Catalytic conversion with zeolite ZSM-39

Claim 2

A proess for catalytic cracking of a hydrocarbon cracking stock, which process comprises contacting said cracking stock under catalytic cracking conditions with a catalyst comprising a catalytically active form of a porous zeolite having a composition, expressed in terms of moles of anhydrous oxides, per 100 moles of silica, as follows: (0-2.5)M.sub.2/n O:(0-2.5)Al.sub.2 O.sub.3 :(100)SiO.sub.2 wherein M is at least one cation having a valence n, and wherein said zeolite is characterized by a characteristic X-ray diffraction pattern as set forth in Table 1 of the specification.

Claim 3

A process for catalytic cracking of a hydrocarbon cracking stock, which process comprises contacting said cracking stock under catalytic cracking conditions with a catalyst comprising a catalytically active form of a porous zeolite having a composition, expressed in terms of moles of anhydrous oxides, per 100 moles of silica as follows: (0-2.5)R.sub.2 O:(0-2.5)M.sub.2/n O:(0-2.5)Al.sub.2 O.sub.3 :100SiO.sub.2 wherein R 2 O is the oxide form of an organic compound which contains an element of Group VB of the Periodic Chart and at least one alkyl or aryl organic group having between 1 and 7 carbon atoms, at least one of which organic groups is ethyl, and M is an alkali or alkaline earth metal having a valence n, and wherein said zeolite is characterized by a characteristic X-ray diffraction pattern as set forth in Table 1 of the specification.

Claim 4

A process for catalytic cracking of a hydrocarbon cracking stock, which process comprises contacting said cracking stock under catalytic cracking conditions with a catalyst comprising a catalytically active form of a porous zeolite having a composition, expressed in terms of moles of anhydrous oxides, per 100 moles of silica as follows: (0-2.5)R.sub.2 O:(0-2.5)M.sub.2/n O:(0-2.5)Al.sub.2 O.sub.3 :100SiO.sub.2 wherein R 2 O is the oxide form of an organic compound which contains an element of Group VB of the Periodic Chart and at least one alkyl or aryl organic group having between 1 and 7 carbon atoms, at least one of which organic groups is ethyl, and M is an alkali or alkaline earth metal having a valence n, and wherein said zeolite is characterized by a characteristic X-ray diffraction pattern as set forth in Table 1 of the specification.

Claim 5

A process according to claim 2 wherein said catalytic cracking comprises hydrocracking of a hydrocrackable charge stock under hydrocracking conditions and wherein said catalyst also comprises a hydrogenation component.

Claim 6

A process for the catalytic reforming of a reforming stock, which process comprises contacting said reforming stock under catalytic reforming conditions with a catalyst comprising a hydrogenation component and a catalytically active form of a porous zeolite having a composition, expressed in terms of moles of anhydrous oxides, per 100 moles of silica, as follows: (0-2.5)M.sub.2/n O:(0-2.5)Al.sub.2 O.sub.3 :(100)SiO.sub.2 wherein M is at least one cation having a valence n, and wherein said zeolite is characterized by a chracteristic X-ray diffraction pattern as set forth in Table 1 of the specification.

Claim 7

A process for the catalytic reforming of a reforming stock, which process comprises contacting said reforming stock under catalytic reforming conditions with a catalyst comprising a hydrogenation component and a catalytically active form of a porous zeolite having a composition, expressed in terms of moles of anhydrous oxides, per 100 moles of silica, as follows: (0-2.5)M.sub.2/n O:(0-2.5)Al.sub.2 O.sub.3 :(100)SiO.sub.2 wherein M is at least one cation having a valence n, and wherein said zeolite is characterized by a chracteristic X-ray diffraction pattern as set forth in Table 1 of the specification.

Claim 8

A process for the catalytic reforming of a reforming stock, which process comprises contacting said reforming stock under catalytic reforming conditions with a catalyst comprising a hydrogenation component and a catalytically active form of a porous zeolite having a composition, expressed in terms of moles of anhydrous oxides, per 100 moles of silica as follows: (0-2.5)R.sub.2 O:(0-2.5)M.sub.2/n O:(0-2.5)Al.sub.2 O.sub.3 :100SiO.sub.2 wherein R 2 O is the oxide form of an organic compound which contains an element of Group VB of the Periodic Chart and at least one alkyl or aryl organic group having between 1 and 7 carbon atoms, at least one of which organic groups is ethyl, and M is an alkali or alkaline earth metal having a valence n, and wherein said zeolite is characterized by a characteristic X-ray diffraction pattern as set forth in Table 1 of the specification.

