Claims Analysis
Total Claims: 27
Claim 1
Independent Claim
278 words
A moisture-curable composition comprising: (A) an ungelled partial hydrolysis product of an organosilicon-containing material, said organosilicon-containing material comprising greater than or equal to 10 mole percent of at least one organosilane compound corresponding to the formula R--Si--Y 3 in which R represents hydrogen, or a C 1 -C 10 group joined to Si through an Si--C linkage, and each Y independently represents an easily hydrolyzable group, wherein said partial hydrolysis product is prepared by hydrolyzing said easily hydrolyzable groups of said organosilane compound with water wherein the amount of water is determined according to the following formula (E.sub.1,2 ×0.5)+(E.sub.3,4 ×Z)=W, wherein W represents the total moles H 2 O employed calculated on total equivalents of said easily hydrolyzable groups given that one equivalent of said easily hydrolyzable groups corresponds to 1 mole of said easily hydrolyzable groups employed, E 1 ,2 represents the total number of equivalents of Y employed from organosilane compounds containing one or two Y groups, E 3 ,4 represents the total number of equivalents of Y employed from organosilane compounds containing three or four Y groups, and Z is a number in the range of from 0.023 to 0.43; provided that said organosilicon-containing material has an average functionality of equal to or greater than 2.4 based on easily hydrolyzable Y groups attached to silicon atoms of organosilane compounds containing easily hydrolyzable Y groups present in said organosilicon-containing material but excluding easily hydrolyzable Y groups attached to silicon atoms of organosilane compounds having only 1 easily hydrolyzable Y group which may be present in said organosilicon-containing material; and (B) an acrylic addition interpolymer containing at least one silicon atom directly bonded to a hydrolyzable group.
Claim 2
Dependent Claim
278 words
A moisture-curable composition comprising: (A) an ungelled partial hydrolysis product of an organosilicon-containing material, said organosilicon-containing material comprising greater than or equal to 10 mole percent of at least one organosilane compound corresponding to the formula R--Si--Y 3 in which R represents hydrogen, or a C 1 -C 10 group joined to Si through an Si--C linkage, and each Y independently represents an easily hydrolyzable group, wherein said partial hydrolysis product is prepared by hydrolyzing said easily hydrolyzable groups of said organosilane compound with water wherein the amount of water is determined according to the following formula (E.sub.1,2 ×0.5)+(E.sub.3,4 ×Z)=W, wherein W represents the total moles H 2 O employed calculated on total equivalents of said easily hydrolyzable groups given that one equivalent of said easily hydrolyzable groups corresponds to 1 mole of said easily hydrolyzable groups employed, E 1 ,2 represents the total number of equivalents of Y employed from organosilane compounds containing one or two Y groups, E 3 ,4 represents the total number of equivalents of Y employed from organosilane compounds containing three or four Y groups, and Z is a number in the range of from 0.023 to 0.43; provided that said organosilicon-containing material has an average functionality of equal to or greater than 2.4 based on easily hydrolyzable Y groups attached to silicon atoms of organosilane compounds containing easily hydrolyzable Y groups present in said organosilicon-containing material but excluding easily hydrolyzable Y groups attached to silicon atoms of organosilane compounds having only 1 easily hydrolyzable Y group which may be present in said organosilicon-containing material; and (B) an acrylic addition interpolymer containing at least one silicon atom directly bonded to a hydrolyzable group.
Claim 3
Dependent Claim
22 words
The composition of claim 1 wherein each Y represents --OR 1 wherein R 1 is a C 1 -C 3 alkyl group.
Claim 4
Dependent Claim
56 words
The composition of claim 1 wherein said ungelled partial hydrolysis product contains an amount of said easily hydrolyzable Y groups such that the ratio of the number of grams of said partial hydrolysis product to equivalents of said easily hydrolyzable Y groups in said partial hydrolysis product is in a range of from 40 to 300.
Claim 5
Dependent Claim
29 words
The composition of claim 1 wherein said organosilicon-containing material contains greater than or equal to 30 mole percent of said organosilane compound corresponding to the formula R--Si--Y 3 .
Claim 6
Dependent Claim
50 words
The composition of claim 1 from which at least a portion of volatile components has been removed from said ungelled partial hydrolysis product, prior to combination with said acrylic addition interpolymer, by distillation of said partial hydrolysis product at a temperature of less than or equal to 160 degrees Celsius.
