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Sterically hindered photographic coupler solvents and photographic elements employing same

Assignee: Eastman Kodak Co
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Filing: 1985-12-24
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Granted: 1987-08-04
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Expires: 2005-12-24
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Abstract

Abstract Photographic coupler solvents comprising aromatic carboxylic esters such as phthalates and isophthalates having bulky or branched ester substituents are described for incorporation in photographic emulsions and elements. The solvents are preferably employed in the cyan layer to protect the cyan dye against ferrous ion reduction. The solvents also provide improvements in yellow dye stability to light, cyan dye stability in the dark and magenta dye stability to heat and light.

Inventors

  • 👤 Sundaram Krishnamurthy

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-30 13:16
CPC Classifications
G; G03; G03C; G03C7/00; G03C7/30; G03C7/388; G03C7/3885

Claims Analysis

Total Claims: 16
Claim 1
Independent Claim 229 words
A photographic element comprising a support having thereon at least one silver halide emulsion layer having associated therewith a dye-forming coupler and a coupler solvent therefor having the formula: ##STR76## wherein each X may independently represent a halogen atom, an alkyl group of from 1 to about 20 carbon atoms, an alkoxy group of from 1 to about 20 carbon atoms, or a carboxylic ester; m represents an integer of 0 to 5; n represents an integer of 1 to 4; and R 1 , R 2 , and R 3 each independently represents a substituted or unsubstituted alkyl group; a substituted or unsubstituted alicyclic group, saturated or partially saturated; a substituted or unsubstituted aralkyl group; a substituted or unsubstituted aryl group; a substituted or unsubstituted heterocyclyl group; or may be combined together to form one or more nonaromatic rings; with the proviso that the alpha hydrogens of R 1 , R 2 , and R 3 total no more than seven; and with the further proviso that R 1 can additionally be hydrogen when (a) R 2 and R 3 join together to form a ring substituted by no more than one alpha hydrogen or (b) R 2 and R 3 do not join to form a ring and if at least one of R 2 or R 3 contains an alpha carbon having two different non-hydrogen substituents.
Claim 2
Dependent Claim 229 words
A photographic element comprising a support having thereon at least one silver halide emulsion layer having associated therewith a dye-forming coupler and a coupler solvent therefor having the formula: ##STR76## wherein each X may independently represent a halogen atom, an alkyl group of from 1 to about 20 carbon atoms, an alkoxy group of from 1 to about 20 carbon atoms, or a carboxylic ester; m represents an integer of 0 to 5; n represents an integer of 1 to 4; and R 1 , R 2 , and R 3 each independently represents a substituted or unsubstituted alkyl group; a substituted or unsubstituted alicyclic group, saturated or partially saturated; a substituted or unsubstituted aralkyl group; a substituted or unsubstituted aryl group; a substituted or unsubstituted heterocyclyl group; or may be combined together to form one or more nonaromatic rings; with the proviso that the alpha hydrogens of R 1 , R 2 , and R 3 total no more than seven; and with the further proviso that R 1 can additionally be hydrogen when (a) R 2 and R 3 join together to form a ring substituted by no more than one alpha hydrogen or (b) R 2 and R 3 do not join to form a ring and if at least one of R 2 or R 3 contains an alpha carbon having two different non-hydrogen substituents.
Claim 3
Dependent Claim 28 words
The element of claim 1 wherein said coupler solvent has the formula: ##STR77## wherein R 1 , R 2 and R 3 are defined as in claim 1.
Claim 4
Dependent Claim 20 words
The element of claim 1 wherein said dye-forming coupler forms a cyan dye upon reaction with oxidized color developing agent.
Claim 5
Dependent Claim 31 words
The element of claim 3 wherein said cyan dye-forming coupler is a phenol or a naphthol and said coupler and said coupler solvent are located in said silver halide emulsion layer.
Claim 6
Dependent Claim 87 words
The element of claim 2 wherein R 1 is hydrogen or an alkyl group of from 1 to about 10 carbon atoms, R 2 is an alkyl group of from 1 to about 10 carbon atoms, R 3 is an alkyl or substituted alkyl group of from 2 to about 12 carbon atoms or an aryl or substituted aryl group of 6 to about 20 carbon atoms, or R 2 and R 3 are combined together to form a ring of about 4 to about 10 atoms.
Claim 7
Dependent Claim 44 words
The element of claim 2 wherein R 1 and R 2 are the same or different alkyl or substituted alkyl groups containing from 1 to about 10 carbon atoms and R 3 is an alkyl group containing from 2 to about 12 carbon atoms.
Claim 8
Dependent Claim 37 words
The element of claim 2 wherein R 1 is an alkyl group of from 1 to about 10 carbon atoms and R 2 and R 3 are combined together to form a ring of 6 carbon atoms.
Claim 9
Dependent Claim 17 words
The element of claim 2 wherein R 1 , R 2 and R 3 are each ethyl.
Claim 10
Dependent Claim 21 words
The element of claim 2 wherein R 1 is hydrogen or methyl, R 2 is methyl, and R 3 is ##STR78##
Claim 11
Dependent Claim 19 words
The element of claim 2 wherein R 1 and R 2 are each methyl and R 3 is ##STR79##
Claim 12
Dependent Claim 19 words
The element of claim 2 wherein R 1 is ethyl, R 2 is methyl and R 3 is ##STR80##
Claim 13
Dependent Claim 22 words
The element of claim 2 wherein R 1 is hydrogen or butyl and R 2 --C--R 3 forms the fenchyl group ##STR81##
Claim 14
Dependent Claim 20 words
The element of claim 2 wherein R 1 is methyl and R 2 and R 3 form a cyclohexyl ring.
Claim 15
Dependent Claim 20 words
The element of claim 2 wherein R 1 is methyl and R 2 --C--R 3 forms the menthyl group ##STR82##
Claim 16
Dependent Claim 19 words
The element of claim 2 wherein R 1 is hydrogen, R 2 is methyl and R 3 is phenyl.

References Cited (Backward Citations)

US2322027A Cited
US3475172A Cited
GB1274523A Cited
US3779765A Cited
US4193802A Cited
US4308328A Cited
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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1990-08-03 1991-02-02 1991-08-04 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1994-08-03 1995-02-02 1995-08-04 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1998-08-03 1999-02-02 1999-08-04 $7700.00 Window Closed / Lapsed

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