Claim 9

A process for the catalytic reforming of a reforming stock, which process comprises contacting said reforming stock under catalytic reforming conditions with a catalyst comprising a hydrogenation component and a catalytically active form of a porous zeolite having a composition, expressed in terms of moles of anhydrous oxides, per 100 moles of silica as follows: (0-2.5)R.sub.2 O:(0-2.5)M.sub.2/n O:(0-2.5)Al.sub.2 O.sub.3 :100SiO.sub.2 wherein R 2 O is the oxide form of an organic compound which contains an element of Group VB of the Periodic Chart and at least one alkyl or aryl organic group having between 1 and 7 carbon atoms, at least one of which organic groups is ethyl, and M is an alkali or alkaline earth metal having a valence n, and wherein said zeolite is characterized by a characteristic X-ray diffraction pattern as set forth in Table 1 of the specification.

Claim 10

A process for the catalytic hydroisomerization of a hydrocarbon charge stock comprising normal paraffins or olefins or mixtures thereof, which process comprises contacting said hydrocarbon charge stock under catalytic hydroisomerization conditions with a catalyst comprising a hydrogenation component and a catalytically active form of a porous zeolite having a composition, expressed in terms of moles of anhydrous oxides, per 100 moles of silica, as follows: (0-2.5)M.sub.2/n O:(0-2.5)Al.sub.2 O.sub.3 :(100)SiO.sub.2 wherein M is at least one cation having a valence n, and wherein said zeolite is characterized by a characteristic X-ray diffraction pattern as set forth in Table 1 of the specification.

Claim 11

A process for the catalytic hydroisomerization of a hydrocarbon charge stock comprising normal paraffins or olefins or mixtures thereof, which process comprises contacting said hydrocarbon charge stock under catalytic hydroisomerization conditions with a catalyst comprising a hydrogenation component and a catalytically active form of a porous zeolite having a composition, expressed in terms of moles of anhydrous oxides, per 100 moles of silica, as follows: (0-2.5)M.sub.2/n O:(0-2.5)Al.sub.2 O.sub.3 :(100)SiO.sub.2 wherein M is at least one cation having a valence n, and wherein said zeolite is characterized by a characteristic X-ray diffraction pattern as set forth in Table 1 of the specification.

Claim 12

A process for the catalytic hydroisomerization of a hydrocarbon charge stock comprising normal paraffins or olefins or mixtures thereof, which process comprises contacting said hydrocarbon charge stock under catalytic hydroisomerization conditions with a catalyst comprising a hydrogenation component and a catalytically active form of a porous zeolite having a composition, expressed in terms of moles of anhydrous oxides, per 100 moles of silica as follows: (0-2.5)R.sub.2 O:(0-2.5)M.sub.2/n O:(0-2.5)Al.sub.2 O.sub.3 :100SiO.sub.2 wherein R 2 O is the oxide form of an organic compound which contains an element of Group VB of the Periodic Chart and at least one alkyl or aryl organic group having between 1 and 7 carbon atoms, at least one of which organic groups is ethyl, and M is an alkali or alkaline earth metal having a valence n, and wherein said zeolite is characterized by a characteristic X-ray diffraction pattern as set forth in Table 1 of the specification.

Claim 13

A process for the catalytic hydroisomerization of a hydrocarbon charge stock comprising normal paraffins or olefins or mixtures thereof, which process comprises contacting said hydrocarbon charge stock under catalytic hydroisomerization conditions with a catalyst comprising a hydrogenation component and a catalytically active form of a porous zeolite having a composition, expressed in terms of moles of anhydrous oxides, per 100 moles of silica as follows: (0-2.5)R.sub.2 O:(0-2.5)M.sub.2/n O:(0-2.5)Al.sub.2 O.sub.3 :100SiO.sub.2 wherein R 2 O is the oxide form of an organic compound which contains an element of Group VB of the Periodic Chart and at least one alkyl or aryl organic group having between 1 and 7 carbon atoms, at least one of which organic groups is ethyl, and M is an alkali or alkaline earth metal having a valence n, and wherein said zeolite is characterized by a characteristic X-ray diffraction pattern as set forth in Table 1 of the specification.

Claim 14

A process according to claim 1, 4 or 6 wherein M is selected from the group consisting of hydrogen, ammonium, or a metal of Groups II-VIII of the Periodic Chart or mixtures thereof.

Claim 15

A process according to claim 2, 3, 5 or 7 wherein the Group VB element of the R 2 O compound is nitrogen or phosphorus and the organic group is an alkyl group.

Claim 16

A process according to claim 2, 3, 5 or 7 wherein R 2 O comprises a tetraethylammonium compound and M is selected from the group consisting of sodium and potassium.

Claim 17

A process according to claim 1, 3, 4 or 6 wherein substantially no alumina is present in the zeolite.