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US4673471A Expired / Lapsed US ⏱️ 0.0 years remaining

Method of electrodepositing a chromium alloy deposit

Assignee: JFE Engineering Corp
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Filing: 1986-11-03
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Granted: 1987-06-16
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Expires: 2006-11-03
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Abstract

Abstract The invention provides a Cr alloy plating bath comprising a sulfate bath consisting essentially of divalent Cr ion and trivalent Cr ion in a total amount of between 1.5 to 2.0 mol/l, cation of one or more than two selected from the group consisting of potassium ion, sodium ion and ammonium ion in a total amount of 1.5 to 2.5 mol/l, and metal ion of one or more than two selected from the group consisting of Fe, Ni and Co, in an amount of less than 0.6 mol/l, wherein the invention provides stable plating, without requiring a separation between electrolytes with a diaphragm, and provides good deposition at high current efficiencies.

Inventors

  • 👤 Hiroshi Kagechika
  • 👤 Akira Tonouchi
  • 👤 Roland Kammel

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-23 23:14
CPC Classifications
C; C25; C25D; C25D3/00; C25D3/02; C25D3/56; C25D3/562

Claims Analysis

Total Claims: 4
Claim 1
Independent Claim 121 words
A method of electrodepositing a chromium alloy plate which comprises electrolyzing an aqueous bath consisting of a chromium salt providing from 1.5 to 2.0 mol/liter of trivalent and divalent ions, alkali salt providing from 1.5 to 2.5 mol/liter of an ion selected from the group consisting of potassium ion, sodium ion and ammonium ion, and a salt of alloying metal providing not less than 0.6 mol/liter of an ion selected from the group consisting of iron, nickel and cobalt; wherein said bath is maintained at a temperature between 30° to 80° C., said bath is maintained at a pH of between 1.5 and 1.8, and said bath is subjected to a current density of between 10 to 80 A/dm 2 .
Claim 2
Independent Claim 121 words
A method of electrodepositing a chromium alloy plate which comprises electrolyzing an aqueous bath consisting of a chromium salt providing from 1.5 to 2.0 mol/liter of trivalent and divalent ions, alkali salt providing from 1.5 to 2.5 mol/liter of an ion selected from the group consisting of potassium ion, sodium ion and ammonium ion, and a salt of alloying metal providing not less than 0.6 mol/liter of an ion selected from the group consisting of iron, nickel and cobalt; wherein said bath is maintained at a temperature between 30° to 80° C., said bath is maintained at a pH of between 1.5 and 1.8, and said bath is subjected to a current density of between 10 to 80 A/dm 2 .
Claim 3
Dependent Claim 24 words
The methodof claim 1, wherein said metal ion is a combination of iron, nickel and cobalt used together, and said potassium ion is used.
Claim 4
Dependent Claim 24 words
The method of claim 1, wherein said metal ion is a combination of iron and cobalt used together, and said potassium ion is used.

References Cited (Backward Citations)

US2766196A Cited
US2990343A Cited
US2822326A Cited
US2927066A Cited
US3111464A Cited
US3954574A Cited
US4054494A Cited
US4093521A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1990-06-15 1990-12-15 1991-06-16 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1994-06-15 1994-12-15 1995-06-16 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1998-06-15 1998-12-15 1999-06-16 $7700.00 Window Closed / Lapsed

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