Claim 7
Dependent Claim
57 words
The composition of claim 1 wherein said ungelled partial hydrolysis product comprises at least 10 percent by weight of a compound corresponding to the formula ##STR26## wherein R independently represents a C 1 -C 10 group joined to Si through an Si--C linkage, or hydrogen, and R 6 independently represents a C 1 -C 3 alkyl group.
Claim 8
Dependent Claim
111 words
The composition of claim 1 wherein said ungelled partial hydrolysis product of claim 1 comprises (1) at least 10 percent by weight of a compound corresponding to the formula R--Si(OR 6 ) 3 wherein R independently represents a C 1 -C 10 group joined to Si through an Si--C linkage, or hydrogen, and R 6 independently represents a C 1 -C 3 alkyl group, and (2) at least 10 percent by weight of a compound corresponding to the formula ##STR27## wherein R independently represents a C 1 -C 10 group joined to Si through an Si--C linkage, or hydrogen, and R 6 independently represents a C 1 -C 3 alkyl group.
Claim 9
Dependent Claim
157 words
The composition of claim 1 wherein said ungelled partial hydrolysis product of claim 1 comprises (1) at least 10 percent by weight of a compound corresponding to the formula R--Si(OR 6 ) 3 wherein R independently represents a C 1 -C 10 group joined to Si through an Si--C linkage, or hydrogen, and R 6 independently represents a C 1 -C 3 alkyl group, (2) at least 10 percent by weight of a compound corresponding to the formula ##STR28## wherein R independently represents a C 1 -C 10 group joined to Si through an Si--C linkage, or hydrogen, and R 6 independently represents a C 1 -C 3 alkyl group, and (3) at least 10 percent by weight of a compound corresponding to the formula ##STR29## wherein R independently represents a C 1 -C 10 group joined to Si through an Si--C linkage, or hydrogen, and R 6 independently represents a C 1 -C 3 alkyl group.
Claim 10
Dependent Claim
108 words
The composition of claim 1 wherein said ungelled partial hydrolysis product of claim 1 comprises (1) at least 10 percent by weight of a compound corresponding to the formula ##STR30## wherein R independently represents a C 1 -C 10 group joined to Si through an Si--C linkage, or hydrogen, and R 6 independently represents a C 1 -C 3 alkyl group, and (2) at least 10 percent by weight of a compound corresponding to the formula ##STR31## wherein R independently represents a C 1 -C 10 group joined to Si through an Si--C linkage, or hydrogen, and R 6 independently represents a C 1 -C 3 alkyl group.
Claim 11
Dependent Claim
70 words
The composition of claim 1 wherein said acrylic addition interpolymer contains alkoxy silane groups and/or acyloxy silane groups, said addition interpolymer derived from the reaction of a mixture of monomers wherein the mixture of monomers contains: (i) one or more ethylenically unsaturated silicon-free monomers, and (ii) a copolymerizable ethylenically unsaturated silane monomer selected from the group consisting of an alkoxy silane monomer, an acyloxy silane monomer, and a mixture thereof.
Claim 12
Dependent Claim
70 words
The composition of claim 10 wherein for said acrylic addition interpolymer the amount of said ethylenically unsaturated silicon-free monomers ranges from about 50 percent to about 95 percent by weight based on the total weight of said mixture of monomers, and the amount of said copolymerizable ethylenically unsaturated silane monomer ranges from about 5 to about 50 percent by weight based on the total weight of said mixture of monomers.
Claim 13
Dependent Claim
25 words
The composition of claim 11 wherein said ethylenically unsaturated silicon-free monomers (i) comprise an alkyl acrylate, alkyl methacrylate, vinyl aromatic hydrocarbon or a mixture thereof.
Claim 14
Dependent Claim
24 words
The composition of claim 11 wherein said silane monomer comprises a (meth)acrylatoalkoxysilane monomer having from 1 to 4 carbon atoms in the alkoxy group.
Claim 15
Dependent Claim
28 words
The composition of claim 10 wherein said acrylic addition interpolymer has a peak molecular weight as determined by gel permeation chromatography ranging from about 2,000 to about 20,000.
Claim 16
Dependent Claim
15 words
The composition of claim 10 additionally comprising an effective amount of a cure promoting catalyst.
