semiconductor alloy material may be deposited by glow discharge decomposition: said mixture including a polysilane compound and a germanium-containing compound, said compounds capable of decomposing and depositing at substantially similar rates when subjected to electromagnetic energy; and said polysilane compound having the general formula Si x R y H z , where R is chosen from the group consisting essentially of hydrogen, fluorine, chlorine, iodine, bromine and combinations thereof, x is an integer greater than one, y and z are each an integer or zero, and y+z=2x+2.
Claim 2
Dependent Claim 93 words
A gaseous precursor mixture from which semiconductor alloy material may be deposited by glow discharge decomposition: said mixture including a polysilane compound and a germanium-containing compound, said compounds capable of decomposing and depositing at substantially similar rates when subjected to electromagnetic energy; and said polysilane compound having the general formula Si x R y H z , where R is chosen from the group consisting essentially of hydrogen, fluorine, chlorine, iodine, bromine and combinations thereof, x is an integer greater than one, y and z are each an integer or zero, and y+z=2x+2.
Claim 3
Dependent Claim 11 words
A mixture as in claim 1, further including a diluent gas.
Claim 4
Dependent Claim 12 words
A mixture as in claim 2, wherein the diluent gas is hydrogen.
Claim 5
Dependent Claim 14 words
A mixture as in claim 1, further including a gaseous precursor source of fluorine.
Claim 6
Dependent Claim 14 words
A mixture as in claim 4, wherein said source of fluorine is silicon tetrafluoride.
Claim 7
Dependent Claim 15 words
A mixture as in claim 1, wherein said mixture further includes a source of hydrogen.
Claim 8
Dependent Claim 19 words
A mixture as in claim 1, wherein said mixture further includes a gaseous precursor source of a dopant element.
Claim 9
Dependent Claim 12 words
A mixture as in claim 7, wherein said dopant element is phosphorous.
Claim 10
Dependent Claim 12 words
A mixture as in claim 7, wherein said dopant element is boron.

References Cited (Backward Citations)

US4363868A Cited
US4405656A Cited
US4388344A Cited
US4517223A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1990-09-28 1991-03-30 1991-09-29 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1994-09-28 1995-03-30 1995-09-29 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1998-09-28 1999-03-30 1999-09-29 $7700.00 Window Closed / Lapsed

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