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US4444973A Expired / Lapsed US ⏱️ 0.0 years remaining

Coatings for thermoplastics

Assignee: Bayer AG
•
Filing: 1982-08-26
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Granted: 1984-04-24
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Expires: 2002-08-26
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Abstract

Abstract The present invention relates to protective coating formulations, in particular to transparent abrasion-resistant and scratch-resistant coatings on transparent thermoplastic polymers, which coatings essentially consist of a hydrolyzed siloxane compound, a dispersion of colloidal silicon dioxide, etherified methylolmelamine, a blocked polyisocyanate, acetic acid and a polysiloxane terminated by hydroxyl groups.

Inventors

  • 👤 Manfred Schonfelder
  • 👤 Helmut Steinberger

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-24 22:55
CPC Classifications
C; C09; C09D; C09D183/00; C09D183/04; C08; C08G; C08G18/00; C08G18/06; C08G18/28; C08G18/40; C08G18/61; C08G18/70; C08G18/72; C08G18/80; C08G18/8061; C08J; C08J7/00; C08J7/04; C08J7/0427; C08J7/043; C08J7/046; C08J2483/00; Y; Y10; Y10T; Y10T428/00; Y10T428/31504; Y10T428/31507; Y10T428/31652; Y10T428/31663

Claims Analysis

Total Claims: 4
Claim 1
Independent Claim 311 words
A coating composition consisting of approximately (A) 10-40% by weight, relative to the total weight of the coating composition, of a partially hydrolyzed, siloxane compound which is obtained by hydrolysis in water at about 50°-80° C. for a period of about 1 to 12 hours of at least one of (a), (b), (c) or (d), wherein (a) is a hydrocarbon trialkoxysilane of the formula R'Si(OR").sub.3' wherein R' denotes an alkyl group having 1 to 4 carbon atoms, a phenyl group or vinyl group and R" denotes an alkyl group having 1 to 4 carbon atoms, (b) is a co-condensation product of (a) and 1 to 40% of a phenyltrialkoxysilane or vinyltrialkoxysilane, wherein the alkoxy group contains 1 to 4 carbon atoms, (c) is a co-condensation product of 1 mol of (a) and 0.05 to 1 mol of a tetraalkoxysilane, wherein the alkoxy group contains 1 to 4 carbon atoms, and (d) is a co-condensation product of 1 mol of (a) and 0.05 to 1 mol of a dialkyldialkoxysilane, wherein the alkyl and alkoxy groups contain 1 to 4 carbon atoms, (B) 0 to 40% by weight, relative to the total weight of the coating compositions, of an aqueous dispersion of colloidal silicon dioxide. (C) 0 to 5% by weight, relative to the total weight of the coating agent, of an etherified methylolmelamine, (D) 0.05 to 15% by weight, relative to the total weight of the coating composition, of a blocked polyisocyanate, (E) 0.5 to 30% by weight, relative to the total weight of the coating composition, of acetic acid, and (F) 0.05 to 4% by weight, relative to the total weight of the coating composition, of a polysiloxane which is terminated by hydroxyl group, has an average chain length of between 1 to 25 and a molecular weight of 150 to 1800, and (G) an inert organic solvent as the remainder.
Claim 2
Dependent Claim 311 words
A coating composition consisting of approximately (A) 10-40% by weight, relative to the total weight of the coating composition, of a partially hydrolyzed, siloxane compound which is obtained by hydrolysis in water at about 50°-80° C. for a period of about 1 to 12 hours of at least one of (a), (b), (c) or (d), wherein (a) is a hydrocarbon trialkoxysilane of the formula R'Si(OR").sub.3' wherein R' denotes an alkyl group having 1 to 4 carbon atoms, a phenyl group or vinyl group and R" denotes an alkyl group having 1 to 4 carbon atoms, (b) is a co-condensation product of (a) and 1 to 40% of a phenyltrialkoxysilane or vinyltrialkoxysilane, wherein the alkoxy group contains 1 to 4 carbon atoms, (c) is a co-condensation product of 1 mol of (a) and 0.05 to 1 mol of a tetraalkoxysilane, wherein the alkoxy group contains 1 to 4 carbon atoms, and (d) is a co-condensation product of 1 mol of (a) and 0.05 to 1 mol of a dialkyldialkoxysilane, wherein the alkyl and alkoxy groups contain 1 to 4 carbon atoms, (B) 0 to 40% by weight, relative to the total weight of the coating compositions, of an aqueous dispersion of colloidal silicon dioxide. (C) 0 to 5% by weight, relative to the total weight of the coating agent, of an etherified methylolmelamine, (D) 0.05 to 15% by weight, relative to the total weight of the coating composition, of a blocked polyisocyanate, (E) 0.5 to 30% by weight, relative to the total weight of the coating composition, of acetic acid, and (F) 0.05 to 4% by weight, relative to the total weight of the coating composition, of a polysiloxane which is terminated by hydroxyl group, has an average chain length of between 1 to 25 and a molecular weight of 150 to 1800, and (G) an inert organic solvent as the remainder.
Claim 3
Dependent Claim 17 words
A thermoplastic article produced by coating the article with a composition according to claim 1 and heating.
Claim 4
Dependent Claim 12 words
An article according to claim 2, wherein the thermoplastic material comprises polycarbonate.

References Cited (Backward Citations)

EP0017187A1 Cited
US4315091A Cited
GB2067582A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1987-04-24 1987-10-24 1988-04-24 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1991-04-24 1991-10-24 1992-04-24 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1995-04-24 1995-10-24 1996-04-24 $7700.00 Window Closed / Lapsed

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