Claim 17
Dependent Claim
78 words
The composition of claim 1 wherein said acrylic addition interpolymer has in a molecule thereof at least one group selected from: ##STR32## wherein each M independently is selected from the group of moieties consisting of Y, hydrogen, a C 1 -C 10 group joined to Si through an Si--C linkage, and OR 7 in which R 7 represents alkyl having at least 4 carbon atoms, aryl, alkylaryl, arylalkyl, aryloxyalkyl, or alkyloxyalkyl, wherein Y represents an easily hydrolyzable group.
Claim 18
Dependent Claim
21 words
The composition of claim 16 wherein at least one M is a methoxy group and at least one M is methyl.
Claim 19
Dependent Claim
99 words
The composition claim 16 wherein said acrylic addition interpolymer is a reaction product of an acrylic polyol and an organosilicon-containing material comprising at least 10 percent by weight of said organosilicon-containing material of a compound corresponding to the formula M--Si(OR 6 ) 3 wherein M independently represents OR 6 , hydrogen, a C 1 -C 10 group joined to Si through an Si--C linkage, or a OR 7 group in which R 7 represents alkyl having at least 4 carbon atoms, aryl, alkylaryl, arylalkyl, aryloxyalkyl, or alkyloxyalkyl, and R 6 independently represents a C 1 -C 3 alkyl group.
Claim 20
Dependent Claim
98 words
The composition of claim 16 wherein said acrylic addition interpolymer of is a reaction product of an acrylic polyol and an organosilicon-containing material comprising at least 10 percent by weight of said organosilicon-containing material of a compound corresponding to the formula ##STR33## wherein M independently represents OR 6 , hydrogen, a C 1 -C 10 group joined to Si through an Si--C linkage, or a OR 7 group in which R 7 represents alkyl having at least 4 carbon atoms, aryl, alkylaryl, arylalkyl, aryloxyalkyl, or alkyloxyalkyl, and R 6 independently represents a C 1 -C 3 alkyl group.
Claim 21
Dependent Claim
97 words
The composition of claim 16 wherein said acrylic addition interpolymer is a reaction product of an acrylic polyol and an organosilicon-containing material comprising at least 10 percent by weight of said organosilicon-containing material of a compound corresponding to the formula ##STR34## wherein M independently represents OR 6 , hydrogen, a C 1 -C 10 group joined to Si through an Si--C linkage, or a OR 7 group in which R 7 represents alkyl having at least 4 carbon atoms, aryl, alkylaryl, arylalkyl, aryloxyalkyl, or alkyloxyalkyl, and R 6 independently represents a C 1 -C 3 alkyl group.
Claim 22
Dependent Claim
122 words
The composition of claim 16 wherein said acrylic addition interpolymer is a reaction product of an acrylic polyol and an organosilicon-containing material comprising a mixture containing at least 10 percent by weight of said organosilicon-containing material of a compound corresponding to the formula M--Si(OR 6 ) 3 and at least 10 percent by weight of said organosilicon-containing material of a compound corresponding to the formula ##STR35## wherein M independently represents OR 6 , hydrogen, a C 1 -C 10 group joined to Si through an Si--C linkage, or a OR 7 group in which R 7 represents alkyl having at least 4 carbon atoms, aryl, alkylaryl, arylalkyl, aryloxyalkyl, or alkyloxyalkyl, and R 6 independently represents a C 1 -C 3 alkyl group.
Claim 23
Dependent Claim
90 words
The composition of claim 16 wherein said acrylic addition interpolymer is a reaction product of an acrylic polyol and a partial hydrolysis product of a compound corresponding to the formula M--Si(OR 6 ) 3 wherein M independently represents OR 6 , hydrogen, a C 1 -C 10 group joined to Si through an Si--C linkage, or a OR 7 group in which R 7 represents alkyl having at least 4 carbon atoms, aryl, alkylaryl, arylalkyl, aryloxyalkyl, or alkyloxyalkyl, and R 6 independently represents a C 1 -C 3 alkyl group.
Claim 24
Dependent Claim
22 words
The composition of claim 22 wherein at least one OR 6 is a methoxy group and at least one M is methyl.
Claim 25
Dependent Claim
29 words
The composition of claim 22 wherein said acrylic polyol has a weight average molecular weight determined by gel permeation chromatography using a polystyrene standard of from 600 to 50,000.
Claim 26
Dependent Claim
19 words
The composition of claim 22 wherein said acrylic polyol has a hydroxyl equivalent weight of from 116 to 1,000.
Claim 27
Dependent Claim
15 words
The composition of claim 22 additionally comprising an effective amount of a cure promoting catalyst.