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US4675460A Expired / Lapsed US ⏱️ 0.0 years remaining

Process

Assignee: Commonwealth Scientific and Industrial Research Organisation
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Filing: 1986-01-13
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Granted: 1987-06-23
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Expires: 2006-01-13
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Abstract

Abstract Gasoline capable of further processing into diesel fuel is produced by catalytic conversion of lower olefins, using a zeolite catalyst which has been modified by substituting a significant portion of the cation sites thereof by basic cations. A preferred catalyst comprises a zeolite and a binder, said catalyst containing at least 0.2% by weight of exchangeable basic cations. The gasoline so produced is readily converted by contact with a Friedel Crafts catalyst into a hydrocarbon product having a significant fraction boiling in the distillate range.

Inventors

  • 👤 Duncan Seddon
  • 👤 Sandra Bessell

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-28 16:47
CPC Classifications
C; C10; C10G; C10G50/00; C07; C07C; C07C2/00; C07C2529/00; C07C2529/04; C07C2529/06

Claims Analysis

Total Claims: 19
Claim 1
Independent Claim 98 words
A process for the production of diesel fuel comprising: converting lower olefins into gasoline by contacting said lower olefins with a zeolite catalyst; converting said gasoline into a hydrocarbon product, having a portion thereof boiling in the distillate range, by contacting said gasoline with a Friedel-Crafts catalyst; separating diesel fuel from said hydrocarbon product; wherein said zeolite catalyst is a ZSM-5, a ZSM-11 or a ZSM-12 catalyst having cation sites which has been modified by substituting a portion of said cation sites by at least one basic cation selected from the group consisting of potassium, sodium and calcium.
Claim 2
Dependent Claim 98 words
A process for the production of diesel fuel comprising: converting lower olefins into gasoline by contacting said lower olefins with a zeolite catalyst; converting said gasoline into a hydrocarbon product, having a portion thereof boiling in the distillate range, by contacting said gasoline with a Friedel-Crafts catalyst; separating diesel fuel from said hydrocarbon product; wherein said zeolite catalyst is a ZSM-5, a ZSM-11 or a ZSM-12 catalyst having cation sites which has been modified by substituting a portion of said cation sites by at least one basic cation selected from the group consisting of potassium, sodium and calcium.
Claim 3
Dependent Claim 100 words
A process for conversion of lower olefins to diesel fuel comprising: contacting said lower olefins with a first catalyst to converter said lower olefins into gasoline; contacting said gasoline with a second catalyst to convert said gasoline into a hydrocarbon product containing diesel fuel; separating said diesel fuel from said hydrocarbon product; wherein said first catalyst comprises a zeolite and a binder and contains at least 0.2% by weight of exchangeable basic cations, determined as oxide on the total weight of the catalyst, said cations being at least one member selected from the group consisting of potassium, sodium and calcium.
Claim 4
Dependent Claim 100 words
A process for conversion of lower olefins to diesel fuel comprising: contacting said lower olefins with a first catalyst to converter said lower olefins into gasoline; contacting said gasoline with a second catalyst to convert said gasoline into a hydrocarbon product containing diesel fuel; separating said diesel fuel from said hydrocarbon product; wherein said first catalyst comprises a zeolite and a binder and contains at least 0.2% by weight of exchangeable basic cations, determined as oxide on the total weight of the catalyst, said cations being at least one member selected from the group consisting of potassium, sodium and calcium.
Claim 5
Dependent Claim 30 words
The process according to claim 2, wherein said first catalyst contains at least 0.3% by weight of exchangeable basic cations, determined as oxide on the total weight of the catalyst.
Claim 6
Dependent Claim 17 words
The process according to claim 3, wherein said first catalyst includes alkali metal and acid cationic sites.
Claim 7
Dependent Claim 17 words
The process according to claim 2, wherein said first catalyst includes alkali metal and acid cationic sites.
Claim 8
Dependent Claim 148 words
A process for the production of diesel fuel comprising: (a) converting lower olefins to a first hydrocarbon product containing hydrocarbons boiling in the gasoline boiling range by contacting said lower olefins with a zeolite catalyst; (b) converting said first hydrocarbon product to a second hydrocarbon product having a portion which boils in the distillate range by contacting said first hydrocarbon product with a second catalyst; and (c) separating diesel fuel from said second hydrocarbon product; wherein said conversion of said lower olefins is effected at a temperature between about 100° and 450° C., at a pressure up to about 50 atmospheres, and at an LHSV of about 0.5 to hr -1 , and wherein said zeolite catalyst has cationic sites which have been modified by substituting a portion of said cation sites with at least one basic cation selected from the group consisting of potassium, sodium and calcium.
Claim 9
Dependent Claim 148 words
A process for the production of diesel fuel comprising: (a) converting lower olefins to a first hydrocarbon product containing hydrocarbons boiling in the gasoline boiling range by contacting said lower olefins with a zeolite catalyst; (b) converting said first hydrocarbon product to a second hydrocarbon product having a portion which boils in the distillate range by contacting said first hydrocarbon product with a second catalyst; and (c) separating diesel fuel from said second hydrocarbon product; wherein said conversion of said lower olefins is effected at a temperature between about 100° and 450° C., at a pressure up to about 50 atmospheres, and at an LHSV of about 0.5 to hr -1 , and wherein said zeolite catalyst has cationic sites which have been modified by substituting a portion of said cation sites with at least one basic cation selected from the group consisting of potassium, sodium and calcium.
Claim 10
Dependent Claim 42 words
The process for the production of diesel fuel according to claim 6, wherein said zeolite catalyst comprises a zeolite and a binder, said catalyst containing at least 0.2% of exchangeable basic cations, determined as oxide on the total weight of the catalyst.
Claim 11
Dependent Claim 34 words
The process for the production of diesel fuel according to claim 7, wherein said zeolite catalyst contains at least 0.3% of exchangeable basic cations, determined as oxide on the total weight of the catalyst.
Claim 12
Dependent Claim 33 words
The process for the production of diesel fuel according to claim 6, wherein said zeolite is of the ZSM family having an Al 2 O 3 content of at least 1.0% by weight.
Claim 13
Dependent Claim 27 words
The process according to claim 2, wherein said zeolite is of the ZSM family having an Al 2 O 3 content of at least 1.0% by weight.
Claim 14
Dependent Claim 20 words
The process for the production of diesel fuel according to claim 9, wherein said zeolite is ZSM-5, ZSM-11 or ZSM-12.
Claim 15
Dependent Claim 14 words
The process according to claim 10, wherein said zeolite is ZSM-5, ZSM-11 or ZSM-12.
Claim 16
Dependent Claim 25 words
The process for the production of diesel fuel according to claim 7, wherein said binder comprises up to 90% by weight of said zeolite catalyst.
Claim 17
Dependent Claim 25 words
The process for the production of diesel fuel according to claim 8, wherein said binder comprises up to 90% by weight of said zeolite catalyst.
Claim 18
Dependent Claim 20 words
The process for the production of diesel fuel according to claim 11, wherein said second catalyst is a Friedel-Crafts catalyst.
Claim 19
Dependent Claim 14 words
The process according to claim 12, wherein said second catalyst is a Friedel-Crafts catalyst.

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1990-06-22 1990-12-22 1991-06-23 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1994-06-22 1994-12-22 1995-06-23 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1998-06-22 1998-12-22 1999-06-23 $7700.00 Window Closed / Lapsed

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